Q. What is the bond order of the molecule CO?
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Solution
CO has a bond order of 3, calculated as (10 bonding electrons - 2 antibonding electrons)/2 = 3.
Correct Answer: C — 3
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Q. What is the bond order of the molecule He2?
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Solution
He2 has a bond order of 0, as it has no net bonding electrons.
Correct Answer: A — 0
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Q. What is the bond order of the N2 molecule?
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Solution
N2 has a bond order of 3, calculated as (10 bonding - 0 antibonding)/2 = 3.
Correct Answer: C — 3
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Q. What is the bond order of the O2 molecule according to Molecular Orbital Theory?
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Solution
O2 has 12 total electrons, leading to a bond order of (10 bonding - 6 antibonding)/2 = 1.
Correct Answer: B — 2
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Q. What is the change in enthalpy for an endothermic reaction?
A.
Negative
B.
Positive
C.
Zero
D.
Undefined
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Solution
In an endothermic reaction, heat is absorbed from the surroundings, resulting in a positive change in enthalpy.
Correct Answer: B — Positive
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Q. What is the change in enthalpy for an exothermic reaction?
A.
Positive
B.
Negative
C.
Zero
D.
Undefined
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Solution
In an exothermic reaction, heat is released, resulting in a negative change in enthalpy.
Correct Answer: B — Negative
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Q. What is the change in enthalpy for an isothermal process?
A.
Zero
B.
Positive
C.
Negative
D.
Depends on the system
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Solution
In an isothermal process, the temperature remains constant, and for an ideal gas, the change in enthalpy is zero.
Correct Answer: A — Zero
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Q. What is the change in entropy when 1 mole of an ideal gas expands isothermally and reversibly from volume V1 to V2?
A.
R ln(V2/V1)
B.
R (V2 - V1)
C.
R (V1/V2)
D.
0
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Solution
The change in entropy for an isothermal and reversible expansion of an ideal gas is given by ΔS = nR ln(V2/V1). For 1 mole, n = 1, hence ΔS = R ln(V2/V1).
Correct Answer: A — R ln(V2/V1)
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Q. What is the change in entropy when 1 mole of an ideal gas expands isothermally from volume V1 to V2?
A.
R ln(V2/V1)
B.
R (V2 - V1)
C.
R (V1/V2)
D.
0
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Solution
The change in entropy for an isothermal expansion of an ideal gas is given by ΔS = nR ln(V2/V1). For 1 mole, it simplifies to ΔS = R ln(V2/V1).
Correct Answer: A — R ln(V2/V1)
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Q. What is the change in oxidation state of carbon in the reaction: CH4 + 2O2 → CO2 + 2H2O?
A.
0 to +4
B.
+4 to 0
C.
0 to -4
D.
-4 to 0
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Solution
The oxidation state of carbon changes from -4 in CH4 to +4 in CO2.
Correct Answer: A — 0 to +4
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Q. What is the color of the complex ion [Cu(H2O)6]2+?
A.
Blue
B.
Green
C.
Yellow
D.
Red
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Solution
The complex ion [Cu(H2O)6]2+ is blue due to d-d transitions.
Correct Answer: A — Blue
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Q. What is the color of the complex [Cu(H2O)6]2+?
A.
Blue
B.
Green
C.
Red
D.
Yellow
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Solution
[Cu(H2O)6]2+ is known to exhibit a blue color due to d-d transitions in the presence of water ligands.
Correct Answer: A — Blue
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Q. What is the common oxidation state of actinides in their compounds?
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Solution
The common oxidation state of actinides in their compounds is +4.
Correct Answer: D — +6
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Q. What is the common oxidation state of alkali metals?
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Solution
Alkali metals have a common oxidation state of +1.
Correct Answer: A — +1
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Q. What is the common oxidation state of Chromium in chromates?
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Solution
Chromium commonly exhibits a +6 oxidation state in chromates (CrO4^2-).
Correct Answer: D — +6
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Q. What is the common oxidation state of chromium in Cr2O7^2-?
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Solution
In Cr2O7^2-, chromium has a common oxidation state of +6.
