Q. What is the osmotic pressure of a solution containing 0.5 moles of glucose in 2 liters of solution at 25 °C? (R = 0.0821 L·atm/(K·mol))
A.
6.13 atm
B.
12.26 atm
C.
3.07 atm
D.
1.54 atm
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Solution
Osmotic pressure (π) = nRT/V = (0.5 moles)(0.0821 L·atm/(K·mol))(298 K) / 2 L = 6.13 atm.
Correct Answer: A — 6.13 atm
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Q. What is the osmotic pressure of a solution containing 0.5 moles of solute in 2 liters of solution at 25 °C? (R = 0.0821 L·atm/(K·mol))
A.
10.25 atm
B.
5.12 atm
C.
2.03 atm
D.
1.23 atm
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Solution
Osmotic pressure (π) = nRT/V = (0.5 moles * 0.0821 * 298) / 2 = 12.21 atm.
Correct Answer: B — 5.12 atm
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Q. What is the osmotic pressure of a solution containing 1 mole of glucose in 2 liters of solution at 25 °C? (R = 0.0821 L·atm/(K·mol))
A.
0.41 atm
B.
0.82 atm
C.
1.23 atm
D.
1.64 atm
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Solution
Osmotic pressure (π) = nRT/V = (1 mol)(0.0821 L·atm/(K·mol))(298 K) / 2 L = 0.82 atm.
Correct Answer: B — 0.82 atm
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Q. What is the osmotic pressure of a solution directly proportional to?
A.
Temperature
B.
Concentration of solute
C.
Volume of solvent
D.
Both A and B
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Solution
Osmotic pressure is directly proportional to both the temperature and the concentration of solute.
Correct Answer: D — Both A and B
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Q. What is the oxidation state of chlorine in NaClO3?
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Solution
In NaClO3, chlorine has an oxidation state of +5.
Correct Answer: C — +5
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Q. What is the oxidation state of nitrogen in NH4+?
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Solution
In NH4+, nitrogen has an oxidation state of -3.
Correct Answer: A — -3
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Q. What is the oxidation state of nitrogen in NO3^-?
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Solution
In NO3^-, nitrogen has an oxidation state of +5.
Correct Answer: B — +5
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Q. What is the oxidation state of sulfur in H2SO4?
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Solution
In H2SO4, the oxidation state of sulfur is +6.
Correct Answer: C — +6
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Q. What is the percentage by mass of a solution containing 20 grams of solute in 180 grams of solution?
A.
10%
B.
20%
C.
15%
D.
25%
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Solution
Percentage by mass = (mass of solute / mass of solution) * 100 = (20 g / (20 g + 180 g)) * 100 = 20%.
Correct Answer: B — 20%
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Q. What is the percentage by mass of a solution containing 5 g of NaCl in 95 g of water?
A.
5%
B.
10%
C.
15%
D.
20%
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Solution
Percentage by mass = (mass of solute / total mass) × 100 = (5 g / (5 g + 95 g)) × 100 = 5%.
Correct Answer: A — 5%
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Q. What is the percentage composition of carbon in glucose (C6H12O6)?
A.
40%
B.
50%
C.
60%
D.
30%
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Solution
Molar mass of glucose = 6(12) + 12(1) + 6(16) = 180 g. Percentage of carbon = (72/180) x 100 = 40%.
Correct Answer: A — 40%
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Q. What is the pH of a 0.01 M HCl solution?
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Solution
The pH of a 0.01 M HCl solution is 2, as HCl is a strong acid and fully dissociates.
Correct Answer: B — 2
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Q. What is the pH of a 0.01 M NaOH solution?
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Solution
For NaOH, which is a strong base, pOH = -log[OH-]. [OH-] = 0.01 M, so pOH = 2. Therefore, pH = 14 - pOH = 14 - 2 = 12.
Correct Answer: A — 12
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Q. What is the pH of a 0.01 M solution of sodium acetate (CH3COONa)?
A.
4.76
B.
7.00
C.
9.24
D.
10.00
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Solution
Sodium acetate is a salt of a weak acid (acetic acid) and a strong base (sodium hydroxide). The pH can be calculated using the formula pH = 7 + 0.5(pKa - log[C]), where pKa of acetic acid is 4.76.
Correct Answer: C — 9.24
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Q. What is the pH of a 0.01 M solution of sodium hydroxide (NaOH)?
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Solution
pH = 14 - pOH; pOH = -log[OH-] = -log(0.01) = 2; pH = 14 - 2 = 12.
