Thermodynamics

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Q. What is the change in enthalpy for an isothermal process?
  • A. Zero
  • B. Positive
  • C. Negative
  • D. Depends on the system
Q. What is the change in entropy when 1 mole of an ideal gas expands isothermally and reversibly from volume V1 to V2?
  • A. R ln(V2/V1)
  • B. R (V2 - V1)
  • C. R (V1/V2)
  • D. 0
Q. What is the change in entropy when 1 mole of an ideal gas expands isothermally from volume V1 to V2?
  • A. R ln(V2/V1)
  • B. R (V2 - V1)
  • C. R (V1/V2)
  • D. 0
Q. What is the effect of increasing temperature on a reaction with a negative ΔH and positive ΔS?
  • A. It makes ΔG more negative.
  • B. It makes ΔG less negative.
  • C. It has no effect on ΔG.
  • D. It makes ΔG positive.
Q. What is the effect of increasing temperature on a reaction with ΔH > 0 and ΔS < 0?
  • A. Increases spontaneity
  • B. Decreases spontaneity
  • C. No effect on spontaneity
  • D. Makes it spontaneous at high temperatures
Q. What is the effect of increasing temperature on the entropy of a substance?
  • A. Entropy decreases
  • B. Entropy increases
  • C. Entropy remains constant
  • D. Entropy becomes zero
Q. What is the effect of increasing temperature on the entropy of a system?
  • A. Increases entropy
  • B. Decreases entropy
  • C. No effect
  • D. Depends on the system
Q. What is the effect of increasing temperature on the equilibrium constant of an exothermic reaction?
  • A. Increases
  • B. Decreases
  • C. Remains the same
  • D. Becomes zero
Q. What is the effect of increasing temperature on the equilibrium constant of an endothermic reaction?
  • A. Increases
  • B. Decreases
  • C. No effect
  • D. Depends on the reaction
Q. What is the effect of temperature on the entropy of a substance?
  • A. Entropy decreases with increasing temperature.
  • B. Entropy increases with increasing temperature.
  • C. Entropy remains constant with temperature.
  • D. Temperature has no effect on entropy.
Q. What is the enthalpy change for the formation of 1 mole of CO2 from its elements in their standard states?
  • A. -393.5 kJ/mol
  • B. -285.8 kJ/mol
  • C. 0 kJ/mol
  • D. 100 kJ/mol
Q. What is the enthalpy change for the formation of water from hydrogen and oxygen?
  • A. It is positive.
  • B. It is negative.
  • C. It is zero.
  • D. It is undefined.
Q. What is the enthalpy change for the reaction 2Na + Cl2 → 2NaCl?
  • A. -411 kJ
  • B. -240 kJ
  • C. 0 kJ
  • D. 411 kJ
Q. What is the enthalpy change for the reaction: 2H2(g) + O2(g) → 2H2O(g)?
  • A. It is positive.
  • B. It is negative.
  • C. It is zero.
  • D. It is dependent on temperature.
Q. What is the enthalpy change for the reaction: 2H2(g) + O2(g) → 2H2O(l)?
  • A. -571.6 kJ
  • B. -285.8 kJ
  • C. 0 kJ
  • D. 285.8 kJ
Q. What is the enthalpy change for the reaction: C(s) + O2(g) -> CO2(g)?
  • A. -393.5 kJ/mol
  • B. -241.8 kJ/mol
  • C. 0 kJ/mol
  • D. 285.8 kJ/mol
Q. What is the enthalpy change for the reaction: C(s) + O2(g) → CO2(g)?
  • A. -393.5 kJ/mol
  • B. -241.8 kJ/mol
  • C. 0 kJ/mol
  • D. 285.8 kJ/mol
Q. What is the enthalpy change for the reaction: CaCO3(s) → CaO(s) + CO2(g)?
  • A. It is an endothermic reaction.
  • B. It is an exothermic reaction.
  • C. It has no enthalpy change.
  • D. It is spontaneous at all temperatures.
Q. What is the enthalpy change for the reaction: N2(g) + 3H2(g) → 2NH3(g)?
  • A. It is always positive.
  • B. It is always negative.
  • C. It can be either positive or negative depending on conditions.
  • D. It is zero.
Q. What is the enthalpy change when 1 mole of NaCl is dissolved in water?
  • A. -3.87 kJ
  • B. 0 kJ
  • C. +3.87 kJ
  • D. -7.0 kJ
Q. What is the enthalpy change when 1 mole of water vapor condenses to liquid water?
  • A. It is positive.
  • B. It is negative.
  • C. It is zero.
  • D. It is dependent on pressure.
Q. What is the entropy change for a system that undergoes a phase transition at constant temperature?
  • A. ΔS = 0
  • B. ΔS = Q/T
  • C. ΔS = T/Q
  • D. ΔS = Q + T
Q. What is the entropy change for an ideal gas during an isothermal expansion?
  • A. Zero
  • B. nR ln(Vf/Vi)
  • C. nC_v ln(Tf/Ti)
  • D. nC_p ln(Tf/Ti)
Q. What is the entropy change for the isothermal expansion of an ideal gas from volume V1 to V2 at temperature T?
  • A. R ln(V2/V1)
  • B. R (V2 - V1)/T
  • C. 0
  • D. R (V1/V2)
Q. What is the entropy change for the mixing of two ideal gases at constant temperature?
  • A. 0
  • B. R ln(2)
  • C. R ln(V1/V2)
  • D. R ln(V1*V2)
Q. What is the entropy change when 1 mole of an ideal gas is heated at constant volume from temperature T1 to T2?
  • A. R ln(T2/T1)
  • B. R (T2 - T1)
  • C. 0
  • D. R (T1/T2)
Q. What is the entropy change when 1 mole of an ideal gas is heated at constant volume?
  • A. 0
  • B. R ln(T2/T1)
  • C. R (T2 - T1)
  • D. R (T1/T2)
Q. What is the entropy change when 1 mole of ice at 0°C is converted to water at 0°C?
  • A. 0 J/K
  • B. R ln(2)
  • C. R
  • D. Positive value
Q. What is the entropy change when 2 moles of an ideal gas are compressed isothermally from volume V2 to V1?
  • A. -R ln(V1/V2)
  • B. R ln(V1/V2)
  • C. 0
  • D. R (V2 - V1)
Q. What is the Gibbs Free Energy change (ΔG) at equilibrium?
  • A. ΔG < 0
  • B. ΔG = 0
  • C. ΔG > 0
  • D. ΔG = ΔH - TΔS
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