Q. Which of the following is a characteristic of an SN1 reaction?
A.
Involves a concerted mechanism
B.
Forms a carbocation intermediate
C.
Requires a strong nucleophile
D.
Occurs in a single step
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Solution
SN1 reactions involve the formation of a carbocation intermediate, which is a key characteristic of this two-step mechanism.
Correct Answer: B — Forms a carbocation intermediate
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Q. Which of the following is a characteristic of an SN2 reaction?
A.
Involves a carbocation intermediate
B.
Bimolecular reaction rate
C.
Involves a strong base
D.
Occurs with tertiary substrates
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Solution
SN2 reactions are bimolecular, meaning the rate depends on the concentration of both the substrate and the nucleophile.
Correct Answer: B — Bimolecular reaction rate
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Q. Which of the following is a characteristic of an S_N2 reaction?
A.
Involves a carbocation intermediate
B.
Bimolecular reaction rate
C.
Involves a strong base
D.
Occurs in a polar protic solvent
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Solution
S_N2 reactions are bimolecular and involve a direct attack by the nucleophile, leading to a concerted mechanism without a carbocation.
Correct Answer: B — Bimolecular reaction rate
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Q. Which of the following is a characteristic of cis isomers?
A.
Higher boiling points than trans isomers
B.
Lower boiling points than trans isomers
C.
Same boiling points as trans isomers
D.
Always optically active
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Solution
Cis isomers typically have higher boiling points than their trans counterparts due to increased polarity.
Correct Answer: A — Higher boiling points than trans isomers
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Q. Which of the following is a characteristic of condensation polymerization?
A.
It produces small molecules as byproducts
B.
It requires high temperatures
C.
It only involves alkenes
D.
It is a one-step process
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Solution
Condensation polymerization typically involves the reaction of two different monomers, resulting in the release of small molecules such as water or methanol.
Correct Answer: A — It produces small molecules as byproducts
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Q. Which of the following is a characteristic of coordination compounds?
A.
They contain only ionic bonds.
B.
They have a central metal atom bonded to ligands.
C.
They cannot conduct electricity.
D.
They are always soluble in water.
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Solution
Coordination compounds consist of a central metal atom bonded to one or more ligands.
Correct Answer: B — They have a central metal atom bonded to ligands.
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Q. Which of the following is a characteristic of diastereomers?
A.
They are mirror images of each other.
B.
They have different physical properties.
C.
They have the same connectivity.
D.
They cannot be separated by physical methods.
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Solution
Diastereomers are not mirror images and typically have different physical properties.
Correct Answer: B — They have different physical properties.
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Q. Which of the following is a characteristic of E2 elimination reactions?
A.
Requires a strong nucleophile
B.
Involves a carbocation intermediate
C.
Occurs in a single concerted step
D.
Produces a racemic mixture
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Solution
E2 reactions occur in a single concerted step where the base abstracts a proton while the leaving group departs.
Correct Answer: C — Occurs in a single concerted step
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Q. Which of the following is a characteristic of electrochemical cells?
A.
They convert chemical energy to electrical energy
B.
They only operate in acidic solutions
C.
They require a constant supply of reactants
D.
They cannot be reversed
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Solution
Electrochemical cells convert chemical energy into electrical energy, which is a fundamental characteristic of these systems.
Correct Answer: A — They convert chemical energy to electrical energy
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Q. Which of the following is a characteristic of enantiomers?
A.
They have the same physical properties.
B.
They rotate plane-polarized light in opposite directions.
C.
They can be separated by distillation.
D.
They have different molecular formulas.
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Solution
Enantiomers are non-superimposable mirror images and rotate plane-polarized light in opposite directions.
Correct Answer: B — They rotate plane-polarized light in opposite directions.
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Q. Which of the following is a characteristic of f-block elements?
A.
They are all radioactive
B.
They have partially filled f-orbitals
C.
They are all metals
D.
They have low density
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Solution
F-block elements have partially filled f-orbitals, which is a defining characteristic of these elements.
Correct Answer: B — They have partially filled f-orbitals
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Q. Which of the following is a characteristic of hydrogen as a metalloid?
A.
It conducts electricity
B.
It has a high melting point
C.
It can form cations
D.
It is malleable
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Solution
Hydrogen can form cations (H+) in chemical reactions, which is a characteristic of metals.
Correct Answer: C — It can form cations
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Q. Which of the following is a characteristic of hydrogen as a reducing agent?
A.
It can only reduce metals
B.
It can reduce metal oxides
C.
It cannot reduce nonmetals
D.
It is always oxidized
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Solution
Hydrogen can act as a reducing agent by reducing metal oxides to their corresponding metals.
Correct Answer: B — It can reduce metal oxides
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Q. Which of the following is a characteristic of hydrogen peroxide (H2O2)?
A.
It is a strong acid
B.
It acts as a reducing agent
C.
It is a stable compound
D.
It contains a single bond between oxygen atoms
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Solution
Hydrogen peroxide (H2O2) can act as a reducing agent due to its ability to donate electrons.
Correct Answer: B — It acts as a reducing agent
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Q. Which of the following is a characteristic of metallic bonding?
A.
Electrons are shared between specific atoms.
B.
Electrons are localized around individual atoms.
C.
Electrons are delocalized and free to move.
