Q. What is the hybridization of the central atom in CH4?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
In CH4, the central carbon atom forms four equivalent bonds with hydrogen atoms, indicating sp3 hybridization.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in CO2?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
The carbon atom in CO2 is sp hybridized, forming two double bonds with oxygen atoms.
Correct Answer: A — sp
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Q. What is the hybridization of the central atom in H2O?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
Oxygen in H2O is sp3 hybridized, forming two bonds and two lone pairs.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in N2O?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
The central nitrogen atom in N2O is sp hybridized, leading to a linear arrangement.
Correct Answer: A — sp
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Q. What is the hybridization of the central atom in NH3?
A.
sp
B.
sp2
C.
sp3
D.
sp3d
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Solution
The central nitrogen atom in NH3 is sp3 hybridized due to three bonding pairs and one lone pair.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in NH4+?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
The central atom nitrogen in NH4+ undergoes sp3 hybridization to form four equivalent bonds with hydrogen.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in O3 (ozone)?
A.
sp
B.
sp2
C.
sp3
D.
dsp2
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Solution
The central oxygen atom in O3 is sp2 hybridized, leading to a bent molecular shape.
Correct Answer: B — sp2
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Q. What is the hybridization of the central atom in ozone (O3)?
A.
sp
B.
sp2
C.
sp3
D.
dsp2
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Solution
In ozone (O3), the central oxygen atom is sp2 hybridized, resulting in a bent molecular shape.
Correct Answer: B — sp2
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Q. What is the hybridization of the central atom in PCl5?
A.
sp
B.
sp2
C.
sp3
D.
sp3d
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Solution
In PCl5, phosphorus is sp3d hybridized, allowing for five bonding pairs.
Correct Answer: D — sp3d
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Q. What is the hybridization of the central atom in SO2?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
The sulfur atom in SO2 is sp2 hybridized, forming one double bond and one single bond.
Correct Answer: B — sp2
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Q. What is the hybridization of the central atom in XeF4?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
The xenon atom in XeF4 is dsp3 hybridized, resulting in a square planar geometry.
Correct Answer: D — dsp3
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Q. What is the hybridization of the nitrogen atom in NH3?
A.
sp
B.
sp2
C.
sp3
D.
dsp3
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Solution
In NH3, nitrogen has three bonds and one lone pair, leading to sp3 hybridization.
Correct Answer: C — sp3
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Q. What is the hybridization of the phosphorus atom in PCl5?
A.
sp
B.
sp2
C.
sp3
D.
d2sp3
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Solution
In PCl5, phosphorus is surrounded by five chlorine atoms, indicating d2sp3 hybridization.
Correct Answer: D — d2sp3
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Q. What is the integrated rate law for a first-order reaction?
A.
ln[A] = -kt + ln[A]0
B.
[A] = [A]0 - kt
C.
[A] = [A]0e^(-kt)
D.
1/[A] = kt + 1/[A]0
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Solution
The integrated rate law for a first-order reaction is ln[A] = -kt + ln[A]0.
Correct Answer: A — ln[A] = -kt + ln[A]0
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Q. What is the Kb of ammonia (NH3) if the pKa of its conjugate acid (NH4+) is 9.25?
A.
1.8 x 10^-5
B.
5.6 x 10^-10
C.
1.0 x 10^-14
D.
3.2 x 10^-5
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Solution
Kb = Kw / Ka = 1.0 x 10^-14 / 5.6 x 10^-10 = 1.8 x 10^-5
Correct Answer: A — 1.8 x 10^-5
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Q. What is the Ksp expression for the salt Ag2SO4?
A.
Ksp = [Ag+]^2[SO4^2-]
B.
Ksp = [Ag2+]^2[SO4^2-]
C.
Ksp = [Ag+]^2[SO4^2-]^2
D.
Ksp = [Ag+]^2[SO4^2-]^3
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Solution
The solubility product constant (Ksp) for Ag2SO4 is given by Ksp = [Ag+]^2[SO4^2-] because the dissociation is Ag2SO4 ⇌ 2Ag+ + SO4^2-.
Correct Answer: A — Ksp = [Ag+]^2[SO4^2-]
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Q. What is the Ksp of AgCl if the solubility of AgCl in water is 1.0 x 10^-5 M?
A.
1.0 x 10^-10
B.
