Q. For the reaction N2(g) + 3H2(g) ⇌ 2NH3(g), what is the expression for Kp? (2020)
A.
(P_NH3)^2 / (P_N2)(P_H2)^3
B.
(P_N2)(P_H2)^3 / (P_NH3)^2
C.
(P_NH3)^2 / (P_H2)^3
D.
(P_N2)(P_H2) / (P_NH3)^2
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Solution
Kp is expressed in terms of partial pressures, so for the reaction, Kp = (P_NH3)^2 / (P_N2)(P_H2)^3.
Correct Answer: A — (P_NH3)^2 / (P_N2)(P_H2)^3
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Q. For the reaction N2(g) + 3H2(g) ⇌ 2NH3(g), what is the expression for the equilibrium constant Kp? (2020)
A.
(P_NH3)^2 / (P_N2)(P_H2)^3
B.
(P_N2)(P_H2)^3 / (P_NH3)^2
C.
(P_NH3)^2 (P_N2)(P_H2)^3
D.
(P_N2)(P_H2)^3 (P_NH3)^2
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Solution
Kp is expressed in terms of the partial pressures of the gases involved in the reaction. For this reaction, Kp = (P_NH3)^2 / (P_N2)(P_H2)^3.
Correct Answer: A — (P_NH3)^2 / (P_N2)(P_H2)^3
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Q. For the reaction: 2A(g) + B(g) ⇌ 3C(g), if the volume of the container is decreased, what will be the effect on the equilibrium? (2022)
A.
Shift to the left
B.
Shift to the right
C.
No change
D.
Increase in temperature
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Solution
Decreasing the volume increases the pressure, and the equilibrium will shift towards the side with fewer moles of gas. Here, it shifts to the right, producing more C.
Correct Answer: B — Shift to the right
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Q. For the reaction: 2A(g) + B(g) ⇌ 3C(g), what is the correct expression for the equilibrium constant Kc? (2021)
A.
[C]^3 / ([A]^2[B])
B.
[A]^2[B] / [C]^3
C.
[C]^3 / [A]^2
D.
[B] / [C]^3
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Solution
The equilibrium constant Kc is given by the expression Kc = [C]^3 / ([A]^2[B]), where the concentrations are raised to the power of their coefficients.
Correct Answer: A — [C]^3 / ([A]^2[B])
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Q. For the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g), what happens to the equilibrium position if the volume of the container is decreased? (2020)
A.
Shifts to the left
B.
Shifts to the right
C.
No change
D.
Depends on temperature
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Solution
Decreasing the volume increases the pressure, and according to Le Chatelier's principle, the equilibrium will shift towards the side with fewer moles of gas, which is the right side in this case.
Correct Answer: B — Shifts to the right
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Q. For the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of increasing temperature on the equilibrium if the reaction is exothermic? (2020)
A.
Equilibrium shifts to the right
B.
Equilibrium shifts to the left
C.
No effect on equilibrium
D.
Equilibrium constant increases
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Solution
For an exothermic reaction, increasing the temperature shifts the equilibrium to the left, favoring the reactants.
Correct Answer: B — Equilibrium shifts to the left
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Q. For the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of removing SO3 on the equilibrium? (2020)
A.
The equilibrium will shift to the right
B.
The equilibrium will shift to the left
C.
The equilibrium will remain unchanged
D.
The reaction will stop
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Solution
Removing SO3 will shift the equilibrium to the right to produce more SO3, according to Le Chatelier's principle.
Correct Answer: A — The equilibrium will shift to the right
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Q. For the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g), what will happen if the volume of the container is increased? (2020)
A.
Equilibrium shifts to the right
B.
Equilibrium shifts to the left
C.
No change in equilibrium
D.
Equilibrium shifts to the center
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Solution
Increasing the volume decreases the pressure, and according to Le Chatelier's principle, the equilibrium will shift to the side with more moles of gas, which is the left side in this case.
Correct Answer: B — Equilibrium shifts to the left
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Q. For the reaction: 3A(g) ⇌ 2B(g) + C(g), what is the expression for Kp?
A.
(P_B^2 * P_C) / (P_A^3)
B.
(P_A^3) / (P_B^2 * P_C)
C.
(P_C) / (P_A^3)
D.
(P_B^2) / (P_A^3)
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Solution
The equilibrium constant Kp is expressed as Kp = (P_B^2 * P_C) / (P_A^3).
Correct Answer: A — (P_B^2 * P_C) / (P_A^3)
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Q. For the reaction: A(g) + B(g) ⇌ C(g) + D(g), if the volume of the container is decreased, what will be the effect on the equilibrium? (2023)
A.
Shift to the left
B.
Shift to the right
C.
No effect
D.
Increase the concentration of A
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Solution
Decreasing the volume increases the pressure. According to Le Chatelier's principle, the equilibrium will shift towards the side with fewer moles of gas. If there are more moles of gas on the left side, the equilibrium will shift to the left.