D.
Electrons are transferred from one atom to another.
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Solution
In metallic bonding, electrons are delocalized and can move freely, contributing to conductivity and malleability.
Correct Answer: C — Electrons are delocalized and free to move.
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Q. Which of the following is a characteristic of metals?
A.
Brittle
B.
Good conductors of heat
C.
Dull appearance
D.
Low density
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Solution
Metals are typically good conductors of heat and electricity due to the presence of free-moving electrons.
Correct Answer: B — Good conductors of heat
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Q. Which of the following is a characteristic of physisorption?
A.
High heat of adsorption
B.
Reversible process
C.
Specificity to surface
D.
Formation of strong bonds
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Solution
Physisorption is characterized by weak van der Waals forces, making it a reversible process with low heat of adsorption.
Correct Answer: B — Reversible process
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Q. Which of the following is a characteristic of real gases compared to ideal gases?
A.
No intermolecular forces
B.
Volume of gas particles is negligible
C.
Attraction between particles
D.
Obeys gas laws perfectly
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Solution
Real gases exhibit intermolecular forces, which affect their behavior, especially at high pressures and low temperatures.
Correct Answer: C — Attraction between particles
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Q. Which of the following is a characteristic of saturated fatty acids?
A.
Contain double bonds
B.
Are liquid at room temperature
C.
Have a higher melting point than unsaturated fatty acids
D.
Are more reactive than unsaturated fatty acids
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Solution
Saturated fatty acids contain no double bonds and typically have a higher melting point than unsaturated fatty acids.
Correct Answer: C — Have a higher melting point than unsaturated fatty acids
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Q. Which of the following is a characteristic of stereoisomers?
A.
They have different molecular formulas.
B.
They have the same connectivity of atoms.
C.
They cannot be interconverted without breaking bonds.
D.
They have different boiling points.
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Solution
Stereoisomers have the same connectivity but differ in the spatial arrangement of atoms.
Correct Answer: B — They have the same connectivity of atoms.
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Q. Which of the following is a characteristic of Werner complexes?
A.
They can only form octahedral geometries
B.
They exhibit isomerism
C.
They are always neutral
D.
They contain only anionic ligands
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Solution
Werner complexes can exhibit isomerism due to different arrangements of ligands around the central metal atom.
Correct Answer: B — They exhibit isomerism
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Q. Which of the following is a characteristic property of amines?
A.
They are acidic
B.
They have a fishy odor
C.
They are non-polar
D.
They do not form hydrogen bonds
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Solution
Amines typically have a fishy odor due to their structure and are known for their ability to form hydrogen bonds.
Correct Answer: B — They have a fishy odor
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Q. Which of the following is a characteristic reaction of alkynes?
A.
Hydrogenation
B.
Hydrohalogenation
C.
Halogenation
D.
All of the above
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Solution
Alkynes can undergo hydrogenation, hydrohalogenation, and halogenation reactions, making all of the above options characteristic reactions.
Correct Answer: D — All of the above
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Q. Which of the following is a chiral molecule?
A.
2-butanol
B.
1-butanol
C.
butane
D.
propene
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Solution
2-butanol has a chiral center at the second carbon, making it chiral.
Correct Answer: A — 2-butanol
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Q. Which of the following is a common application of acid-base titration?
A.
Determining the purity of a solid
B.
Measuring the pH of a solution
C.
Analyzing the concentration of acetic acid in vinegar
D.
Identifying unknown compounds
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Solution
Acid-base titration is commonly used to analyze the concentration of acetic acid in vinegar.
Correct Answer: C — Analyzing the concentration of acetic acid in vinegar
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Q. Which of the following is a common application of aromatic compounds in the real world?
A.
Dyes
B.
Pharmaceuticals
C.
Plastics
D.
All of the above
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Solution
Aromatic compounds are widely used in the production of dyes, pharmaceuticals, and plastics, making them versatile in various applications.
Correct Answer: D — All of the above
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Q. Which of the following is a common application of coordination compounds in medicine?
A.
Antacids
B.
Chemotherapy drugs
C.
Pain relievers
D.
Antibiotics
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Solution
Coordination compounds are commonly used in chemotherapy drugs, such as cisplatin, which is used to treat various cancers.
Correct Answer: B — Chemotherapy drugs
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Q. Which of the following is a common application of electrochemistry in corrosion prevention?
A.
Cathodic protection
B.
Anodic oxidation
C.
Thermal treatment
D.
Mechanical reinforcement
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Solution
Cathodic protection is a technique that prevents corrosion by making the metal surface the cathode of an electrochemical cell.
Correct Answer: A — Cathodic protection
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Q. Which of the following is a common application of electrolysis?
A.
Water splitting
B.
Photosynthesis
C.
Combustion
D.
Fermentation
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Solution
Electrolysis is commonly used for water splitting to produce hydrogen and oxygen gases.
Correct Answer: A — Water splitting
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Q. Which of the following is a common application of electrophoresis?
A.
Determining pH of a solution
B.
Separating proteins based on size and charge
C.
Measuring absorbance of light
D.
Titrating an acid with a base
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Solution
Electrophoresis is commonly used to separate proteins based on their size and charge by applying an electric field.
Correct Answer: B — Separating proteins based on size and charge
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