Thermodynamics

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Q. Which of the following is a unit of enthalpy?
  • A. Joules
  • B. Calories
  • C. Kilojoules
  • D. All of the above
Q. Which of the following is an example of an endothermic reaction?
  • A. Respiration
  • B. Photosynthesis
  • C. Combustion
  • D. Neutralization
Q. Which of the following is an extensive property?
  • A. Temperature
  • B. Pressure
  • C. Volume
  • D. Density
Q. Which of the following is true about the entropy of a system?
  • A. It always decreases.
  • B. It is a measure of disorder.
  • C. It is independent of temperature.
  • D. It can never increase.
Q. Which of the following is true about the heat capacity of a substance?
  • A. It is always constant
  • B. It depends on the amount of substance
  • C. It is independent of temperature
  • D. It is the same for all substances
Q. Which of the following is true for an endothermic reaction?
  • A. Heat is released
  • B. ΔH is negative
  • C. ΔH is positive
  • D. The reaction is spontaneous
Q. Which of the following processes has a negative ΔG?
  • A. Melting of ice at 0°C.
  • B. Freezing of water at 0°C.
  • C. Dissolving salt in water.
  • D. Sublimation of dry ice.
Q. Which of the following processes has a positive ΔG?
  • A. Combustion of fuels
  • B. Dissolution of salts in water
  • C. Photosynthesis
  • D. Respiration
Q. Which of the following processes is associated with a positive change in entropy?
  • A. Condensation of steam
  • B. Sublimation of dry ice
  • C. Freezing of water
  • D. Compression of gas
Q. Which of the following processes is associated with an increase in entropy?
  • A. Freezing of water
  • B. Condensation of steam
  • C. Sublimation of dry ice
  • D. Melting of ice
Q. Which of the following processes is characterized by constant pressure?
  • A. Isothermal
  • B. Isochoric
  • C. Isobaric
  • D. Adiabatic
Q. Which of the following processes is endothermic and results in an increase in entropy?
  • A. Dissolving salt in water
  • B. Combustion of methane
  • C. Condensation of steam
  • D. Freezing of water
Q. Which of the following processes is endothermic?
  • A. Combustion of fuels
  • B. Dissolving ammonium nitrate in water
  • C. Respiration
  • D. Condensation of steam
Q. Which of the following processes is exothermic?
  • A. Melting of ice
  • B. Dissolving ammonium nitrate in water
  • C. Combustion of methane
  • D. Evaporation of water
Q. Which of the following processes is expected to have the largest increase in entropy?
  • A. Dissolving salt in water
  • B. Melting ice
  • C. Boiling water
  • D. Sublimation of solid iodine
Q. Which of the following processes is expected to have the largest positive change in entropy?
  • A. Dissolving salt in water
  • B. Condensing steam
  • C. Melting ice
  • D. Combining hydrogen and oxygen gases
Q. Which of the following processes is irreversible and leads to an increase in entropy?
  • A. Reversible isothermal expansion
  • B. Free expansion of gas
  • C. Isothermal compression
  • D. Adiabatic expansion
Q. Which of the following processes is isothermal?
  • A. Heating a gas in a closed container
  • B. Compressing a gas without heat exchange
  • C. Allowing a gas to expand slowly while maintaining constant temperature
  • D. Cooling a gas in a closed container
Q. Which of the following processes is spontaneous at constant temperature and pressure?
  • A. Decreasing entropy
  • B. Increasing entropy
  • C. Constant entropy
  • D. None of the above
Q. Which of the following processes results in an increase in entropy?
  • A. Isothermal compression
  • B. Adiabatic expansion
  • C. Isobaric heating
  • D. All of the above
Q. Which of the following reactions has a negative enthalpy change?
  • A. Dissolving NaCl in water
  • B. Photosynthesis
  • C. Respiration
  • D. Melting of ice
Q. Which of the following reactions has a positive ΔG at standard conditions?
  • A. Combustion of glucose
  • B. Formation of water from hydrogen and oxygen
  • C. Dissolution of salt in water
  • D. Decomposition of hydrogen peroxide
Q. Which of the following reactions has a positive ΔH and a positive ΔS?
  • A. Combustion of fuels
  • B. Dissolution of salts
  • C. Sublimation of dry ice
  • D. Formation of water from hydrogen and oxygen
Q. Which of the following reactions has the highest enthalpy change?
  • A. Dissolving NaCl in water
  • B. Combustion of propane
  • C. Formation of NH3 from N2 and H2
  • D. Sublimation of dry ice
Q. Which of the following reactions is expected to have a positive change in entropy?
  • A. N2(g) + 3H2(g) → 2NH3(g)
  • B. C(s) + O2(g) → CO2(g)
  • C. 2H2O(l) → 2H2(g) + O2(g)
  • D. CaCO3(s) → CaO(s) + CO2(g)
Q. Which of the following reactions is likely to have a negative ΔG?
  • A. Combustion of hydrocarbons.
  • B. Formation of ice from water at 0°C.
  • C. Dissolution of salt in water.
  • D. Decomposition of hydrogen peroxide.
Q. Which of the following reactions is spontaneous at all temperatures?
  • A. ΔH < 0 and ΔS < 0
  • B. ΔH > 0 and ΔS > 0
  • C. ΔH < 0 and ΔS > 0
  • D. ΔH > 0 and ΔS < 0
Q. Which of the following reactions will have a negative ΔG at high temperatures?
  • A. Exothermic reactions with negative ΔS
  • B. Endothermic reactions with positive ΔS
  • C. Exothermic reactions with positive ΔS
  • D. Endothermic reactions with negative ΔS
Q. Which of the following represents the enthalpy change for a reaction at constant pressure?
  • A. ΔU
  • B. ΔH
  • C. ΔS
  • D. ΔG
Q. Which of the following statements about enthalpy is true?
  • A. Enthalpy is an extensive property.
  • B. Enthalpy is an intensive property.
  • C. Enthalpy cannot be measured directly.
  • D. Enthalpy is always positive.
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