Q. Which of the following has the lowest bond order?
Solution
He2 has a bond order of 0, calculated as (2 bonding electrons - 2 antibonding electrons)/2 = 0.
Correct Answer: D — He2
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Q. Which of the following molecular orbitals is filled first according to the Aufbau principle?
-
A.
σ1s
-
B.
σ*1s
-
C.
π2p
-
D.
σ2p
Solution
According to the Aufbau principle, the σ1s molecular orbital is filled first as it has the lowest energy.
Correct Answer: A — σ1s
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Q. Which of the following molecular orbitals is lower in energy than the 2p atomic orbitals?
-
A.
σ2s
-
B.
σ*2s
-
C.
π2p
-
D.
σ2p
Solution
σ2s is lower in energy than the 2p atomic orbitals.
Correct Answer: A — σ2s
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Q. Which of the following molecules exhibits resonance?
-
A.
H2O
-
B.
CO2
-
C.
O3
-
D.
CH4
Solution
Ozone (O3) exhibits resonance due to the delocalization of electrons.
Correct Answer: C — O3
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Q. Which of the following molecules has a bent shape according to VSEPR theory?
-
A.
CO2
-
B.
H2O
-
C.
NH3
-
D.
CH4
Solution
H2O has two bonding pairs and two lone pairs, leading to a bent molecular geometry.
Correct Answer: B — H2O
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Q. Which of the following molecules has a bent shape?
-
A.
CO2
-
B.
H2O
-
C.
NH3
-
D.
CH4
Solution
H2O has two bonding pairs and two lone pairs, leading to a bent molecular geometry.
Correct Answer: B — H2O
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Q. Which of the following molecules has a bond order of 1?
-
A.
H2
-
B.
He2
-
C.
Li2
-
D.
B2
Solution
Li2 has a bond order of 1, calculated as (2 bonding electrons - 0 antibonding electrons)/2 = 1.
Correct Answer: C — Li2
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Q. Which of the following molecules has a bond order of 2?
Solution
N2 has a bond order of 2, calculated as (number of bonding electrons - number of antibonding electrons)/2 = (10-6)/2 = 2.
Correct Answer: B — N2
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Q. Which of the following molecules has a higher bond order than N2?
Solution
O2 has a bond order of 2, while N2 has a bond order of 3, so none have a higher bond order than N2.
Correct Answer: A — O2
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Q. Which of the following molecules has a higher bond order: N2 or O2?
-
A.
N2
-
B.
O2
-
C.
Both are equal
-
D.
Cannot be determined
Solution
N2 has a bond order of 3, while O2 has a bond order of 2, so N2 has a higher bond order.
Correct Answer: A — N2
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Q. Which of the following molecules has a linear shape?
-
A.
CH4
-
B.
H2O
-
C.
CO2
-
D.
NH3
Solution
CO2 has a linear shape due to the arrangement of its double bonds.
Correct Answer: C — CO2
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Q. Which of the following molecules has a trigonal bipyramidal geometry?
-
A.
NH3
-
B.
PCl5
-
C.
H2O
-
D.
CO2
Solution
PCl5 has five bonding pairs and no lone pairs, leading to a trigonal bipyramidal geometry.
Correct Answer: B — PCl5
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Q. Which of the following molecules has a triple bond?
Solution
N2 has a triple bond, consisting of one sigma bond and two pi bonds.
Correct Answer: A — N2
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Q. Which of the following molecules has the highest bond order?
Solution
N2 has the highest bond order of 3, calculated as (10 bonding electrons - 2 antibonding electrons)/2 = 3.
Correct Answer: A — N2
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Q. Which of the following molecules is diamagnetic?
Solution
F2 is diamagnetic as it has all electrons paired in its molecular orbitals.
Correct Answer: C — F2
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Q. Which of the following molecules is isoelectronic with N2?
Solution
C2 is isoelectronic with N2, both having 10 electrons.
