Chemistry (School & UG)
Q. What is the purpose of using a buffer solution in a titration?
A.
To maintain a constant pH
B.
To increase the reaction rate
C.
To dilute the analyte
D.
To enhance color change
Show solution
Solution
A buffer solution is used in titration to maintain a constant pH, which is crucial for accurate results, especially in acid-base titrations.
Correct Answer: A — To maintain a constant pH
Learn More →
Q. What is the purpose of using a buffer solution in electrophoresis?
A.
To increase the conductivity of the solution
B.
To maintain a constant pH during the separation
C.
To enhance the visibility of the bands
D.
To prevent overheating of the gel
Show solution
Solution
Buffer solutions maintain a stable pH, which is crucial for the proper separation of charged molecules during electrophoresis.
Correct Answer: B — To maintain a constant pH during the separation
Learn More →
Q. What is the purpose of using a pH meter in titration?
A.
To measure the volume of titrant added
B.
To determine the exact endpoint of the titration
C.
To mix the solutions thoroughly
D.
To calculate the concentration of the analyte
Show solution
Solution
A pH meter is used to determine the exact endpoint of the titration by providing precise pH measurements throughout the process.
Correct Answer: B — To determine the exact endpoint of the titration
Learn More →
Q. What is the purpose of using a reference sample in UV-Vis spectroscopy?
A.
To calibrate the instrument
B.
To increase the sensitivity of the measurement
C.
To compare the sample's absorbance against a known standard
D.
To reduce background noise
Show solution
Solution
A reference sample is used to compare the absorbance of the sample against a known standard, ensuring accurate measurements.
Correct Answer: C — To compare the sample's absorbance against a known standard
Learn More →
Q. What is the purpose of using a standard solution in titration?
A.
To dilute the analyte
B.
To provide a known concentration for comparison
C.
To stabilize the temperature
D.
To increase the reaction rate
Show solution
Solution
A standard solution is used in titration to provide a known concentration that allows for accurate determination of the analyte's concentration.
Correct Answer: B — To provide a known concentration for comparison
Learn More →
Q. What is the rate constant (k) for a first-order reaction with a half-life of 10 minutes?
A.
0.0693 min^-1
B.
0.1 min^-1
C.
0.693 min^-1
D.
0.5 min^-1
Show solution
Solution
For a first-order reaction, k = 0.693 / t1/2. Thus, k = 0.693 / 10 min = 0.0693 min^-1.
Correct Answer: A — 0.0693 min^-1
Learn More →
Q. What is the rate law for a reaction that is first order with respect to A and second order with respect to B?
A.
Rate = k[A][B]
B.
Rate = k[A]^1[B]^2
C.
Rate = k[A]^2[B]^1
D.
Rate = k[A]^2[B]^2
Show solution
Solution
The rate law is determined by the order of the reaction with respect to each reactant. For first order in A and second order in B, the rate law is Rate = k[A]^1[B]^2.
Correct Answer: B — Rate = k[A]^1[B]^2
Learn More →
Q. What is the rate law for a reaction that is second order in A and first order in B?
A.
Rate = k[A]^2[B]
B.
Rate = k[A][B]^2
C.
Rate = k[A][B]
D.
Rate = k[A]^2 + k[B]
Show solution
Solution
The rate law is determined by the stoichiometry of the rate-determining step. For second order in A and first order in B, the rate law is Rate = k[A]^2[B].
Correct Answer: A — Rate = k[A]^2[B]
Learn More →
Q. What is the rate law for a reaction that is second order with respect to A and first order with respect to B?
A.
Rate = k[A][B]
B.
Rate = k[A]^2[B]
C.
Rate = k[A]^2
D.
Rate = k[A][B]^2
Show solution
Solution
The rate law is determined by the orders of the reactants. For second order in A and first order in B, the rate law is Rate = k[A]^2[B].
Correct Answer: B — Rate = k[A]^2[B]
Learn More →
Q. What is the rate law for a second-order reaction?
A.
Rate = k[A]
B.
Rate = k[A]^2
C.
Rate = k[A][B]
D.
Rate = k[A]^2[B]
Show solution
Solution
For a second-order reaction with respect to A, the rate law is Rate = k[A]^2.