Correct Answer: A — 12
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Q. What is the pH of a 0.01 M solution of sulfuric acid (H2SO4)?
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Solution
H2SO4 is a strong acid and dissociates completely, so pH = -log(0.01) = 2.
Correct Answer: A — 1
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Q. What is the pH of a 0.05 M solution of sulfuric acid (H2SO4)?
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Solution
H2SO4 is a strong acid and dissociates completely; [H+] = 0.05 M, so pH = -log(0.05) ≈ 1.3
Correct Answer: B — 1.3
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Q. What is the pH of a 0.1 M NaOH solution?
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Solution
pOH = -log[OH-] = -log(0.1) = 1; pH = 14 - pOH = 14 - 1 = 13
Correct Answer: C — 12
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Q. What is the pH of a 0.1 M solution of acetic acid (CH3COOH) given its Ka is 1.8 x 10^-5?
A.
2.87
B.
4.76
C.
3.87
D.
5.00
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Solution
Using the formula for weak acids, pH = 0.5(pKa - log[C]) = 0.5(4.74 - log(0.1)) = 4.76.
Correct Answer: B — 4.76
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Q. What is the pH of a 0.1 M solution of ammonium chloride (NH4Cl)?
A.
5.1
B.
5.5
C.
6.1
D.
6.5
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Solution
NH4Cl is a salt of a weak base and a strong acid; it hydrolyzes to give H+, resulting in a pH < 7.
Correct Answer: C — 6.1
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Q. What is the pH of a 0.1 M solution of hydrochloric acid (HCl)?
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Solution
The pH of a strong acid like HCl is calculated using the formula pH = -log[H+]. For 0.1 M HCl, [H+] = 0.1 M, so pH = -log(0.1) = 1.
Correct Answer: A — 1
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Q. What is the pH of a 0.1 M solution of potassium hydrogen phthalate (KHP)?
A.
4.0
B.
5.0
C.
6.0
D.
7.0
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Solution
KHP is a weak acid; its pKa is approximately 5.0, so the pH of a 0.1 M solution is around 5.0.
Correct Answer: B — 5.0
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Q. What is the pH of a 0.1 M solution of sodium acetate (CH3COONa)?
A.
4.76
B.
7
C.
9.24
D.
10
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Solution
pH = 7 + 0.5(pKa + log[C]) = 7 + 0.5(4.76 + log(0.1)) = 9.24
Correct Answer: C — 9.24
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Q. What is the pH of a 0.1 M solution of sodium bicarbonate (NaHCO3)?
A.
7.5
B.
8.4
C.
9.0
D.
6.0
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Solution
NaHCO3 is a weak base; its pH is around 8.4.
Correct Answer: B — 8.4
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Q. What is the pH of a buffer solution containing 0.1 M acetic acid and 0.1 M sodium acetate?
A.
4.74
B.
5.74
C.
6.74
D.
7.74
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Solution
Using the Henderson-Hasselbalch equation, pH = pKa + log([A-]/[HA]). Here, pKa ≈ 4.74, so pH = 4.74 + log(1) = 4.74.
Correct Answer: A — 4.74
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Q. What is the pH of a buffer solution containing 0.2 M acetic acid and 0.1 M sodium acetate?
A.
4.76
B.
5.00
C.
5.74
D.
6.00
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Solution
Using the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]) = 4.76 + log(0.1/0.2) = 5.74
Correct Answer: C — 5.74
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Q. What is the pH of a buffer solution made from 0.2 M acetic acid and 0.2 M sodium acetate?
A.
4.76
B.
5.76
C.
6.76
D.
7.76
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Solution
Using the Henderson-Hasselbalch equation, pH = pKa + log([A-]/[HA]) = 4.76.
Correct Answer: A — 4.76
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Q. What is the pH of a neutral solution at 25°C?
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Solution
At 25°C, the pH of a neutral solution is 7.
Correct Answer: B — 7
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Q. What is the pH of a solution formed by mixing equal volumes of 0.1 M HCl and 0.1 M NaOH?
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Solution
HCl and NaOH neutralize each other completely, resulting in a neutral solution with a pH of 7.
Correct Answer: A — 7
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Q. What is the pH of a solution that has a hydrogen ion concentration of 1 x 10^-5 M?
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Solution
pH is calculated as pH = -log[H+]. For [H+] = 1 x 10^-5 M, pH = -log(1 x 10^-5) = 5.
Correct Answer: A — 5
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