Q. What is the effect of increasing the size of the halogen in haloalkanes on the reactivity? (2023)
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A.
Increases reactivity
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B.
Decreases reactivity
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C.
No effect
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D.
Reactivity depends on the solvent
Solution
Increasing the size of the halogen decreases the bond strength, thus increasing the reactivity of haloalkanes in nucleophilic substitution.
Correct Answer: A — Increases reactivity
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Q. What is the main product of the reaction of 1-bromo-2-methylpropane with KOH in ethanol? (2020)
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A.
2-methylpropene
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B.
2-methylpropan-1-ol
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C.
1-bromo-2-methylpropane
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D.
2-bromo-2-methylpropane
Solution
The reaction of 1-bromo-2-methylpropane with KOH in ethanol leads to the formation of 2-methylpropene through an elimination reaction.
Correct Answer: A — 2-methylpropene
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Q. What is the main product when 1-bromopropane is treated with alcoholic KOH? (2021)
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A.
Propene
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B.
1-propanol
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C.
2-propanol
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D.
Bromopropane
Solution
Alcoholic KOH promotes elimination reactions, leading to the formation of propene from 1-bromopropane.
Correct Answer: A — Propene
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Q. What is the main product when 1-bromopropane is treated with magnesium in dry ether? (2019)
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A.
Propane
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B.
Grignard reagent
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C.
Bromopropane
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D.
Propyl alcohol
Solution
The reaction of 1-bromopropane with magnesium in dry ether forms the Grignard reagent, propylmagnesium bromide.
Correct Answer: B — Grignard reagent
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Q. What is the main product when 1-chloropropane is treated with alcoholic KOH? (2019)
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A.
Propene
-
B.
Propan-1-ol
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C.
Propan-2-ol
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D.
Chloropropane
Solution
Alcoholic KOH promotes elimination reactions, leading to the formation of propene from 1-chloropropane.
Correct Answer: A — Propene
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Q. What is the main product when 1-chloropropane is treated with excess alcoholic KOH? (2020)
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A.
Propene
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B.
1-Propanol
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C.
2-Propanol
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D.
Chloropropane
Solution
Excess alcoholic KOH promotes elimination reactions, leading to the formation of propene from 1-chloropropane.
Correct Answer: A — Propene
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Q. What is the product of the reaction between 1-bromobutane and sodium ethoxide in ethanol? (2020)
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A.
Butane
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B.
Ethyl butanoate
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C.
Butyl ethyl ether
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D.
1-Butanol
Solution
The reaction of 1-bromobutane with sodium ethoxide leads to the formation of butyl ethyl ether through an SN2 mechanism.
Correct Answer: C — Butyl ethyl ether
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Q. What type of reaction occurs when 1-bromopropane reacts with sodium cyanide? (2023)
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A.
Elimination
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B.
Substitution
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C.
Addition
-
D.
Redox
Solution
The reaction between 1-bromopropane and sodium cyanide is a nucleophilic substitution reaction, resulting in the formation of propanenitrile.
Correct Answer: B — Substitution
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Q. What type of reaction occurs when 1-bromopropane reacts with sodium ethoxide? (2023)
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A.
Elimination
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B.
Nucleophilic substitution
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C.
Addition
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D.
Oxidation
Solution
The reaction of 1-bromopropane with sodium ethoxide is a nucleophilic substitution reaction where the ethoxide ion replaces the bromine atom.
Correct Answer: B — Nucleophilic substitution
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Q. What type of reaction occurs when 1-chlorobutane is treated with aqueous KOH? (2023)
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A.
Elimination
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B.
Substitution
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C.
Addition
-
D.
Redox
Solution
When 1-chlorobutane is treated with aqueous KOH, a nucleophilic substitution reaction occurs, resulting in the formation of butanol.
Correct Answer: B — Substitution
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Q. What type of reaction occurs when 1-chloropropane reacts with aqueous KOH? (2023)
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A.
Elimination
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B.
Substitution
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C.
Addition
-
D.
Redox
Solution
The reaction of 1-chloropropane with aqueous KOH leads to an elimination reaction, forming propene.
Correct Answer: B — Substitution
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Q. What type of reaction occurs when 1-chloropropane reacts with potassium cyanide? (2019)
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A.
Nucleophilic substitution
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B.
Electrophilic substitution
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C.
Addition reaction
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D.
Elimination reaction
Solution
The reaction between 1-chloropropane and potassium cyanide is a nucleophilic substitution reaction, resulting in the formation of propanenitrile.
Correct Answer: A — Nucleophilic substitution
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Q. What type of reaction occurs when 1-chloropropane reacts with sodium cyanide? (2023)
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A.
Elimination
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B.
Nucleophilic substitution
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C.