Correct Answer: B — Rate = k[A]^2
Learn More →
Q. What is the rate law for the reaction A + B → C if the rate is found to be first order in A and second order in B?
A.
Rate = k[A][B]
B.
Rate = k[A]^2[B]
C.
Rate = k[A][B]^2
D.
Rate = k[A]^2[B]^2
Show solution
Solution
The rate law is determined by the orders of the reactants. Since the reaction is first order in A and second order in B, the rate law is Rate = k[A][B]^2.
Correct Answer: C — Rate = k[A][B]^2
Learn More →
Q. What is the relationship between (R)-2-butanol and (S)-2-butanol?
A.
They are identical.
B.
They are diastereomers.
C.
They are enantiomers.
D.
They are constitutional isomers.
Show solution
Solution
(R)-2-butanol and (S)-2-butanol are enantiomers because they are non-superimposable mirror images.
Correct Answer: C — They are enantiomers.
Learn More →
Q. What is the relationship between atomic radius and ionization energy?
A.
Directly proportional
B.
Inversely proportional
C.
No relationship
D.
Fluctuates
Show solution
Solution
Atomic radius and ionization energy are inversely proportional; as atomic radius increases, ionization energy decreases.
Correct Answer: B — Inversely proportional
Learn More →
Q. What is the relationship between atomic size and metallic character?
A.
Directly proportional
B.
Inversely proportional
C.
No relationship
D.
Fluctuates
Show solution
Solution
Metallic character increases with atomic size, as larger atoms can lose electrons more easily.
Correct Answer: A — Directly proportional
Learn More →
Q. What is the relationship between enthalpy and internal energy at constant pressure?
A.
ΔH = ΔU + PΔV.
B.
ΔH = ΔU - PΔV.
C.
ΔH = ΔU.
D.
ΔH = PΔV.
Show solution
Solution
At constant pressure, the change in enthalpy (ΔH) is related to the change in internal energy (ΔU) and the pressure-volume work done (PΔV) by the equation ΔH = ΔU + PΔV.
Correct Answer: A — ΔH = ΔU + PΔV.
Learn More →
Q. What is the relationship between enthalpy change and bond dissociation energy?
A.
ΔH is always equal to bond dissociation energy.
B.
ΔH is the sum of bond dissociation energies of reactants minus products.
C.
ΔH is the sum of bond dissociation energies of products minus reactants.
D.
There is no relationship.
Show solution
Solution
The enthalpy change (ΔH) for a reaction can be calculated as the sum of the bond dissociation energies of the reactants minus that of the products.
Correct Answer: B — ΔH is the sum of bond dissociation energies of reactants minus products.
Learn More →
Q. What is the relationship between enthalpy change and heat at constant pressure?
A.
ΔH = Q
B.
ΔH = W
C.
ΔH = Q + W
D.
ΔH = 0
Show solution
Solution
At constant pressure, the change in enthalpy (ΔH) is equal to the heat exchanged (Q).
Correct Answer: A — ΔH = Q
Learn More →
Q. What is the relationship between enthalpy change and the heat capacity at constant pressure (Cp)?
A.
ΔH = Cp * ΔT
B.
ΔH = Cv * ΔT
C.
ΔH = Cp / ΔT
D.
ΔH = ΔT / Cp
Show solution
Solution
The change in enthalpy (ΔH) is directly related to the heat capacity at constant pressure (Cp) and the change in temperature (ΔT) as ΔH = Cp * ΔT.
Correct Answer: A — ΔH = Cp * ΔT
Learn More →
Q. What is the relationship between enthalpy change and the spontaneity of a reaction?
A.
A negative enthalpy change guarantees spontaneity
B.
A positive enthalpy change guarantees spontaneity
C.
Enthalpy change does not affect spontaneity
D.
Spontaneity depends on enthalpy and entropy changes
Show solution
Solution
Spontaneity is determined by both enthalpy and entropy changes, as described by the Gibbs free energy equation.
Correct Answer: D — Spontaneity depends on enthalpy and entropy changes
Learn More →
Q. What is the relationship between Gibbs free energy (G) and spontaneity of a reaction?
A.
G < 0 indicates non-spontaneous reaction
B.
G > 0 indicates spontaneous reaction
C.
G = 0 indicates spontaneous reaction
D.
G < 0 indicates spontaneous reaction
Show solution
Solution
A negative Gibbs free energy change (G < 0) indicates that a reaction is spontaneous.
