Physical Chemistry

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Q. What does a positive ΔG indicate about a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is non-spontaneous.
  • C. The reaction is at equilibrium.
  • D. The reaction releases energy.
Q. What does a positive ΔG indicate about the spontaneity of a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is non-spontaneous.
  • C. The reaction is at equilibrium.
  • D. The reaction is exothermic.
Q. What does a positive ΔS indicate about a system?
  • A. The system is becoming more ordered.
  • B. The system is becoming more disordered.
  • C. The reaction is non-spontaneous.
  • D. The reaction is at equilibrium.
Q. What does a ΔG value of zero indicate about a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is at equilibrium.
  • C. The reaction is non-spontaneous.
  • D. The reaction is exothermic.
Q. What does Raoult's Law state about the vapor pressure of a solution?
  • A. It is directly proportional to the mole fraction of the solvent.
  • B. It is inversely proportional to the mole fraction of the solute.
  • C. It is equal to the vapor pressure of the solute.
  • D. It is independent of temperature.
Q. What does the Gibbs free energy change indicate?
  • A. Spontaneity of a reaction
  • B. Rate of a reaction
  • C. Equilibrium constant
  • D. Activation energy
Q. What does the term 'enthalpy of reaction' refer to?
  • A. The heat absorbed or released at constant pressure
  • B. The change in internal energy
  • C. The work done by the system
  • D. The temperature change during a reaction
Q. What does the term 'entropy' refer to in thermodynamics?
  • A. Energy stored in a system
  • B. Disorder or randomness in a system
  • C. Heat content of a system
  • D. Pressure of a system
Q. What does the term 'Gibbs free energy' indicate?
  • A. The total energy of a system
  • B. The energy available to do work
  • C. The heat content of a system
  • D. The entropy of a system
Q. What effect does increasing temperature have on the Gibbs Free Energy of an endothermic reaction?
  • A. ΔG increases.
  • B. ΔG decreases.
  • C. ΔG remains constant.
  • D. ΔG becomes zero.
Q. What effect does increasing the concentration of a reactant have on the rate of a first-order reaction?
  • A. Increases the rate
  • B. Decreases the rate
  • C. No effect
  • D. Rate becomes zero
Q. What happens to the boiling point of a liquid when the atmospheric pressure decreases?
  • A. It increases.
  • B. It decreases.
  • C. It remains the same.
  • D. It becomes unpredictable.
Q. What happens to the boiling point of a solvent when a non-volatile solute is added?
  • A. It decreases
  • B. It remains the same
  • C. It increases
  • D. It becomes zero
Q. What happens to the entropy of a system when it undergoes an irreversible process?
  • A. It decreases
  • B. It remains constant
  • C. It increases
  • D. It becomes zero
Q. What happens to the equilibrium constant if the reaction is reversed?
  • A. K remains the same
  • B. K is doubled
  • C. K is inverted
  • D. K is halved
Q. What happens to the equilibrium constant when a reaction is reversed?
  • A. It remains the same
  • B. It doubles
  • C. It is inverted
  • D. It is halved
Q. What happens to the freezing point of a solvent when a non-volatile solute is added?
  • A. It increases
  • B. It decreases
  • C. It remains the same
  • D. It fluctuates
Q. What happens to the kinetic energy of particles as a substance changes from solid to liquid?
  • A. It decreases
  • B. It remains the same
  • C. It increases
  • D. It fluctuates
Q. What happens to the pressure of a gas if the volume is doubled at constant temperature?
  • A. It doubles
  • B. It halves
  • C. It remains the same
  • D. It quadruples
Q. What happens to the pressure of a gas if the volume is halved at constant temperature?
  • A. It doubles
  • B. It halves
  • C. It remains the same
  • D. It quadruples
Q. What happens to the pressure of a gas if the volume is halved while the temperature remains constant?
  • A. Pressure doubles
  • B. Pressure halves
  • C. Pressure remains the same
  • D. Pressure quadruples
Q. What happens to the vapor pressure of a solution as the concentration of a non-volatile solute increases?
  • A. It increases.
  • B. It decreases.
  • C. It remains constant.
  • D. It fluctuates.
Q. What happens to the vapor pressure of a solvent when a non-volatile solute is added?
  • A. It increases
  • B. It decreases
  • C. It remains the same
  • D. It fluctuates
Q. What happens to the vapor pressure of a solvent when a volatile solute is added?
  • A. It increases.
  • B. It decreases.
  • C. It remains the same.
  • D. It becomes zero.
Q. What happens to the volume of a gas if the temperature is increased at constant pressure?
  • A. It decreases
  • B. It increases
  • C. It remains the same
  • D. It becomes zero
Q. What happens to the volume of a gas when the pressure is increased at constant temperature?
  • A. Increases
  • B. Decreases
  • C. Remains the same
  • D. Becomes zero
Q. What is Raoult's Law primarily used to describe?
  • A. The behavior of ideal gases
  • B. The vapor pressure of solutions
  • C. The boiling point elevation
  • D. The freezing point depression
Q. What is Raoult's Law primarily used to determine?
  • A. Vapor pressure of a solution
  • B. Boiling point elevation
  • C. Freezing point depression
  • D. Molarity of a solution
Q. What is the boiling point elevation of a solution containing 1 mol of NaCl in 1 kg of water? (K_b for water = 0.512 °C kg/mol)
  • A. 0.512 °C
  • B. 1.024 °C
  • C. 1.536 °C
  • D. 2.048 °C
Q. What is the boiling point of a liquid?
  • A. The temperature at which vapor pressure equals atmospheric pressure
  • B. The temperature at which a liquid freezes
  • C. The temperature at which a liquid evaporates
  • D. The temperature at which a liquid condenses
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