Chemistry (School & UG)

Q. What is the purpose of using a buffer solution in a titration?
  • A. To maintain a constant pH
  • B. To increase the reaction rate
  • C. To dilute the analyte
  • D. To enhance color change
Q. What is the purpose of using a buffer solution in electrophoresis?
  • A. To increase the conductivity of the solution
  • B. To maintain a constant pH during the separation
  • C. To enhance the visibility of the bands
  • D. To prevent overheating of the gel
Q. What is the purpose of using a pH meter in titration?
  • A. To measure the volume of titrant added
  • B. To determine the exact endpoint of the titration
  • C. To mix the solutions thoroughly
  • D. To calculate the concentration of the analyte
Q. What is the purpose of using a reference sample in UV-Vis spectroscopy?
  • A. To calibrate the instrument
  • B. To increase the sensitivity of the measurement
  • C. To compare the sample's absorbance against a known standard
  • D. To reduce background noise
Q. What is the purpose of using a standard solution in titration?
  • A. To dilute the analyte
  • B. To provide a known concentration for comparison
  • C. To stabilize the temperature
  • D. To increase the reaction rate
Q. What is the rate constant (k) for a first-order reaction with a half-life of 10 minutes?
  • A. 0.0693 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. What is the rate law for a reaction that is first order with respect to A and second order with respect to B?
  • A. Rate = k[A][B]
  • B. Rate = k[A]^1[B]^2
  • C. Rate = k[A]^2[B]^1
  • D. Rate = k[A]^2[B]^2
Q. What is the rate law for a reaction that is second order in A and first order in B?
  • A. Rate = k[A]^2[B]
  • B. Rate = k[A][B]^2
  • C. Rate = k[A][B]
  • D. Rate = k[A]^2 + k[B]
Q. What is the rate law for a reaction that is second order with respect to A and first order with respect to B?
  • A. Rate = k[A][B]
  • B. Rate = k[A]^2[B]
  • C. Rate = k[A]^2
  • D. Rate = k[A][B]^2
Q. What is the rate law for a second-order reaction?
  • A. Rate = k[A]
  • B. Rate = k[A]^2
  • C. Rate = k[A][B]
  • D. Rate = k[A]^2[B]
Q. What is the rate law for the reaction A + B → C if the rate is found to be first order in A and second order in B?
  • A. Rate = k[A][B]
  • B. Rate = k[A]^2[B]
  • C. Rate = k[A][B]^2
  • D. Rate = k[A]^2[B]^2
Q. What is the relationship between (R)-2-butanol and (S)-2-butanol?
  • A. They are identical.
  • B. They are diastereomers.
  • C. They are enantiomers.
  • D. They are constitutional isomers.
Q. What is the relationship between atomic radius and ionization energy?
  • A. Directly proportional
  • B. Inversely proportional
  • C. No relationship
  • D. Fluctuates
Q. What is the relationship between atomic size and metallic character?
  • A. Directly proportional
  • B. Inversely proportional
  • C. No relationship
  • D. Fluctuates
Q. What is the relationship between enthalpy and internal energy at constant pressure?
  • A. ΔH = ΔU + PΔV.
  • B. ΔH = ΔU - PΔV.
  • C. ΔH = ΔU.
  • D. ΔH = PΔV.
Q. What is the relationship between enthalpy change and bond dissociation energy?
  • A. ΔH is always equal to bond dissociation energy.
  • B. ΔH is the sum of bond dissociation energies of reactants minus products.
  • C. ΔH is the sum of bond dissociation energies of products minus reactants.
  • D. There is no relationship.
Q. What is the relationship between enthalpy change and heat at constant pressure?
  • A. ΔH = Q
  • B. ΔH = W
  • C. ΔH = Q + W
  • D. ΔH = 0
Q. What is the relationship between enthalpy change and the heat capacity at constant pressure (Cp)?
  • A. ΔH = Cp * ΔT
  • B. ΔH = Cv * ΔT
  • C. ΔH = Cp / ΔT
  • D. ΔH = ΔT / Cp
Q. What is the relationship between enthalpy change and the spontaneity of a reaction?
  • A. A negative enthalpy change guarantees spontaneity
  • B. A positive enthalpy change guarantees spontaneity
  • C. Enthalpy change does not affect spontaneity
  • D. Spontaneity depends on enthalpy and entropy changes
Q. What is the relationship between Gibbs free energy (G) and spontaneity of a reaction?
  • A. G < 0 indicates non-spontaneous reaction
  • B. G > 0 indicates spontaneous reaction
  • C. G = 0 indicates spontaneous reaction
  • D. G < 0 indicates spontaneous reaction
Q. What is the relationship between Gibbs free energy (ΔG) and cell potential (E) in an electrochemical cell?
  • A. ΔG = -nFE
  • B. ΔG = nFE
  • C. ΔG = -E/nF
  • D. ΔG = E/nF
Q. What is the relationship between Gibbs free energy and cell potential?
  • A. G = -nFE
  • B. G = nFE
  • C. G = 0
  • D. G = nF/E
Q. What is the relationship between Gibbs free energy change (ΔG) and cell potential (E) in electrochemistry?
  • A. ΔG = -nFE
  • B. ΔG = nFE
  • C. ΔG = -E/nF
  • D. ΔG = E/nF
Q. What is the relationship between pressure and temperature in a closed container of gas?
  • A. Directly proportional
  • B. Inversely proportional
  • C. No relationship
  • D. Exponential relationship
Q. What is the relationship between pressure and temperature in a closed system according to Gay-Lussac's Law?
  • A. Pressure is directly proportional to volume
  • B. Pressure is inversely proportional to temperature
  • C. Pressure is directly proportional to temperature
  • D. Pressure is independent of temperature
Q. What is the relationship between pressure and volume for an ideal gas at constant temperature?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Graham's Law
Q. What is the relationship between pressure and volume in a gas at constant temperature?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Ideal Gas Law
Q. What is the relationship between pressure and volume in an ideal gas at constant temperature?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Graham's Law
Q. What is the relationship between reaction rate and concentration for a first-order reaction?
  • A. Rate is proportional to concentration
  • B. Rate is proportional to the square of concentration
  • C. Rate is independent of concentration
  • D. Rate is inversely proportional to concentration
Q. What is the relationship between the rate constant and temperature according to the Arrhenius equation?
  • A. Rate constant is independent of temperature
  • B. Rate constant increases with temperature
  • C. Rate constant decreases with temperature
  • D. Rate constant is constant at all temperatures
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