Physical Chemistry

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Q. Which of the following is an example of an endothermic reaction?
  • A. Respiration
  • B. Photosynthesis
  • C. Combustion
  • D. Neutralization
Q. Which of the following is an example of physisorption?
  • A. Adsorption of hydrogen on palladium
  • B. Adsorption of water on silica gel
  • C. Adsorption of oxygen on activated charcoal
  • D. Adsorption of ammonia on copper
Q. Which of the following is an extensive property?
  • A. Temperature
  • B. Pressure
  • C. Volume
  • D. Density
Q. Which of the following is NOT a characteristic of adsorption?
  • A. It is a surface phenomenon.
  • B. It is a bulk phenomenon.
  • C. It is exothermic in nature.
  • D. It reaches equilibrium.
Q. Which of the following is NOT a characteristic of chemisorption?
  • A. Reversible
  • B. High heat of adsorption
  • C. Specificity
  • D. Monolayer formation
Q. Which of the following is NOT a characteristic of gases?
  • A. They have no definite shape.
  • B. They are compressible.
  • C. They have a definite volume.
  • D. They fill the container they are in.
Q. Which of the following is NOT a characteristic of liquids?
  • A. Definite volume
  • B. Definite shape
  • C. Incompressible
  • D. Fluidity
Q. Which of the following is NOT a condition for Raoult's Law to be applicable?
  • A. The solution must be ideal.
  • B. The solute must be non-volatile.
  • C. The components must be miscible in all proportions.
  • D. The solution must be at high pressure.
Q. Which of the following is NOT a condition for Raoult's Law to hold true?
  • A. The solution must be ideal.
  • B. The solute must be volatile.
  • C. The solute and solvent must be miscible.
  • D. The temperature must be constant.
Q. Which of the following is NOT a factor affecting solubility?
  • A. Temperature
  • B. Pressure
  • C. Nature of solute and solvent
  • D. Color of solute
Q. Which of the following is NOT a factor affecting the solubility of a solute in a solvent?
  • A. Temperature
  • B. Pressure
  • C. Nature of solute and solvent
  • D. Color of solute
Q. Which of the following is NOT a method to increase the rate of adsorption?
  • A. Increasing temperature
  • B. Increasing surface area
  • C. Increasing pressure
  • D. Decreasing particle size
Q. Which of the following is NOT a postulate of the kinetic molecular theory?
  • A. Gas particles are in constant random motion
  • B. Gas particles have negligible volume
  • C. Gas particles attract each other
  • D. The average kinetic energy of gas particles is proportional to temperature
Q. Which of the following is not a state function?
  • A. Enthalpy
  • B. Internal Energy
  • C. Heat
  • D. Gibbs Free Energy
Q. Which of the following is not a state of matter?
  • A. Solid
  • B. Liquid
  • C. Gas
  • D. Plasma
Q. Which of the following is NOT a type of adsorption isotherm?
  • A. Langmuir
  • B. Freundlich
  • C. BET
  • D. Henry
Q. Which of the following is not an assumption of the kinetic molecular theory?
  • A. Gas particles are in constant motion
  • B. Gas particles have no volume
  • C. Gas particles attract each other
  • D. Collisions between gas particles are elastic
Q. Which of the following is the correct expression for the van der Waals equation?
  • A. (P + a(n/V)^2)(V - nb) = nRT
  • B. (P - a(n/V)^2)(V + nb) = nRT
  • C. PV = nRT + a(n/V)^2
  • D. PV = nRT - nb
Q. Which of the following is the correct unit for measuring the amount of substance?
  • A. Liter
  • B. Gram
  • C. Mole
  • D. Cubic meter
Q. Which of the following is the correct unit for molality?
  • A. mol/L
  • B. mol/kg
  • C. mol/mL
  • D. mol/1000g
Q. Which of the following is the correct unit for molarity?
  • A. mol/L
  • B. mol/kg
  • C. g/L
  • D. g/mol
Q. Which of the following is true about a buffer solution?
  • A. Resists changes in pH
  • B. Has a pH of 7
  • C. Contains only strong acids
  • D. Is always neutral
Q. Which of the following is true about a saturated solution?
  • A. It contains more solute than can dissolve
  • B. It contains less solute than can dissolve
  • C. It is always at boiling point
  • D. It is always at freezing point
Q. Which of the following is true about an exothermic reaction?
  • A. ΔH is positive
  • B. ΔH is negative
  • C. ΔH is zero
  • D. ΔH can be either positive or negative
Q. Which of the following is true about the entropy of a system?
  • A. It always decreases.
  • B. It is a measure of disorder.
  • C. It is independent of temperature.
  • D. It can never increase.
Q. Which of the following is true about the Freundlich adsorption isotherm?
  • A. It applies only to monolayer adsorption
  • B. It is applicable to heterogeneous surfaces
  • C. It assumes a fixed number of adsorption sites
  • D. It is a linear isotherm
Q. Which of the following is true about the Gibbs free energy change (ΔG) for a spontaneous process?
  • A. ΔG > 0
  • B. ΔG < 0
  • C. ΔG = 0
  • D. ΔG is always positive
Q. Which of the following is true about the Gibbs free energy change (ΔG)?
  • A. ΔG < 0 indicates a spontaneous process
  • B. ΔG > 0 indicates a spontaneous process
  • C. ΔG = 0 indicates a non-spontaneous process
  • D. ΔG is always positive
Q. Which of the following is true about the heat capacity of a substance?
  • A. It is always constant
  • B. It depends on the amount of substance
  • C. It is independent of temperature
  • D. It is the same for all substances
Q. Which of the following is true for an endothermic reaction?
  • A. Heat is released
  • B. ΔH is negative
  • C. ΔH is positive
  • D. The reaction is spontaneous
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