Correct Answer: C — +6
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Q. What is the common oxidation state of Chromium in its compounds?
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Solution
Chromium commonly exhibits a +6 oxidation state in compounds such as chromium trioxide (CrO3).
Correct Answer: C — +6
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Q. What is the common oxidation state of Group 17 elements?
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Solution
Group 17 elements, also known as halogens, commonly exhibit an oxidation state of -1.
Correct Answer: A — -1
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Q. What is the common oxidation state of nitrogen in ammonia (NH3)?
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Solution
In ammonia, nitrogen has an oxidation state of -3.
Correct Answer: A — -3
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Q. What is the common oxidation state of the p-block elements in group 13?
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Solution
The common oxidation state of group 13 elements, such as Aluminum, is +3.
Correct Answer: C — +3
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Q. What is the common oxidation state of transition metals in their compounds?
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Solution
Transition metals commonly exhibit a +2 oxidation state due to the loss of two 4s electrons.
Correct Answer: B — +2
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Q. What is the concentration in g/L of a solution containing 0.5 moles of KCl in 1.5 L of solution? (Molar mass of KCl = 74.5 g/mol)
A.
24.83 g/L
B.
49.67 g/L
C.
37.25 g/L
D.
50 g/L
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Solution
Mass of KCl = 0.5 moles × 74.5 g/mol = 37.25 g. Concentration = 37.25 g / 1.5 L = 24.83 g/L.
Correct Answer: B — 49.67 g/L
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Q. What is the concentration in molality of a solution made by dissolving 5 moles of solute in 3 kg of solvent?
A.
1.67 m
B.
2 m
C.
1.5 m
D.
2.5 m
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Solution
Molality (m) = moles of solute / kg of solvent = 5 moles / 3 kg = 1.67 m.
Correct Answer: B — 2 m
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Q. What is the concentration in molarity of a solution that contains 0.5 moles of solute in 1.5 liters of solution?
A.
0.33 M
B.
0.5 M
C.
0.75 M
D.
1 M
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Solution
Molarity (M) = moles of solute / liters of solution = 0.5 moles / 1.5 L = 0.33 M.
Correct Answer: C — 0.75 M
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Q. What is the concentration in ppm of a solution containing 1 gram of solute in 1 liter of solution?
A.
1000 ppm
B.
100 ppm
C.
10 ppm
D.
1 ppm
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Solution
PPM = (mass of solute in grams / volume of solution in liters) * 10^6 = (1 g / 1 L) * 10^6 = 1000 ppm.
Correct Answer: A — 1000 ppm
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Q. What is the concentration of a solution if 10 grams of NaCl is dissolved in 500 mL of water? (Molar mass of NaCl = 58.5 g/mol)
A.
0.34 M
B.
0.17 M
C.
0.50 M
D.
0.25 M
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Solution
Molarity (M) = moles of solute / liters of solution = (10 g / 58.5 g/mol) / 0.5 L = 0.34 M.
Correct Answer: A — 0.34 M
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Q. What is the concentration of H+ ions in a solution with a pH of 3?
A.
0.001 M
B.
0.01 M
C.
0.1 M
D.
1 M
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Solution
[H+] = 10^(-pH) = 10^(-3) = 0.001 M
Correct Answer: A — 0.001 M
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Q. What is the coordination number of the central metal ion in the complex [Co(NH3)6]Cl3?
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Solution
The coordination number is determined by the number of ligands attached to the central metal ion. In [Co(NH3)6]Cl3, there are six NH3 ligands, so the coordination number is 6.
Correct Answer: C — 6
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Q. What is the coordination number of the central metal ion in [Co(NH3)6]Cl3?
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Solution
The coordination number of the central metal ion (Co) in [Co(NH3)6]Cl3 is 6.
Correct Answer: C — 6
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Q. What is the critical point in a phase diagram?
A.
The point where solid and liquid coexist
B.
The point where liquid and gas coexist
C.
The point beyond which gas cannot be liquefied
D.
The point of maximum pressure
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Solution
The critical point is where the liquid and gas phases become indistinguishable.
Correct Answer: C — The point beyond which gas cannot be liquefied
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