Q. Which of the following statements is true for an adiabatic process? (2022) 2022
A.
Heat is exchanged with the surroundings
B.
Work done is zero
C.
Temperature changes
D.
Pressure remains constant
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Solution
In an adiabatic process, there is no heat exchange with the surroundings, and the temperature of the system changes due to work done on or by the system.
Correct Answer: C — Temperature changes
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Q. Which of the following statements is true for an endothermic reaction?
A.
ΔH is negative
B.
ΔH is positive
C.
Activation energy is zero
D.
It occurs spontaneously
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Solution
In an endothermic reaction, the enthalpy change (ΔH) is positive as heat is absorbed.
Correct Answer: B — ΔH is positive
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Q. Which of the following statements is true for an exothermic reaction?
A.
ΔH is positive
B.
ΔH is negative
C.
ΔH = 0
D.
ΔH is undefined
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Solution
In an exothermic reaction, heat is released, so ΔH is negative.
Correct Answer: B — ΔH is negative
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Q. Which of the following statements is true for an ideal gas?
A.
The internal energy depends on temperature only
B.
The internal energy depends on volume and pressure
C.
The internal energy is constant at all temperatures
D.
The internal energy is independent of temperature
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Solution
For an ideal gas, the internal energy depends only on temperature, not on volume or pressure.
Correct Answer: A — The internal energy depends on temperature only
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Q. Which of the following statements is true for an isobaric process?
A.
Pressure remains constant
B.
Volume remains constant
C.
Temperature remains constant
D.
Internal energy remains constant
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Solution
In an isobaric process, the pressure remains constant.
Correct Answer: A — Pressure remains constant
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Q. Which of the following statements is true for an isochoric process? (2023)
A.
Volume remains constant
B.
Pressure remains constant
C.
Temperature remains constant
D.
Heat is absorbed
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Solution
In an isochoric process, the volume of the system remains constant.
Correct Answer: A — Volume remains constant
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Q. Which of the following statements is true for real gases?
A.
They obey the ideal gas law at all conditions
B.
They have no volume
C.
They experience intermolecular forces
D.
They have a fixed shape
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Solution
Real gases experience intermolecular forces, which causes deviations from ideal behavior.
Correct Answer: C — They experience intermolecular forces
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Q. Which of the following statements is true for the complex [Fe(CN)6]3-? (2023)
A.
It is a high-spin complex
B.
It is a low-spin complex
C.
It has a coordination number of 4
D.
It is paramagnetic
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Solution
The complex [Fe(CN)6]3- is a low-spin complex due to the strong field nature of CN- ligands, resulting in paired electrons.
Correct Answer: B — It is a low-spin complex
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Q. Which of the following statements is true regarding a balanced Wheatstone bridge?
A.
The total resistance is minimized.
B.
The potential difference across the galvanometer is zero.
C.
The current through the resistors is equal.
D.
The resistors must be of equal value.
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Solution
In a balanced Wheatstone bridge, the potential difference across the galvanometer is zero, indicating no current flow.
Correct Answer: B — The potential difference across the galvanometer is zero.
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Q. Which of the following statements is true regarding a catalyst?
A.
Increases activation energy
B.
Lowers activation energy
C.
Changes the equilibrium constant
D.
Is consumed in the reaction
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Solution
A catalyst lowers the activation energy of a reaction, thereby increasing the rate without being consumed.
Correct Answer: B — Lowers activation energy
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Q. Which of the following statements is true regarding a double-elimination tournament?
A.
A team is eliminated after one loss.
B.
A team must lose twice to be eliminated.
C.
All teams play the same number of matches.
D.
The tournament ends after a fixed number of matches.
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Solution
In a double-elimination tournament, a team must lose twice to be eliminated, allowing for a second chance.
Correct Answer: B — A team must lose twice to be eliminated.
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Q. Which of the following statements is true regarding a potentiometer?
A.
It can measure both AC and DC voltages
B.
It can only measure DC voltages
C.
It can only measure AC voltages
D.
It cannot measure voltages
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Solution
A potentiometer can measure both AC and DC voltages, but it is primarily used for DC measurements due to its principle of operation.
Correct Answer: B — It can only measure DC voltages
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Q. Which of the following statements is true regarding a saturated solution?
A.
It contains more solute than solvent.
B.
It is in dynamic equilibrium.
C.
It can dissolve more solute.
D.
It is always at room temperature.
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Solution
A saturated solution is in dynamic equilibrium where the rate of dissolution equals the rate of crystallization.
Correct Answer: B — It is in dynamic equilibrium.
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Q. Which of the following statements is true regarding a Wheatstone bridge?
A.
It can only be used for DC circuits.
B.
It can only be used for AC circuits.
C.
It can be used for both AC and DC circuits.
D.
It is only used for measuring voltage.
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Solution
A Wheatstone bridge can be used for both AC and DC circuits to measure resistance.
Correct Answer: C — It can be used for both AC and DC circuits.
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Q. Which of the following statements is true regarding adsorption isotherms? (2020)
A.
They describe the relationship between pressure and volume.
B.
They describe the relationship between temperature and solubility.
C.
They describe the relationship between the amount of adsorbate and its pressure at constant temperature.
D.
They describe the relationship between the surface area and the mass of adsorbent.
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Solution
Adsorption isotherms describe the relationship between the amount of adsorbate on the adsorbent and its pressure at a constant temperature, illustrating how adsorption varies with pressure.
