Chemistry

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Q. The half-life of a first-order reaction is independent of the initial concentration of the reactant. What is the expression for the half-life (t1/2)? (2022)
  • A. t1/2 = 0.693/k
  • B. t1/2 = k/0.693
  • C. t1/2 = 1/k
  • D. t1/2 = k/2
Q. The half-life of a first-order reaction is independent of which of the following? (2022)
  • A. Initial concentration
  • B. Rate constant
  • C. Temperature
  • D. All of the above
Q. The half-life of a first-order reaction is independent of which parameter?
  • A. Initial concentration
  • B. Rate constant
  • C. Temperature
  • D. All of the above
Q. The heat capacity at constant volume (Cv) for an ideal gas is related to which of the following? (2023)
  • A. Change in internal energy
  • B. Change in enthalpy
  • C. Change in entropy
  • D. Change in Gibbs free energy
Q. The heat capacity at constant volume (Cv) is defined as: (2022)
  • A. The amount of heat required to raise the temperature of a substance by 1°C at constant pressure.
  • B. The amount of heat required to raise the temperature of a substance by 1°C at constant volume.
  • C. The total heat content of a substance.
  • D. The heat required to change the phase of a substance.
Q. The heat capacity of a substance is defined as: (2023)
  • A. The amount of heat required to raise the temperature of one gram by one degree Celsius.
  • B. The amount of heat required to raise the temperature of one mole by one degree Celsius.
  • C. The total heat content of the substance.
  • D. The heat required to change the state of the substance.
Q. The rate of a reaction is defined as the change in concentration of a reactant or product per unit time. What is the general form of the rate equation? (2023)
  • A. Rate = k[A]^n
  • B. Rate = k[A][B]
  • C. Rate = k[A]^2[B]
  • D. Rate = k[A] + [B]
Q. The rate of a reaction is directly proportional to the concentration of one reactant raised to the power of 2. What is the order of the reaction? (2022)
  • A. Zero order
  • B. First order
  • C. Second order
  • D. Third order
Q. The rate of a reaction is directly proportional to the product of the concentrations of the reactants raised to their respective powers. This statement defines:
  • A. Rate law
  • B. Equilibrium constant
  • C. Reaction quotient
  • D. Catalytic efficiency
Q. The rate of a reaction is directly proportional to the product of the concentrations of the reactants raised to their respective powers. This statement defines which law?
  • A. Law of conservation of mass
  • B. Rate law
  • C. Le Chatelier's principle
  • D. Gibbs free energy
Q. The rate of a reaction is given by the equation rate = k[A]^2[B]. What is the overall order of the reaction? (2020)
  • A. 1
  • B. 2
  • C. 3
  • D. 4
Q. The term 'adsorption' refers to: (2022)
  • A. The process of a substance being taken up by a liquid.
  • B. The accumulation of molecules on a surface.
  • C. The mixing of two liquids.
  • D. The dissolution of a solid in a liquid.
Q. The uncertainty principle is associated with which of the following scientists? (2023)
  • A. Bohr
  • B. Heisenberg
  • C. Schrodinger
  • D. Planck
Q. The unit cell of a diamond structure is best described as which of the following? (2020)
  • A. Simple cubic
  • B. Face-centered cubic
  • C. Body-centered cubic
  • D. Hexagonal
Q. What does the term 'enthalpy' (H) represent? (2019)
  • A. Internal energy plus pressure-volume work
  • B. Total energy of the system
  • C. Heat content at constant pressure
  • D. All of the above
Q. What effect does increasing temperature have on the rate of a chemical reaction? (2023)
  • A. Decreases the rate
  • B. Increases the rate
  • C. No effect
  • D. Depends on the reaction
Q. What happens to the equilibrium constant when a reaction is multiplied by a factor? (2023)
  • A. It remains the same
  • B. It is multiplied by the factor
  • C. It is raised to the power of the factor
  • D. It is divided by the factor
Q. What happens to the equilibrium position when a catalyst is added to a reaction at equilibrium? (2023)
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No change
  • D. Increases Kc
Q. What is the balanced equation for the redox reaction between Cr2O7^2- and Fe^2+ in acidic medium? (2020)
  • A. Cr2O7^2- + 6Fe^2+ → 2Cr^3+ + 3Fe^3+
  • B. Cr2O7^2- + 3Fe^2+ → 2Cr^3+ + 3Fe^3+
  • C. Cr2O7^2- + 4Fe^2+ → 2Cr^3+ + 4Fe^3+
  • D. Cr2O7^2- + 2Fe^2+ → 2Cr^3+ + Fe^3+
Q. What is the basic structural unit of lipids? (2020)
  • A. Amino acids
  • B. Nucleotides
  • C. Fatty acids
  • D. Monosaccharides
Q. What is the boiling point elevation for a solution with 0.5 moles of a non-volatile solute in 1 kg of water? (Kb for water = 0.512 °C kg/mol) (2022)
  • A. 0.256 °C
  • B. 0.512 °C
  • C. 1.024 °C
  • D. 0.128 °C
Q. What is the boiling point trend among amines? (2020)
  • A. Amines have lower boiling points than alkanes
  • B. Amines have higher boiling points than alcohols
  • C. Boiling points increase with molecular weight
  • D. All of the above
Q. What is the bond angle in the water molecule (H2O)? (2023)
  • A. 90 degrees
  • B. 104.5 degrees
  • C. 120 degrees
  • D. 180 degrees
Q. What is the bond angle in water (H2O) due to the presence of hydrogen? (2023)
  • A. 90 degrees
  • B. 104.5 degrees
  • C. 120 degrees
  • D. 180 degrees
Q. What is the bond angle in water (H2O) due to the presence of lone pairs on oxygen? (2019)
  • A. 104.5°
  • B. 109.5°
  • C. 120°
  • D. 90°
Q. What is the change in internal energy (ΔU) for an ideal gas during an isothermal process? (2021)
  • A. ΔU = 0
  • B. ΔU = nRT
  • C. ΔU = -nRT
  • D. ΔU = PV
Q. What is the change in internal energy (ΔU) for an ideal gas undergoing an isothermal process? (2021)
  • A. ΔU = 0
  • B. ΔU = Q
  • C. ΔU = W
  • D. ΔU = Q + W
Q. What is the change in internal energy (ΔU) for an isothermal process for an ideal gas? (2021)
  • A. ΔU = 0
  • B. ΔU = nRT
  • C. ΔU = -nRT
  • D. ΔU = PV
Q. What is the change in internal energy (ΔU) for an isothermal process of an ideal gas? (2021)
  • A. ΔU = 0
  • B. ΔU = nRT
  • C. ΔU = -nRT
  • D. ΔU = PV
Q. What is the change in oxidation state of carbon in the reaction C6H12O6 → 2C2H5OH? (2023)
  • A. +1
  • B. 0
  • C. -1
  • D. -2
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