Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH2-CH2-CH2-COOH?
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A.
Hexanoic acid
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B.
Pentanoic acid
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C.
Heptanoic acid
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D.
Octanoic acid
Solution
The longest chain has six carbons, and the functional group is a carboxylic acid, hence the name is Hexanoic acid.
Correct Answer: A — Hexanoic acid
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH2-CH2-CH=CH2?
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A.
1-Hexene
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B.
2-Hexene
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C.
3-Hexene
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D.
Cyclohexene
Solution
The compound is an alkene with a double bond at the first carbon, named 1-Hexene.
Correct Answer: A — 1-Hexene
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH2-CH2-CHO?
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A.
Butanal
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B.
Pentanal
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C.
Hexanal
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D.
Heptanal
Solution
The longest chain has five carbons and ends with an aldehyde, hence it is Pentanal.
Correct Answer: B — Pentanal
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH2-CH2-COOH?
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A.
Pentanoic acid
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B.
Hexanoic acid
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C.
Butanoic acid
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D.
Heptanoic acid
Solution
The compound has a carboxylic acid functional group and a five-carbon chain, making it Pentanoic acid.
Correct Answer: A — Pentanoic acid
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH2-COOH?
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A.
Butanoic acid
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B.
Propanoic acid
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C.
Pentanoic acid
-
D.
Hexanoic acid
Solution
The compound has a carboxylic acid functional group and a four-carbon chain, making it Butanoic acid.
Correct Answer: A — Butanoic acid
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CH=CH2?
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A.
1-Butene
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B.
2-Butene
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C.
Butyne
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D.
Butane
Solution
The compound has a double bond between the first and second carbons, making it 1-Butene.
Correct Answer: A — 1-Butene
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-CO-CH3?
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A.
Butan-2-one
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B.
Propan-2-one
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C.
Butan-1-one
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D.
Pentanal
Solution
The compound is a ketone with four carbons and the carbonyl group on the second carbon, hence it is Butan-2-one.
Correct Answer: A — Butan-2-one
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Q. What is the IUPAC name for the compound with the structure CH3-CH2-COOH?
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A.
Propanoic acid
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B.
Butanoic acid
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C.
Acetic acid
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D.
Methanoic acid
Solution
The compound is a carboxylic acid with 3 carbons, named Propanoic acid.
Correct Answer: A — Propanoic acid
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Q. What is the IUPAC name for the compound with the structure CH3-CO-CH2-COOH?
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A.
3-Oxobutanoic acid
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B.
2-Oxobutanoic acid
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C.
Butanoic acid
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D.
Acetic acid
Solution
The compound has a ketone and a carboxylic acid, making it 3-Oxobutanoic acid.
Correct Answer: A — 3-Oxobutanoic acid
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Q. What is the IUPAC name of CH3-CH2-CH(CH3)-CH2-CH3?
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A.
2-Pentyl
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B.
3-Pentyl
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C.
2-Methylpentane
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D.
3-Methylpentane
Solution
The longest carbon chain has 5 carbons, and there is a methyl group on the second carbon, making it 2-Methylpentane.
Correct Answer: C — 2-Methylpentane
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Q. What is the IUPAC name of CH3-CH2-CH2-CHO?
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A.
Butanal
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B.
Propionaldehyde
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C.
Pentanal
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D.
Hexanal
Solution
The compound is a four-carbon aldehyde, hence its IUPAC name is Butanal.
Correct Answer: A — Butanal
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Q. What is the IUPAC name of CH3-CH2-CH2-COOH?
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A.
Butanoic acid
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B.
Propanoic acid
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C.
Pentanoic acid
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D.
Hexanoic acid
Solution
The longest carbon chain contains four carbons, and the functional group is a carboxylic acid, hence the name is Butanoic acid.
Correct Answer: A — Butanoic acid
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Q. What is the IUPAC name of CH3-CH2-CHO?
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A.
Ethanal
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B.
Propanal
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C.
Butanal
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D.
Methanal
Solution
The compound CH3-CH2-CHO is an aldehyde and is named ethanal.
Correct Answer: A — Ethanal
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Q. What is the IUPAC name of the compound with the formula C2H5-CO-CH3?
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A.
Butan-2-one
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B.
Propan-2-one
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C.
Butan-1-one
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D.
Propan-1-one
Solution
The compound is a ketone with four carbons, and the carbonyl group is on the second carbon, thus it is Butan-2-one.
Correct Answer: A — Butan-2-one
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Q. What is the IUPAC name of the compound with the formula C6H5-CH2-CHO?
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A.
Benzaldehyde
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B.
Benzylaldehyde
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C.
Phenylacetaldehyde
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D.
Phenylaldehyde
Solution
The compound has a benzyl group and an aldehyde functional group, making the correct name Benzylaldehyde.