Correct Answer: C — They describe the relationship between the amount of adsorbate and its pressure at constant temperature.
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Q. Which of the following statements is true regarding adsorption?
A.
Adsorption is always an exothermic process
B.
Adsorption increases with increasing temperature
C.
Adsorption is a bulk phenomenon
D.
Adsorption does not depend on surface area
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Solution
Adsorption is generally an exothermic process, as it releases energy.
Correct Answer: A — Adsorption is always an exothermic process
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Q. Which of the following statements is true regarding Ampere's Law?
A.
It applies only to static currents
B.
It can be used for time-varying fields
C.
It is valid in all geometries
D.
It is independent of the medium
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Solution
Ampere's Law is primarily applicable to static currents and requires modifications for time-varying fields.
Correct Answer: A — It applies only to static currents
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Q. Which of the following statements is true regarding an arithmetic progression?
A.
The sum of any two terms is constant.
B.
The difference between consecutive terms is constant.
C.
The product of any two terms is constant.
D.
The ratio of any two terms is constant.
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Solution
In an arithmetic progression, the difference between consecutive terms is constant, which is the defining property of an AP.
Correct Answer: B — The difference between consecutive terms is constant.
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Q. Which of the following statements is true regarding an endothermic reaction?
A.
Heat is released
B.
Heat is absorbed
C.
No heat change
D.
It occurs spontaneously
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Solution
In an endothermic reaction, heat is absorbed from the surroundings.
Correct Answer: B — Heat is absorbed
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Q. Which of the following statements is true regarding an ideal gas? (2022)
A.
It has no volume
B.
It has no intermolecular forces
C.
It behaves according to the ideal gas law at all temperatures and pressures
D.
Both A and B
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Solution
An ideal gas is considered to have no volume and no intermolecular forces, making option D correct.
Correct Answer: D — Both A and B
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Q. Which of the following statements is true regarding capacitors in parallel? (2022)
A.
Total capacitance is the sum of individual capacitances
B.
Total capacitance is the product of individual capacitances
C.
Total capacitance is always less than the smallest capacitance
D.
Total capacitance is independent of the voltage
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Solution
For capacitors in parallel, the total capacitance is the sum of the individual capacitances: C_total = C₁ + C₂ + ...
Correct Answer: A — Total capacitance is the sum of individual capacitances
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Q. Which of the following statements is true regarding catalysts?
A.
They are consumed in the reaction
B.
They increase the activation energy
C.
They provide an alternative pathway
D.
They change the equilibrium constant
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Solution
Catalysts provide an alternative pathway with a lower activation energy, thus increasing the reaction rate without being consumed.
Correct Answer: C — They provide an alternative pathway
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Q. Which of the following statements is true regarding chemisorption?
A.
It is a reversible process.
B.
It involves the formation of a chemical bond.
C.
It occurs at low temperatures.
D.
It is independent of surface area.
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Solution
Chemisorption involves the formation of a chemical bond and is generally an irreversible process.
Correct Answer: B — It involves the formation of a chemical bond.
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Q. Which of the following statements is true regarding colligative properties?
A.
They depend on the identity of the solute
B.
They depend on the concentration of the solute
C.
They depend on the nature of the solvent
D.
They depend on the number of solute particles
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Solution
Colligative properties depend on the number of solute particles, not their identity.
Correct Answer: D — They depend on the number of solute particles
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Q. Which of the following statements is true regarding coordination compounds?
A.
They always have a fixed oxidation state.
B.
They can exhibit different colors.
C.
They cannot form isomers.
D.
They are always soluble in water.
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Solution
Coordination compounds can exhibit different colors due to the presence of different ligands and their ability to split d-orbitals.
Correct Answer: B — They can exhibit different colors.
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Q. Which of the following statements is true regarding divisibility by 5?
A.
A number must end in 0 or 5
B.
A number must be even
C.
A number must be a multiple of 10
D.
A number must be a prime number
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Solution
A number is divisible by 5 if it ends in either 0 or 5.
Correct Answer: A — A number must end in 0 or 5
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Q. Which of the following statements is true regarding dynamic equilibrium?
A.
The concentrations of reactants and products are equal
B.
The rate of the forward reaction equals the rate of the reverse reaction
C.
The reaction has stopped
D.
All reactions reach dynamic equilibrium
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Solution
Dynamic equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction, not necessarily when concentrations are equal.
Correct Answer: B — The rate of the forward reaction equals the rate of the reverse reaction
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Q. Which of the following statements is true regarding electric current? (2020)
A.
It flows from negative to positive
B.
It flows from positive to negative
C.
It does not require a closed circuit
D.
It is independent of voltage
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Solution
Electric current flows from positive to negative in a circuit.
Correct Answer: B — It flows from positive to negative
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Q. Which of the following statements is true regarding electric field lines?
A.
They can cross each other
B.
They are always straight
C.
They point from positive to negative charges
D.
They are always circular
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Solution
Electric field lines point from positive to negative charges and never cross each other.
Correct Answer: C — They point from positive to negative charges
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Q. Which of the following statements is true regarding enthalpy?
A.
Enthalpy is a state function
B.
Enthalpy depends on the path taken
C.
Enthalpy cannot be measured
D.
Enthalpy is always positive
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Solution
Enthalpy is a state function, meaning it depends only on the initial and final states, not the path taken.
Correct Answer: A — Enthalpy is a state function
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