Correct Answer: D — G < 0 indicates spontaneous reaction
Learn More →
Q. What is the relationship between Gibbs free energy (ΔG) and cell potential (E) in an electrochemical cell?
A.
ΔG = -nFE
B.
ΔG = nFE
C.
ΔG = -E/nF
D.
ΔG = E/nF
Show solution
Solution
The relationship is given by ΔG = -nFE, where n is the number of moles of electrons and F is Faraday's constant.
Correct Answer: A — ΔG = -nFE
Learn More →
Q. What is the relationship between Gibbs free energy and cell potential?
A.
G = -nFE
B.
G = nFE
C.
G = 0
D.
G = nF/E
Show solution
Solution
The relationship is given by the equation G = -nFE, where G is Gibbs free energy, n is moles of electrons, F is Faraday's constant, and E is cell potential.
Correct Answer: A — G = -nFE
Learn More →
Q. What is the relationship between Gibbs free energy change (ΔG) and cell potential (E) in electrochemistry?
A.
ΔG = -nFE
B.
ΔG = nFE
C.
ΔG = -E/nF
D.
ΔG = E/nF
Show solution
Solution
The relationship is given by ΔG = -nFE, where n is the number of moles of electrons and F is Faraday's constant.
Correct Answer: A — ΔG = -nFE
Learn More →
Q. What is the relationship between pressure and temperature in a closed container of gas?
A.
Directly proportional
B.
Inversely proportional
C.
No relationship
D.
Exponential relationship
Show solution
Solution
According to Gay-Lussac's Law, pressure is directly proportional to temperature when volume is held constant.
Correct Answer: A — Directly proportional
Learn More →
Q. What is the relationship between pressure and temperature in a closed system according to Gay-Lussac's Law?
A.
Pressure is directly proportional to volume
B.
Pressure is inversely proportional to temperature
C.
Pressure is directly proportional to temperature
D.
Pressure is independent of temperature
Show solution
Solution
Gay-Lussac's Law states that the pressure of a gas is directly proportional to its absolute temperature when volume is held constant.
Correct Answer: C — Pressure is directly proportional to temperature
Learn More →
Q. What is the relationship between pressure and volume for an ideal gas at constant temperature?
A.
Boyle's Law
B.
Charles's Law
C.
Avogadro's Law
D.
Graham's Law
Show solution
Solution
Boyle's Law states that for a given mass of gas at constant temperature, the pressure of the gas is inversely proportional to its volume (P1V1 = P2V2).
Correct Answer: A — Boyle's Law
Learn More →
Q. What is the relationship between pressure and volume in a gas at constant temperature?
A.
Boyle's Law
B.
Charles's Law
C.
Avogadro's Law
D.
Ideal Gas Law
Show solution
Solution
Boyle's Law states that the pressure of a gas is inversely proportional to its volume at constant temperature (P1V1 = P2V2).
Correct Answer: A — Boyle's Law
Learn More →
Q. What is the relationship between pressure and volume in an ideal gas at constant temperature?
A.
Boyle's Law
B.
Charles's Law
C.
Avogadro's Law
D.
Graham's Law
Show solution
Solution
Boyle's Law states that the pressure of a gas is inversely proportional to its volume at constant temperature (P1V1 = P2V2).
Correct Answer: A — Boyle's Law
Learn More →
Q. What is the relationship between reaction rate and concentration for a first-order reaction?
A.
Rate is proportional to concentration
B.
Rate is proportional to the square of concentration
C.
Rate is independent of concentration
D.
Rate is inversely proportional to concentration
Show solution
Solution
For a first-order reaction, the rate is directly proportional to the concentration of the reactant.
Correct Answer: A — Rate is proportional to concentration
Learn More →
Q. What is the relationship between the rate constant and temperature according to the Arrhenius equation?
A.
Rate constant is independent of temperature
B.
Rate constant increases with temperature
C.
Rate constant decreases with temperature
D.
Rate constant is constant at all temperatures
Show solution
Solution
According to the Arrhenius equation, the rate constant increases with temperature due to the exponential dependence on the negative activation energy divided by temperature.
Correct Answer: B — Rate constant increases with temperature
Learn More →
Showing 1051 to 1080 of 1878 (63 Pages)