Correct Answer: B — Benzylaldehyde
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Q. What is the IUPAC name of the compound with the structure CH3-CH(CH3)-C(CH3)2-CH2-CH3?
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A.
2,3-Dimethylpentane
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B.
3,3-Dimethylpentane
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C.
2,2-Dimethylpentane
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D.
3-Methylpentane
Solution
The longest chain has 5 carbons, and there are two methyl groups on the third carbon, so the name is 3,3-Dimethylpentane.
Correct Answer: B — 3,3-Dimethylpentane
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Q. What is the main characteristic of geometric isomers?
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A.
Different connectivity
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B.
Different spatial arrangement
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C.
Different molecular formula
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D.
Different functional groups
Solution
Geometric isomers have the same connectivity but differ in the spatial arrangement of groups around a double bond.
Correct Answer: B — Different spatial arrangement
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Q. What is the main characteristic of optical isomers?
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A.
Different boiling points
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B.
Different melting points
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C.
Different optical activities
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D.
Different molecular weights
Solution
Optical isomers differ in their ability to rotate plane-polarized light.
Correct Answer: C — Different optical activities
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Q. What is the main product of the dehydration of ethanol?
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A.
Ethylene
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B.
Acetaldehyde
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C.
Ethane
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D.
Diethyl ether
Solution
The dehydration of ethanol primarily produces ethylene (ethene) through the elimination of water.
Correct Answer: A — Ethylene
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Q. What is the main reason for the existence of geometric isomers?
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A.
Presence of double bonds
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B.
Presence of single bonds
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C.
Presence of chiral centers
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D.
Presence of functional groups
Solution
Geometric isomers arise due to restricted rotation around double bonds.
Correct Answer: A — Presence of double bonds
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Q. What is the molecular formula of benzene?
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A.
C6H6
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B.
C6H12
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C.
C6H10
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D.
C6H8
Solution
Benzene has the molecular formula C6H6, indicating it is an aromatic hydrocarbon.
Correct Answer: A — C6H6
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Q. What is the primary effect of a -CN group on a benzene ring?
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A.
+M effect
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B.
-M effect
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C.
+I effect
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D.
-I effect
Solution
-CN exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
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Q. What is the primary effect of the -COOH group on a benzene ring?
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A.
+M effect
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B.
-M effect
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C.
+I effect
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D.
-I effect
Solution
The -COOH group primarily exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
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Q. What is the primary effect of the -COOH group on aromatic compounds?
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A.
+M effect
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B.
-M effect
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C.
+I effect
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D.
-I effect
Solution
-COOH exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
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Q. What is the primary effect of the inductive effect in organic compounds?
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A.
Stabilization of positive charge
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B.
Stabilization of negative charge
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C.
Delocalization of electrons
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D.
Formation of hydrogen bonds
Solution
The inductive effect involves the shifting of electron density through sigma bonds, which stabilizes positive charges.
Correct Answer: A — Stabilization of positive charge
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Q. What is the primary effect of the inductive effect in organic molecules?
-
A.
Stabilization of positive charge
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B.
Stabilization of negative charge
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C.
Delocalization of electrons
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D.
Formation of hydrogen bonds
Solution
The inductive effect involves the shifting of electron density through sigma bonds, which can stabilize positive charges.
Correct Answer: A — Stabilization of positive charge
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Q. What is the primary reason for the +M effect of -OCH3?
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A.
Inductive effect
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B.
Resonance effect
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C.
Steric hindrance
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D.
Electronegativity
Solution
The +M effect of -OCH3 is primarily due to resonance effect, where the lone pairs on oxygen can delocalize into the aromatic ring.
Correct Answer: B — Resonance effect
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Q. What is the primary reason for the acidity of chloroacetic acid compared to acetic acid?
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A.
Inductive effect
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B.
Mesomeric effect
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C.
Steric hindrance
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D.
Hydrogen bonding
Solution
The inductive effect of the -Cl group in chloroacetic acid increases its acidity compared to acetic acid.
Correct Answer: A — Inductive effect
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Q. What is the primary reason for the stability of phenol compared to cyclohexanol?
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A.
Inductive effect
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B.
Mesomeric effect
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C.
Steric hindrance
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D.
Hydrogen bonding
Solution
Phenol is stabilized by resonance (mesomeric effect) which is not present in cyclohexanol.
Correct Answer: B — Mesomeric effect
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Q. What is the product of the complete combustion of an alkane?
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A.
Carbon monoxide and water
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B.
Carbon dioxide and water
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C.
Carbon and hydrogen
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D.
Hydrogen gas
Solution
The complete combustion of an alkane produces carbon dioxide and water.
Correct Answer: B — Carbon dioxide and water
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