Thermodynamics

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Q. What is the unit of enthalpy?
  • A. Joules per mole (J/mol)
  • B. Calories per mole (cal/mol)
  • C. Both A and B
  • D. Liters per mole (L/mol)
Q. What is the unit of entropy?
  • A. J/mol·K
  • B. J/K
  • C. K
  • D. J/mol
Q. What is the work done by a gas during an isothermal expansion from volume Vi to Vf?
  • A. nRT ln(Vf/Vi)
  • B. nR(Tf - Ti)
  • C. Zero
  • D. nRT
Q. What is the work done by an ideal gas during an isothermal expansion from volume Vi to Vf?
  • A. nRT ln(Vf/Vi)
  • B. nR(Tf - Ti)
  • C. Zero
  • D. nRT
Q. Which factor does NOT affect the Gibbs Free Energy of a reaction?
  • A. Temperature
  • B. Pressure
  • C. Concentration of reactants
  • D. Nature of the solvent
Q. Which factor does NOT affect the Gibbs Free Energy of a system?
  • A. Temperature
  • B. Pressure
  • C. Concentration of reactants
  • D. Nature of the solvent
Q. Which law states that energy cannot be created or destroyed?
  • A. Zeroth law
  • B. First law
  • C. Second law
  • D. Third law
Q. Which law states that the total enthalpy change for a reaction is the same, regardless of the number of steps taken?
  • A. First Law of Thermodynamics
  • B. Second Law of Thermodynamics
  • C. Hess's Law
  • D. Gibbs Free Energy
Q. Which law states that the total enthalpy change for a reaction is the same, regardless of the number of steps in the reaction?
  • A. First Law of Thermodynamics
  • B. Second Law of Thermodynamics
  • C. Hess's Law
  • D. Gibbs Free Energy
Q. Which law states that the total entropy of an isolated system can never decrease over time?
  • A. Zeroth Law
  • B. First Law
  • C. Second Law
  • D. Third Law
Q. Which of the following conditions will favor the spontaneity of a reaction?
  • A. High ΔH and low ΔS
  • B. Low ΔH and high ΔS
  • C. High ΔH and high ΔS
  • D. Low ΔH and low ΔS
Q. Which of the following conditions will lead to a decrease in Gibbs Free Energy?
  • A. Increasing temperature for an exothermic reaction.
  • B. Decreasing entropy.
  • C. Increasing pressure for a gas-phase reaction.
  • D. Increasing ΔH.
Q. Which of the following conditions will lead to a negative ΔG?
  • A. High temperature and low ΔH
  • B. Low temperature and high ΔH
  • C. High temperature and high ΔS
  • D. Low temperature and low ΔS
Q. Which of the following conditions will lead to a positive ΔG?
  • A. High temperature and low entropy.
  • B. Low temperature and high enthalpy.
  • C. High temperature and high entropy.
  • D. Low temperature and low enthalpy.
Q. Which of the following conditions will lead to a spontaneous reaction?
  • A. ΔH > 0 and ΔS < 0
  • B. ΔH < 0 and ΔS > 0
  • C. ΔH > 0 and ΔS > 0
  • D. ΔH < 0 and ΔS < 0
Q. Which of the following equations relates Gibbs Free Energy to enthalpy and entropy?
  • A. ΔG = ΔH - TΔS
  • B. ΔG = TΔS - ΔH
  • C. ΔG = ΔH + TΔS
  • D. ΔG = ΔH / T + ΔS
Q. Which of the following expressions correctly relates ΔG, ΔH, and ΔS?
  • A. ΔG = ΔH + TΔS
  • B. ΔG = ΔH - TΔS
  • C. ΔG = TΔS - ΔH
  • D. ΔG = ΔH + ΔS
Q. Which of the following factors does NOT affect Gibbs Free Energy?
  • A. Temperature
  • B. Pressure
  • C. Concentration of reactants
  • D. Nature of the solvent
Q. Which of the following factors does NOT affect the enthalpy change of a reaction?
  • A. Nature of reactants
  • B. Temperature
  • C. Pressure
  • D. Pathway of the reaction
Q. Which of the following factors does NOT affect the entropy of a system?
  • A. Temperature
  • B. Volume
  • C. Pressure
  • D. Nature of the substance
Q. Which of the following factors does NOT affect the Gibbs Free Energy of a system?
  • A. Temperature
  • B. Pressure
  • C. Concentration of reactants
  • D. Nature of the solvent
Q. Which of the following has the highest enthalpy of formation?
  • A. O2(g)
  • B. H2(g)
  • C. C(s)
  • D. CO2(g)
Q. Which of the following has the highest entropy at 25°C?
  • A. Ice
  • B. Water
  • C. Steam
  • D. All have the same entropy
Q. Which of the following has the highest entropy at 298 K?
  • A. Ice (solid H2O)
  • B. Liquid water (H2O)
  • C. Water vapor (H2O(g))
  • D. None of the above
Q. Which of the following has the highest entropy at room temperature?
  • A. Solid NaCl
  • B. Liquid water
  • C. Water vapor
  • D. Ice
Q. Which of the following has the highest entropy?
  • A. Ice at 0 °C
  • B. Water at 0 °C
  • C. Water vapor at 100 °C
  • D. Water at 100 °C
Q. Which of the following has the highest standard molar entropy (S°) at 298 K?
  • A. H2(g)
  • B. O2(g)
  • C. N2(g)
  • D. H2O(l)
Q. Which of the following is a correct expression for Gibbs Free Energy?
  • A. ΔG = ΔH + TΔS
  • B. ΔG = ΔH - TΔS
  • C. ΔG = TΔS - ΔH
  • D. ΔG = ΔS - ΔH
Q. Which of the following is a correct unit for Gibbs Free Energy?
  • A. Joules per mole (J/mol)
  • B. Kilojoules (kJ)
  • C. Calories (cal)
  • D. All of the above
Q. Which of the following is a state function?
  • A. Work
  • B. Heat
  • C. Enthalpy
  • D. All of the above
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