Correct Answer: B — C2
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Q. Which of the following molecules is isoelectronic with Ne?
Solution
N2 is isoelectronic with Ne, both having 10 electrons.
Correct Answer: C — N2
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Q. Which of the following molecules is polar?
-
A.
CCl4
-
B.
CO2
-
C.
NH3
-
D.
CH4
Solution
Ammonia (NH3) is polar due to its trigonal pyramidal shape and the presence of a lone pair on nitrogen.
Correct Answer: C — NH3
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Q. Which of the following molecules is predicted to be stable according to molecular orbital theory?
-
A.
He2
-
B.
Li2
-
C.
Be2
-
D.
B2
Solution
Li2 is stable with a bond order of 1, while He2 and Be2 are not stable.
Correct Answer: B — Li2
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Q. Which of the following pairs of atoms will form a bond with the highest bond order?
-
A.
C and O
-
B.
N and O
-
C.
C and N
-
D.
O and O
Solution
C and N will form a bond with the highest bond order of 3, as seen in the molecule CN.
Correct Answer: C — C and N
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Q. Which of the following pairs of atoms will form a stable diatomic molecule according to molecular orbital theory?
-
A.
N and O
-
B.
O and F
-
C.
C and N
-
D.
B and O
Solution
C and N will form a stable diatomic molecule as they have suitable bond orders and electron configurations.
Correct Answer: C — C and N
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Q. Which of the following pairs of molecules has the same bond order?
-
A.
N2 and CO
-
B.
O2 and F2
-
C.
C2 and B2
-
D.
He2 and Ne2
Solution
N2 and CO both have a bond order of 3.
Correct Answer: A — N2 and CO
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Q. Which of the following species exhibits sp3d hybridization?
-
A.
SF4
-
B.
XeF2
-
C.
NH3
-
D.
C2H4
Solution
In SF4, the sulfur atom is sp3d hybridized, resulting in a seesaw molecular geometry.
Correct Answer: A — SF4
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Q. Which of the following species has a bond order of 1?
Solution
F2 has a bond order of 1, calculated as (8 bonding electrons - 6 antibonding electrons)/2 = 1.
Correct Answer: C — F2
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Q. Which of the following species has a central atom with sp3 hybridization?
-
A.
CCl4
-
B.
CO2
-
C.
BF3
-
D.
H2O
Solution
In CCl4, the central carbon atom is sp3 hybridized, forming a tetrahedral geometry.
Correct Answer: A — CCl4
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Q. Which of the following species has a linear geometry due to hybridization?
-
A.
H2O
-
B.
CO2
-
C.
NH3
-
D.
CH4
Solution
CO2 has a linear geometry due to the sp hybridization of the carbon atom.
Correct Answer: B — CO2
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Q. Which of the following species has a linear molecular geometry?
-
A.
BeCl2
-
B.
NH3
-
C.
H2O
-
D.
CH3Cl
Solution
BeCl2 has two bonding pairs and no lone pairs, resulting in a linear molecular geometry.
Correct Answer: A — BeCl2
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Q. Which of the following species has a linear molecular shape?
-
A.
BeCl2
-
B.
SF6
-
C.
NH3
-
D.
H2O
Solution
BeCl2 has two bonding pairs and no lone pairs, resulting in a linear shape.
Correct Answer: A — BeCl2
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Q. Which of the following species has a tetrahedral shape?
-
A.
CH4
-
B.
C2H4
-
C.
NH3
-
D.
H2O
Solution
CH4 has a tetrahedral shape due to sp3 hybridization of the carbon atom.
Correct Answer: A — CH4
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Q. Which of the following species has a trigonal bipyramidal geometry?
-
A.
PCl5
-
B.
BF3
-
C.
H2O
-
D.
NH4+
Solution
PCl5 has five bonding pairs and no lone pairs, resulting in a trigonal bipyramidal geometry.
Correct Answer: A — PCl5
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