1.0 x 10^-5
C.
1.0 x 10^-15
D.
1.0 x 10^-20
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Solution
Ksp = [Ag+][Cl-] = (1.0 x 10^-5)(1.0 x 10^-5) = 1.0 x 10^-10.
Correct Answer: A — 1.0 x 10^-10
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Q. What is the limiting reagent when 3 moles of A react with 2 moles of B to produce 4 moles of C?
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Solution
The reaction requires 1.5 moles of B for 3 moles of A. Since only 2 moles of B are available, B is the limiting reagent.
Correct Answer: B — B
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Q. What is the limiting reagent when 5 moles of A react with 3 moles of B in the reaction A + 2B → C?
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Solution
The reaction requires 2 moles of B for every mole of A. For 5 moles of A, 10 moles of B are needed. Since only 3 moles of B are available, B is the limiting reagent.
Correct Answer: B — B
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Q. What is the magnetic quantum number for a 3d orbital?
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Solution
The magnetic quantum number (m_l) for a 3d orbital can be -2, -1, 0, 1, or 2.
Correct Answer: A — -2
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Q. What is the main characteristic of a catalyst in surface chemistry?
A.
It increases the rate of reaction by changing the equilibrium.
B.
It is consumed in the reaction.
C.
It provides an alternative reaction pathway.
D.
It decreases the activation energy of the reaction.
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Solution
A catalyst provides an alternative reaction pathway, which lowers the activation energy and increases the reaction rate.
Correct Answer: C — It provides an alternative reaction pathway.
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Q. What is the main characteristic of a catalyst in surface reactions?
A.
It is consumed in the reaction.
B.
It lowers the activation energy.
C.
It increases the temperature of the reaction.
D.
It changes the equilibrium constant.
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Solution
A catalyst lowers the activation energy of a reaction without being consumed in the process.
Correct Answer: B — It lowers the activation energy.
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Q. What is the main component of air?
A.
Oxygen
B.
Nitrogen
C.
Carbon Dioxide
D.
Argon
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Solution
Nitrogen makes up about 78% of the Earth's atmosphere, making it the main component of air.
Correct Answer: B — Nitrogen
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Q. What is the main component of natural gas?
A.
Ethane
B.
Propane
C.
Methane
D.
Butane
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Solution
The main component of natural gas is methane (CH4).
Correct Answer: C — Methane
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Q. What is the main difference between adsorption and absorption?
A.
Adsorption involves a surface phenomenon
B.
Absorption is a surface phenomenon
C.
Both are the same
D.
Adsorption is faster than absorption
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Solution
Adsorption is a surface phenomenon, while absorption involves the entire volume of the material.
Correct Answer: A — Adsorption involves a surface phenomenon
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Q. What is the main difference between physisorption and chemisorption?
A.
Temperature dependence
B.
Nature of forces involved
C.
Reversibility
D.
All of the above
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Solution
The main difference lies in the nature of forces involved; physisorption is due to weak van der Waals forces, while chemisorption involves strong chemical bonds.
Correct Answer: D — All of the above
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Q. What is the main function of a salt bridge in a galvanic cell?
A.
To provide a path for electrons
B.
To maintain charge balance
C.
To increase voltage
D.
To decrease resistance
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Solution
The main function of a salt bridge is to maintain charge balance by allowing ions to flow.
Correct Answer: B — To maintain charge balance
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Q. What is the main reason that gases have low density compared to solids and liquids?
A.
High temperature
B.
Low pressure
C.
Large particle separation
D.
High kinetic energy
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Solution
Gases have low density because their particles are far apart, leading to a larger volume for the same mass.
Correct Answer: C — Large particle separation
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Q. What is the mass of 0.25 moles of glucose (C6H12O6)? (Molar mass = 180 g/mol)
A.
45 g
B.
90 g
C.
60 g
D.
75 g
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Solution
Mass = moles × molar mass = 0.25 moles × 180 g/mol = 45 g.
Correct Answer: B — 90 g
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Q. What is the mass of 0.5 moles of CaCO3?
A.
50 g
B.
25 g
C.
100 g
D.
75 g
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Solution
Molar mass of CaCO3 = 40 + 12 + 16*3 = 100 g/mol. Mass = moles x molar mass = 0.5 moles x 100 g/mol = 50 g.
Correct Answer: B — 25 g
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