Physical Chemistry

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Q. What is the entropy change for a system that undergoes a phase transition at constant temperature?
  • A. ΔS = 0
  • B. ΔS = Q/T
  • C. ΔS = T/Q
  • D. ΔS = Q + T
Q. What is the entropy change for an ideal gas during an isothermal expansion?
  • A. Zero
  • B. nR ln(Vf/Vi)
  • C. nC_v ln(Tf/Ti)
  • D. nC_p ln(Tf/Ti)
Q. What is the entropy change for the isothermal expansion of an ideal gas from volume V1 to V2 at temperature T?
  • A. R ln(V2/V1)
  • B. R (V2 - V1)/T
  • C. 0
  • D. R (V1/V2)
Q. What is the entropy change for the mixing of two ideal gases at constant temperature?
  • A. 0
  • B. R ln(2)
  • C. R ln(V1/V2)
  • D. R ln(V1*V2)
Q. What is the entropy change when 1 mole of an ideal gas is heated at constant volume from temperature T1 to T2?
  • A. R ln(T2/T1)
  • B. R (T2 - T1)
  • C. 0
  • D. R (T1/T2)
Q. What is the entropy change when 1 mole of an ideal gas is heated at constant volume?
  • A. 0
  • B. R ln(T2/T1)
  • C. R (T2 - T1)
  • D. R (T1/T2)
Q. What is the entropy change when 1 mole of ice at 0°C is converted to water at 0°C?
  • A. 0 J/K
  • B. R ln(2)
  • C. R
  • D. Positive value
Q. What is the entropy change when 2 moles of an ideal gas are compressed isothermally from volume V2 to V1?
  • A. -R ln(V1/V2)
  • B. R ln(V1/V2)
  • C. 0
  • D. R (V2 - V1)
Q. What is the equilibrium constant expression for the reaction N2(g) + 3H2(g) ⇌ 2NH3(g)?
  • A. Kc = [NH3]^2 / ([N2][H2]^3)
  • B. Kc = [N2][H2]^3 / [NH3]^2
  • C. Kc = [NH3]^2 / [N2][H2]
  • D. Kc = [N2][H2] / [NH3]^2
Q. What is the equilibrium constant expression for the reaction: 2A + B ⇌ C?
  • A. [C]/([A]^2[B])
  • B. [A]^2[B]/[C]
  • C. [C]/[A][B]
  • D. [A][B]/[C]
Q. What is the equilibrium constant expression for the reaction: aA + bB ⇌ cC + dD?
  • A. K = [C]^c [D]^d / [A]^a [B]^b
  • B. K = [A]^a [B]^b / [C]^c [D]^d
  • C. K = [C]^c [D]^d
  • D. K = [A]^a [B]^b
Q. What is the equivalent weight of H2SO4 if its molar mass is 98 g/mol?
  • A. 49 g
  • B. 98 g
  • C. 196 g
  • D. 24.5 g
Q. What is the expected osmotic pressure of a 0.5 M NaCl solution at 25 °C?
  • A. 12.3 atm
  • B. 24.6 atm
  • C. 6.1 atm
  • D. 3.1 atm
Q. What is the formula for calculating boiling point elevation?
  • A. ΔT_b = K_b * m
  • B. ΔT_b = K_f * m
  • C. ΔT_b = i * K_b * m
  • D. ΔT_b = i * K_f * m
Q. What is the formula for calculating the depression of freezing point?
  • A. ΔTf = Kf * m
  • B. ΔTf = Kb * m
  • C. ΔTf = R * T
  • D. ΔTf = P * V
Q. What is the formula for calculating the number of moles?
  • A. Moles = Mass / Volume
  • B. Moles = Mass x Volume
  • C. Moles = Mass / Molar Mass
  • D. Moles = Molar Mass / Mass
Q. What is the freezing point depression constant (Kf) for water?
  • A. 1.86 °C kg/mol
  • B. 0.52 °C kg/mol
  • C. 2.00 °C kg/mol
  • D. 3.72 °C kg/mol
Q. What is the freezing point depression of a solution containing 2 moles of KCl in 1 kg of water?
  • A. -3.72 °C
  • B. -1.86 °C
  • C. -2.52 °C
  • D. -4.0 °C
Q. What is the freezing point depression of a solution containing 2 moles of KCl in 1 kg of water? (Kf for water = 1.86 °C kg/mol)
  • A. 3.72 °C
  • B. 1.86 °C
  • C. 2.0 °C
  • D. 5.58 °C
Q. What is the freezing point depression of a solution containing 2 moles of NaCl in 1 kg of water? (Kf for water = 1.86 °C kg/mol)
  • A. 3.72 °C
  • B. 1.86 °C
  • C. 2.72 °C
  • D. 5.72 °C
Q. What is the freezing point depression of a solution directly proportional to?
  • A. The molar mass of the solute
  • B. The number of solute particles
  • C. The volume of the solvent
  • D. The temperature of the solvent
Q. What is the freezing point depression of a solution if 0.5 mol of a non-volatile solute is dissolved in 1 kg of water? (Kf for water = 1.86 °C kg/mol)
  • A. 0.93 °C
  • B. 1.86 °C
  • C. 3.72 °C
  • D. 0.5 °C
Q. What is the freezing point of a solution containing 0.3 mol of glucose in 1 kg of water? (K_f for water = 1.86 °C kg/mol)
  • A. -0.558 °C
  • B. -0.558 K
  • C. -1.86 °C
  • D. -1.86 K
Q. What is the geometry of a molecule with sp3d hybridization?
  • A. Linear
  • B. Trigonal planar
  • C. Tetrahedral
  • D. Trigonal bipyramidal
Q. What is the Gibbs Free Energy change (ΔG) at equilibrium?
  • A. ΔG < 0
  • B. ΔG = 0
  • C. ΔG > 0
  • D. ΔG = ΔH - TΔS
Q. What is the Gibbs free energy change for a spontaneous process?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Undefined
Q. What is the hybridization of a molecule with a tetrahedral shape?
  • A. sp
  • B. sp2
  • C. sp3
  • D. sp3d
Q. What is the hybridization of the carbon atom in acetylene (C2H2)?
  • A. sp
  • B. sp2
  • C. sp3
  • D. dsp3
Q. What is the hybridization of the carbon atom in CO2?
  • A. sp
  • B. sp2
  • C. sp3
  • D. dsp3
Q. What is the hybridization of the central atom in a molecule with a tetrahedral shape?
  • A. sp
  • B. sp2
  • C. sp3
  • D. sp3d
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