Correct Answer: A — Shift to the left
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Q. For the reaction: A(g) ⇌ B(g) + C(g), if the concentration of A is increased, what will happen to the equilibrium position?
A.
Shift to the left
B.
Shift to the right
C.
No change
D.
Depends on temperature
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Solution
According to Le Chatelier's principle, increasing the concentration of a reactant will shift the equilibrium to the right.
Correct Answer: B — Shift to the right
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Q. For the set E = {1, 2, 3, 4}, how many subsets contain the element 1?
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Solution
If 1 is included, we can choose from the remaining elements {2, 3, 4}, which has 2^3 = 8 subsets.
Correct Answer: C — 12
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Q. For the set E = {1, 2, 3, 4}, how many subsets have exactly 2 elements?
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Solution
The number of ways to choose 2 elements from 4 is given by the combination formula C(4,2) = 6.
Correct Answer: B — 6
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Q. For the set F = {a, b, c}, how many subsets have exactly 2 elements?
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Solution
The subsets with exactly 2 elements are {a, b}, {a, c}, and {b, c}. Total = 3.
Correct Answer: C — 3
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Q. For the vectors A = (1, 0, 0) and B = (0, 1, 0), what is the scalar product A · B?
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Solution
A · B = 1*0 + 0*1 + 0*0 = 0.
Correct Answer: A — 0
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Q. For vectors A = (2, 3) and B = (4, 5), find the scalar product A · B.
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Solution
A · B = 2*4 + 3*5 = 8 + 15 = 23.
Correct Answer: A — 23
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Q. For vectors A = (3, -2, 1) and B = (1, 4, -2), find A · B.
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Solution
A · B = 3*1 + (-2)*4 + 1*(-2) = 3 - 8 - 2 = -7.
Correct Answer: A — -1
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Q. For what value of b is the function f(x) = { x^3 - 3x + b, x < 1; 2x + 1, x >= 1 continuous at x = 1?
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Solution
Setting 1^3 - 3(1) + b = 2(1) + 1 gives b = 2.
Correct Answer: B — 1
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Q. For which of the following diatomic molecules is the bond order equal to 2?
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Solution
F2 has a bond order of 1, while C2 has a bond order of 2.
Correct Answer: D — F2
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Q. For which of the following molecules is the bond order equal to 0?
A.
He2
B.
H2
C.
Li2
D.
Be2
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Solution
He2 has a bond order of 0, as it has equal bonding and antibonding electrons.
Correct Answer: A — He2
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Q. For which of the following molecules is the molecular orbital diagram similar to that of O2?
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Solution
The molecular orbital diagram of F2 is similar to that of O2, with the same energy level arrangement.
Correct Answer: B — F2
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Q. For which of the following pairs of molecules is the bond order the same?
A.
N2 and C2
B.
O2 and F2
C.
B2 and C2
D.
N2 and O2
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Solution
O2 and F2 both have a bond order of 2.
Correct Answer: B — O2 and F2
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Q. For which value of a is the function f(x) = x^2 + ax + 1 differentiable at x = -1?
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Solution
To ensure differentiability at x = -1, we find f'(-1) exists. Setting a = 0 ensures the derivative is defined.
Correct Answer: B — 0
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Q. For which value of a is the function f(x) = x^2 + ax + 1 differentiable everywhere?
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Solution
The function is a polynomial and is differentiable for all real numbers, hence any value of a works.
Correct Answer: B — 0
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Q. For which value of a is the function f(x) = x^2 - ax + 2 differentiable at x = 1?
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Solution
Setting the derivative f'(1) = 0 gives a = 1 for differentiability.
Correct Answer: B — 1
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Q. For which value of a is the function f(x) = x^2 - ax + 4 differentiable at x = 2?
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Solution
f(x) is a polynomial and is differentiable for all a, hence any value of a works.
Correct Answer: A — 0
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Q. For which value of a is the function f(x) = x^3 - 3ax + 2 differentiable at x = 1?
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Solution
Setting f'(1) = 0 gives a = 1, ensuring differentiability at that point.
Correct Answer: B — 1
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Q. For which value of a is the function f(x) = x^3 - 3ax^2 + 3a^2x + 1 differentiable at x = 1?
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Solution
Setting f'(1) = 0 gives a = 1 for differentiability at x = 1.
Correct Answer: B — 1
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Q. For which value of a is the function f(x) = { 2x + a, x < 0; x^2 + 1, x >= 0 continuous at x = 0?
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Solution
Setting a = 1 gives continuity at x = 0.
Correct Answer: B — 0
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Q. For which value of a is the function f(x) = { 3x + a, x < 2; 4x - 1, x >= 2 continuous at x = 2?
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Solution
Setting 3(2) + a = 4(2) - 1 gives a = 1.
Correct Answer: A — -1
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