Thermodynamics

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Q. What is the Gibbs free energy change for a spontaneous process?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Undefined
Q. What is the relationship between enthalpy (H), internal energy (U), and pressure-volume work (PV)?
  • A. H = U + PV
  • B. H = U - PV
  • C. H = U * PV
  • D. H = U / PV
Q. What is the relationship between enthalpy and internal energy?
  • A. H = U + PV
  • B. H = U - PV
  • C. H = U * PV
  • D. H = U / PV
Q. What is the relationship between enthalpy change and internal energy change at constant pressure?
  • A. ΔH = ΔU + PΔV
  • B. ΔH = ΔU - PΔV
  • C. ΔH = ΔU
  • D. ΔH = PΔV
Q. What is the relationship between entropy and spontaneity of a process?
  • A. Higher entropy means the process is non-spontaneous.
  • B. Lower entropy means the process is spontaneous.
  • C. Higher entropy generally indicates a spontaneous process.
  • D. Entropy has no relation to spontaneity.
Q. What is the relationship between entropy and temperature?
  • A. Entropy increases with decreasing temperature
  • B. Entropy decreases with increasing temperature
  • C. Entropy increases with increasing temperature
  • D. Entropy is independent of temperature
Q. What is the relationship between Gibbs Free Energy and spontaneity?
  • A. ΔG < 0 indicates non-spontaneous reactions.
  • B. ΔG = 0 indicates spontaneous reactions.
  • C. ΔG > 0 indicates spontaneous reactions.
  • D. ΔG < 0 indicates spontaneous reactions.
Q. What is the relationship between Gibbs Free Energy and the equilibrium constant (K)?
  • A. ΔG = -RT ln(K)
  • B. ΔG = RT ln(K)
  • C. ΔG = KRT
  • D. ΔG = K - RT
Q. What is the relationship between heat capacity at constant pressure (C_p) and at constant volume (C_v)?
  • A. C_p = C_v
  • B. C_p > C_v
  • C. C_p < C_v
  • D. C_p = 0
Q. What is the relationship between heat capacity at constant pressure (C_p) and heat capacity at constant volume (C_v)?
  • A. C_p = C_v
  • B. C_p > C_v
  • C. C_p < C_v
  • D. C_p = 2C_v
Q. What is the relationship between ΔG and equilibrium constant K?
  • A. ΔG = -RT ln K
  • B. ΔG = RT ln K
  • C. ΔG = KRT
  • D. ΔG = K/R
Q. What is the relationship between ΔG and the equilibrium constant (K)?
  • A. ΔG = -RT ln(K)
  • B. ΔG = RT ln(K)
  • C. ΔG = KRT
  • D. ΔG = K - RT
Q. What is the relationship between ΔG, ΔH, and ΔS at constant temperature?
  • A. ΔG = ΔH + TΔS
  • B. ΔG = ΔH - TΔS
  • C. ΔG = TΔS - ΔH
  • D. ΔG = ΔH/ΔS
Q. What is the relationship between ΔH and ΔG at equilibrium?
  • A. ΔG = 0
  • B. ΔH = 0
  • C. ΔG = ΔH
  • D. ΔG = ΔH + TΔS
Q. What is the relationship between ΔH and ΔU for a reaction at constant pressure?
  • A. ΔH = ΔU + PΔV
  • B. ΔH = ΔU - PΔV
  • C. ΔH = ΔU
  • D. ΔH = PΔV
Q. What is the significance of a negative ΔG in biochemical reactions?
  • A. It indicates the reaction is reversible.
  • B. It indicates the reaction is spontaneous.
  • C. It indicates the reaction is at equilibrium.
  • D. It indicates the reaction requires energy.
Q. What is the significance of the Gibbs Free Energy in chemical thermodynamics?
  • A. It predicts the direction of a reaction.
  • B. It measures the heat of reaction.
  • C. It indicates the concentration of reactants.
  • D. It determines the rate of reaction.
Q. What is the significance of the Gibbs Free Energy of formation (ΔGf°)?
  • A. It indicates the stability of a compound.
  • B. It is the energy required to form a compound from its elements.
  • C. It is always negative.
  • D. It is temperature dependent.
Q. What is the standard enthalpy change for the formation of a compound?
  • A. ΔHf
  • B. ΔHc
  • C. ΔHrxn
  • D. ΔHsol
Q. What is the standard enthalpy change for the formation of an element in its standard state?
  • A. Zero
  • B. Positive
  • C. Negative
  • D. Depends on the element
Q. What is the standard enthalpy change for the formation of water from its elements?
  • A. -285.83 kJ/mol
  • B. -241.82 kJ/mol
  • C. -393.5 kJ/mol
  • D. -572.4 kJ/mol
Q. What is the standard enthalpy change for the reaction 2H2(g) + O2(g) → 2H2O(l)?
  • A. -285.83 kJ/mol
  • B. -241.82 kJ/mol
  • C. -572.4 kJ/mol
  • D. -1000 kJ/mol
Q. What is the standard enthalpy change of formation for a substance?
  • A. The enthalpy change when one mole of a compound is formed from its elements in their standard states.
  • B. The enthalpy change when one mole of a substance is completely burned in oxygen.
  • C. The enthalpy change when one mole of a substance is dissolved in water.
  • D. The enthalpy change when one mole of a gas is compressed to a smaller volume.
Q. What is the standard enthalpy change of formation for elements in their standard state?
  • A. 0 kJ/mol
  • B. 100 kJ/mol
  • C. 298 kJ/mol
  • D. 1 kJ/mol
Q. What is the standard enthalpy change of formation for water (H2O) at 25°C?
  • A. -285.83 kJ/mol
  • B. -241.82 kJ/mol
  • C. -393.5 kJ/mol
  • D. -241.0 kJ/mol
Q. What is the standard entropy change (ΔS°) for the reaction: 2 SO2(g) + O2(g) → 2 SO3(g)?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Cannot be determined
Q. What is the standard entropy change (ΔS°) for the reaction: 2H2(g) + O2(g) → 2H2O(g)?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Cannot be determined
Q. What is the standard entropy change (ΔS°) for the reaction: 2SO2(g) + O2(g) → 2SO3(g)?
  • A. Increases
  • B. Decreases
  • C. Remains constant
  • D. Cannot be determined
Q. What is the standard Gibbs Free Energy change (ΔG°) for a reaction at standard conditions?
  • A. Always zero
  • B. Depends on the reaction
  • C. Is a constant value
  • D. Is always positive
Q. What is the standard molar entropy of a substance?
  • A. Entropy at 0 K
  • B. Entropy at 25 °C and 1 atm
  • C. Entropy at boiling point
  • D. Entropy at melting point
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