Physical Chemistry - Chemical Kinetics

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Q. For a zero-order reaction, how does the concentration of reactants change over time? (2020)
  • A. Linearly
  • B. Exponentially
  • C. Quadratically
  • D. Logarithmically
Q. The half-life of a first-order reaction is independent of the initial concentration of the reactant. What is the expression for the half-life? (2022)
  • A. t₁/₂ = 0.693/k
  • B. t₁/₂ = k/0.693
  • C. t₁/₂ = 1/k
  • D. t₁/₂ = k/1
Q. The half-life of a first-order reaction is independent of the initial concentration of the reactant. What is the expression for the half-life (t₁/₂)? (2022)
  • A. t₁/₂ = 0.693/k
  • B. t₁/₂ = k/0.693
  • C. t₁/₂ = 1/k
  • D. t₁/₂ = k/1
Q. The half-life of a first-order reaction is independent of the initial concentration. What is the expression for the half-life?
  • A. t₁/₂ = 0.693/k
  • B. t₁/₂ = k/0.693
  • C. t₁/₂ = 1/k
  • D. t₁/₂ = k/1
Q. The half-life of a first-order reaction is independent of the initial concentration of the reactant. What is the expression for the half-life (t1/2)? (2022)
  • A. t1/2 = 0.693/k
  • B. t1/2 = k/0.693
  • C. t1/2 = 1/k
  • D. t1/2 = k/2
Q. The half-life of a first-order reaction is independent of which of the following? (2022)
  • A. Initial concentration
  • B. Rate constant
  • C. Temperature
  • D. All of the above
Q. The half-life of a first-order reaction is independent of which parameter?
  • A. Initial concentration
  • B. Rate constant
  • C. Temperature
  • D. All of the above
Q. The rate of a reaction is defined as the change in concentration of a reactant or product per unit time. What is the general form of the rate equation? (2023)
  • A. Rate = k[A]^n
  • B. Rate = k[A][B]
  • C. Rate = k[A]^2[B]
  • D. Rate = k[A] + [B]
Q. The rate of a reaction is directly proportional to the concentration of one reactant raised to the power of 2. What is the order of the reaction? (2022)
  • A. Zero order
  • B. First order
  • C. Second order
  • D. Third order
Q. The rate of a reaction is directly proportional to the product of the concentrations of the reactants raised to their respective powers. This statement defines:
  • A. Rate law
  • B. Equilibrium constant
  • C. Reaction quotient
  • D. Catalytic efficiency
Q. The rate of a reaction is directly proportional to the product of the concentrations of the reactants raised to their respective powers. This statement defines which law?
  • A. Law of conservation of mass
  • B. Rate law
  • C. Le Chatelier's principle
  • D. Gibbs free energy
Q. The rate of a reaction is given by the equation rate = k[A]^2[B]. What is the overall order of the reaction? (2020)
  • A. 1
  • B. 2
  • C. 3
  • D. 4
Q. What effect does increasing temperature have on the rate of a chemical reaction? (2023)
  • A. Decreases the rate
  • B. Increases the rate
  • C. No effect
  • D. Depends on the reaction
Q. What is the effect of a catalyst on a chemical reaction? (2019)
  • A. Increases activation energy
  • B. Decreases activation energy
  • C. Changes the equilibrium constant
  • D. Has no effect on the reaction rate
Q. Which of the following statements is true regarding the Arrhenius equation? (2023)
  • A. It relates temperature to the rate constant
  • B. It is only applicable to zero-order reactions
  • C. It does not include activation energy
  • D. It is a linear equation
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