Addition
-
D.
Redox
Solution
The reaction between 1-chloropropane and sodium cyanide is a nucleophilic substitution reaction where the cyanide ion replaces the chlorine atom.
Correct Answer: B — Nucleophilic substitution
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Q. What type of reaction occurs when 1-chloropropane reacts with sodium iodide in acetone? (2023)
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A.
Elimination
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B.
Nucleophilic substitution
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C.
Addition
-
D.
Redox
Solution
The reaction is a nucleophilic substitution (S_N2) where iodide ion replaces the chlorine atom.
Correct Answer: B — Nucleophilic substitution
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Q. What type of reaction occurs when 2-bromopropane is treated with aqueous KOH? (2023)
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A.
Elimination
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B.
Substitution
-
C.
Addition
-
D.
Redox
Solution
The reaction of 2-bromopropane with aqueous KOH leads to an elimination reaction, forming propene.
Correct Answer: A — Elimination
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Q. What type of reaction occurs when chlorobenzene is treated with magnesium in dry ether? (2019)
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A.
Grignard reaction
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B.
Nucleophilic substitution
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C.
Electrophilic substitution
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D.
Reduction reaction
Solution
The reaction of chlorobenzene with magnesium in dry ether forms a Grignard reagent, which is a key step in organic synthesis.
Correct Answer: A — Grignard reaction
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Q. Which haloalkane is most likely to undergo elimination reactions? (2023)
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A.
1-bromopropane
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B.
2-bromobutane
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C.
3-bromobutane
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D.
Bromobenzene
Solution
3-bromobutane is more likely to undergo elimination reactions due to the presence of a tertiary carbon.
Correct Answer: C — 3-bromobutane
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Q. Which of the following compounds is an aryl halide? (2019)
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A.
Chloroethane
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B.
Bromobenzene
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C.
Iodobutane
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D.
Chloropropane
Solution
Bromobenzene is an aryl halide as it contains a halogen atom bonded to an aromatic ring.
Correct Answer: B — Bromobenzene
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Q. Which of the following compounds is an example of a haloarene? (2019)
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A.
Chloroethane
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B.
Bromobenzene
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C.
Iodobutane
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D.
Chloropropane
Solution
Bromobenzene is a haloarene as it contains a halogen atom directly attached to an aromatic ring.
Correct Answer: B — Bromobenzene
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Q. Which of the following compounds is least reactive in nucleophilic substitution reactions? (2023)
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A.
1-bromopropane
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B.
2-bromopropane
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C.
3-bromopropane
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D.
Benzyl bromide
Solution
Benzyl bromide is less reactive in nucleophilic substitution due to the resonance stabilization of the benzyl cation formed during the reaction.
Correct Answer: D — Benzyl bromide
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Q. Which of the following compounds is least soluble in water? (2022)
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A.
Chloroethane
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B.
Bromobenzene
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C.
Iodopropane
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D.
Chlorobenzene
Solution
Bromobenzene is least soluble in water due to its non-polar nature and the presence of the aromatic ring.
Correct Answer: B — Bromobenzene
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Q. Which of the following haloalkanes can undergo elimination reaction more readily? (2023)
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A.
1-bromopropane
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B.
2-bromopropane
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C.
3-bromopropane
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D.
Bromobenzene
Solution
Tertiary haloalkanes like 3-bromopropane can undergo elimination reactions more readily due to the stability of the resulting alkene.
Correct Answer: C — 3-bromopropane
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Q. Which of the following haloalkanes can undergo elimination reaction to form an alkene? (2021)
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A.
1-bromopropane
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B.
2-bromobutane
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C.
Bromobenzene
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D.
Chloroethane
Solution
2-bromobutane can undergo elimination to form an alkene due to the presence of a beta-hydrogen.
Correct Answer: B — 2-bromobutane
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Q. Which of the following haloalkanes can undergo elimination to form an alkene? (2021)
-
A.
1-bromopropane
-
B.
2-bromobutane
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C.
Bromobenzene
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D.
Chloroethane
Solution
2-bromobutane can undergo elimination to form an alkene due to the presence of a beta-hydrogen.
Correct Answer: B — 2-bromobutane
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Q. Which of the following is the correct order of reactivity of haloalkanes in nucleophilic substitution reactions? (2023)
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A.
R-I > R-Br > R-Cl > R-F
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B.
R-F > R-Cl > R-Br > R-I
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C.
R-Cl > R-Br > R-I > R-F
-
D.
R-Br > R-I > R-Cl > R-F
Solution
The reactivity of haloalkanes in nucleophilic substitution reactions decreases in the order R-I > R-Br > R-Cl > R-F due to bond strength.
Correct Answer: A — R-I > R-Br > R-Cl > R-F
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