Physical Chemistry

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Q. Which of the following reactions has a negative enthalpy change?
  • A. Dissolving NaCl in water
  • B. Photosynthesis
  • C. Respiration
  • D. Melting of ice
Q. Which of the following reactions has a positive ΔG at standard conditions?
  • A. Combustion of glucose
  • B. Formation of water from hydrogen and oxygen
  • C. Dissolution of salt in water
  • D. Decomposition of hydrogen peroxide
Q. Which of the following reactions has a positive ΔH and a positive ΔS?
  • A. Combustion of fuels
  • B. Dissolution of salts
  • C. Sublimation of dry ice
  • D. Formation of water from hydrogen and oxygen
Q. Which of the following reactions has the highest enthalpy change?
  • A. Dissolving NaCl in water
  • B. Combustion of propane
  • C. Formation of NH3 from N2 and H2
  • D. Sublimation of dry ice
Q. Which of the following reactions is a redox reaction?
  • A. H2 + Cl2 → 2HCl
  • B. NaOH + HCl → NaCl + H2O
  • C. CaCO3 → CaO + CO2
  • D. C6H12O6 + 6O2 → 6CO2 + 6H2O
Q. Which of the following reactions is expected to have a positive change in entropy?
  • A. N2(g) + 3H2(g) → 2NH3(g)
  • B. C(s) + O2(g) → CO2(g)
  • C. 2H2O(l) → 2H2(g) + O2(g)
  • D. CaCO3(s) → CaO(s) + CO2(g)
Q. Which of the following reactions is likely to have a negative ΔG?
  • A. Combustion of hydrocarbons.
  • B. Formation of ice from water at 0°C.
  • C. Dissolution of salt in water.
  • D. Decomposition of hydrogen peroxide.
Q. Which of the following reactions is spontaneous at all temperatures?
  • A. ΔH < 0 and ΔS < 0
  • B. ΔH > 0 and ΔS > 0
  • C. ΔH < 0 and ΔS > 0
  • D. ΔH > 0 and ΔS < 0
Q. Which of the following reactions will have a negative ΔG at high temperatures?
  • A. Exothermic reactions with negative ΔS
  • B. Endothermic reactions with positive ΔS
  • C. Exothermic reactions with positive ΔS
  • D. Endothermic reactions with negative ΔS
Q. Which of the following represents a physical change?
  • A. Burning wood
  • B. Dissolving sugar in water
  • C. Rusting of iron
  • D. Cooking an egg
Q. Which of the following represents an endothermic reaction?
  • A. Combustion of gasoline
  • B. Dissolving ammonium nitrate in water
  • C. Respiration
  • D. Rusting of iron
Q. Which of the following represents the correct relationship between moles and mass?
  • A. Moles = Mass / Molar Mass
  • B. Mass = Moles x Molar Mass
  • C. Molar Mass = Mass / Moles
  • D. All of the above
Q. Which of the following represents the correct relationship between moles, mass, and molar mass?
  • A. moles = mass × molar mass
  • B. mass = moles × molar mass
  • C. molar mass = mass / moles
  • D. mass = moles / molar mass
Q. Which of the following represents the enthalpy change for a reaction at constant pressure?
  • A. ΔU
  • B. ΔH
  • C. ΔS
  • D. ΔG
Q. Which of the following represents the number of particles in one mole of a substance?
  • A. 6.022 x 10^23
  • B. 3.14 x 10^22
  • C. 1.6 x 10^19
  • D. 9.11 x 10^28
Q. Which of the following salts will produce a basic solution when dissolved in water?
  • A. NaCl
  • B. KNO3
  • C. NH4Cl
  • D. Na2CO3
Q. Which of the following sets of quantum numbers corresponds to a 3p electron?
  • A. n=3, l=0, m_l=0
  • B. n=3, l=1, m_l=1
  • C. n=2, l=1, m_l=0
  • D. n=3, l=2, m_l=0
Q. Which of the following sets of quantum numbers corresponds to an electron in a 4d orbital?
  • A. n=4, l=0, m_l=0
  • B. n=4, l=2, m_l=1
  • C. n=3, l=2, m_l=2
  • D. n=4, l=1, m_l=0
Q. Which of the following sets of quantum numbers is not allowed?
  • A. n=2, l=1, m_l=0
  • B. n=3, l=2, m_l=2
  • C. n=1, l=0, m_l=1
  • D. n=4, l=3, m_l=-3
Q. Which of the following sets of quantum numbers is not possible?
  • A. n=3, l=2, m_l=1
  • B. n=2, l=1, m_l=2
  • C. n=4, l=3, m_l=0
  • D. n=1, l=0, m_l=0
Q. Which of the following solutions has the highest boiling point?
  • A. 0.1 M NaCl
  • B. 0.1 M KCl
  • C. 0.1 M CaCl2
  • D. 0.1 M glucose
Q. Which of the following solutions has the highest concentration?
  • A. 0.1 M NaCl
  • B. 0.2 M KCl
  • C. 0.05 M CaCl2
  • D. 0.3 M MgSO4
Q. Which of the following solutions will have the highest boiling point?
  • A. 0.1 M NaCl
  • B. 0.1 M KCl
  • C. 0.1 M glucose
  • D. 0.1 M MgCl2
Q. Which of the following solutions will have the lowest freezing point?
  • A. 0.1 M NaCl
  • B. 0.1 M KBr
  • C. 0.1 M MgCl2
  • D. 0.1 M glucose
Q. Which of the following solutions will have the lowest vapor pressure?
  • A. 0.1 M NaCl
  • B. 0.1 M KBr
  • C. 0.1 M MgCl2
  • D. 0.1 M glucose
Q. Which of the following species exhibits sp3d hybridization?
  • A. SF4
  • B. XeF2
  • C. NH3
  • D. C2H4
Q. Which of the following species has a bond order of 1?
  • A. N2
  • B. O2
  • C. F2
  • D. C2
Q. Which of the following species has a central atom with sp3 hybridization?
  • A. CCl4
  • B. CO2
  • C. BF3
  • D. H2O
Q. Which of the following species has a linear geometry due to hybridization?
  • A. H2O
  • B. CO2
  • C. NH3
  • D. CH4
Q. Which of the following species has a linear molecular geometry?
  • A. BeCl2
  • B. NH3
  • C. H2O
  • D. CH3Cl
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