Q. How does the presence of a +M group affect the stability of a carbocation?
A.
Increases stability
B.
Decreases stability
C.
No effect
D.
Depends on the solvent
Show solution
Solution
A +M group increases the stability of a carbocation by donating electron density through resonance.
Correct Answer: A — Increases stability
Learn More →
Q. How does the presence of a -I group affect the stability of a carbocation?
A.
Increases stability
B.
Decreases stability
C.
No effect
D.
Depends on the size of the group
Show solution
Solution
A -I group decreases the stability of a carbocation by withdrawing electron density.
Correct Answer: B — Decreases stability
Learn More →
Q. Identify the group that shows a -I effect.
A.
-NH2
B.
-CH3
C.
-F
D.
-OCH3
Show solution
Solution
The -F group shows a -I effect as it withdraws electron density through its electronegativity.
Correct Answer: C — -F
Learn More →
Q. In which of the following cases does the mesomeric effect dominate over the inductive effect?
A.
Aromatic compounds
B.
Aliphatic compounds
C.
Alkynes
D.
Alkenes
Show solution
Solution
In aromatic compounds, the mesomeric effect dominates due to resonance stabilization.
Correct Answer: A — Aromatic compounds
Learn More →
Q. In which of the following compounds does the inductive effect play a significant role?
A.
Benzene
B.
Acetic acid
C.
Cyclohexane
D.
Ethylene
Show solution
Solution
In acetic acid, the inductive effect of the –COOH group influences the acidity of the compound.
Correct Answer: B — Acetic acid
Learn More →
Q. What is the effect of -NO2 group on the stability of benzene derivatives?
A.
Stabilizing
B.
Destabilizing
C.
No effect
D.
Enhancing acidity
Show solution
Solution
-NO2 is a strong electron-withdrawing group and destabilizes benzene derivatives.
Correct Answer: B — Destabilizing
Learn More →
Q. What is the effect of a -CF3 group on the stability of a benzene ring?
A.
Stabilizing
B.
Destabilizing
C.
No effect
D.
Depends on substituents
Show solution
Solution
-CF3 is a strong electron-withdrawing group, which destabilizes the benzene ring.
Correct Answer: B — Destabilizing
Learn More →
Q. What is the effect of a -CH3 group on the stability of a carbocation?
A.
Destabilizes
B.
No effect
C.
Stabilizes
D.
Increases acidity
Show solution
Solution
The -CH3 group is an electron-donating group and stabilizes the carbocation through hyperconjugation.
Correct Answer: C — Stabilizes
Learn More →
Q. What is the effect of a -COOH group on the stability of a benzene ring?
A.
Stabilizing
B.
Destabilizing
C.
No effect
D.
Depends on substituents
Show solution
Solution
The -COOH group is a strong electron-withdrawing group, thus it destabilizes the benzene ring.
Correct Answer: B — Destabilizing
Learn More →
Q. What is the effect of a -I group on the acidity of a carboxylic acid?
A.
Increases acidity
B.
Decreases acidity
C.
No effect
D.
Only affects basicity
Show solution
Solution
A -I group increases the acidity of a carboxylic acid by stabilizing the negative charge on the conjugate base.
Correct Answer: A — Increases acidity
Learn More →
Q. What is the effect of a -I group on the acidity of carboxylic acids?
A.
Increases acidity
B.
Decreases acidity
C.
No effect
D.
Depends on the solvent
Show solution
Solution
A -I group increases the acidity of carboxylic acids by stabilizing the negative charge on the conjugate base.
Correct Answer: A — Increases acidity
Learn More →
Q. What is the effect of a -NO2 group on the stability of a benzene ring?
A.
Stabilizing
B.
Destabilizing
C.
No effect
D.
Enhances reactivity
Show solution
Solution
The -NO2 group is a strong electron-withdrawing group, which destabilizes the benzene ring.
Correct Answer: B — Destabilizing
Learn More →
Q. What is the effect of the +M effect on the stability of a carbocation?
A.
Destabilizes the carbocation
B.
Stabilizes the carbocation
C.
No effect on stability
D.
Increases acidity
Show solution
Solution
The +M effect stabilizes the carbocation by donating electron density through resonance.
Correct Answer: B — Stabilizes the carbocation
Learn More →
Q. What is the effect of the -I effect on acidity?
A.
Increases acidity
B.
Decreases acidity
C.
No effect on acidity
D.
Depends on the solvent
Show solution
Solution
The -I effect increases acidity by stabilizing the negative charge on the conjugate base.
Correct Answer: A — Increases acidity
Learn More →
Q. What is the effect of the -I group on acidity?
A.
Increases acidity
B.
Decreases acidity
C.
No effect on acidity
D.
Depends on the solvent
Show solution
Solution
Electron-withdrawing groups (-I) increase the acidity of compounds by stabilizing the negative charge on the conjugate base.
Correct Answer: A — Increases acidity
Learn More →
Q. What is the effect of the -M (mesomeric) effect on the stability of a carbocation?
A.
Destabilizes the carbocation
B.
Stabilizes the carbocation
C.
No effect on stability
D.
Increases acidity
Show solution
Solution
The -M effect can stabilize a carbocation by delocalizing the positive charge.
Correct Answer: B — Stabilizes the carbocation
Learn More →
Q. What is the effect of the -M group on the stability of a carbocation?
A.
Destabilizes the carbocation
B.
Stabilizes the carbocation
C.
No effect on stability
D.
Increases acidity
Show solution
Solution
-M groups destabilize carbocations by withdrawing electron density through resonance.
Correct Answer: A — Destabilizes the carbocation
Learn More →
Q. What is the primary effect of a -CN group on a benzene ring?
A.
+M effect
B.
-M effect
C.
+I effect
D.
-I effect
Show solution
Solution
-CN exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
Learn More →
Q. What is the primary effect of the -COOH group on a benzene ring?
A.
+M effect
B.
-M effect
C.
+I effect
D.
-I effect
Show solution
Solution
The -COOH group primarily exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
Learn More →
Q. What is the primary effect of the -COOH group on aromatic compounds?
A.
+M effect
B.
-M effect
C.
+I effect
D.
-I effect
Show solution
Solution
-COOH exhibits a -M effect as it withdraws electron density through resonance.
Correct Answer: B — -M effect
Learn More →
Q. What is the primary effect of the inductive effect in organic compounds?
A.
Stabilization of positive charge
B.
Stabilization of negative charge
C.
Delocalization of electrons
D.
Formation of hydrogen bonds
Show solution
Solution
The inductive effect involves the shifting of electron density through sigma bonds, which stabilizes positive charges.
Correct Answer: A — Stabilization of positive charge
Learn More →
Q. What is the primary effect of the inductive effect in organic molecules?
A.
Stabilization of positive charge
B.
Stabilization of negative charge
C.
Delocalization of electrons
D.
Formation of hydrogen bonds
Show solution
Solution
The inductive effect involves the shifting of electron density through sigma bonds, which can stabilize positive charges.
Correct Answer: A — Stabilization of positive charge
Learn More →
Q. What is the primary reason for the +M effect of -OCH3?
A.
Inductive effect
B.
Resonance effect
C.
Steric hindrance
D.
Electronegativity
Show solution
Solution
The +M effect of -OCH3 is primarily due to resonance effect, where the lone pairs on oxygen can delocalize into the aromatic ring.
Correct Answer: B — Resonance effect
Learn More →
Q. What is the primary reason for the acidity of chloroacetic acid compared to acetic acid?
A.
Inductive effect
B.
Mesomeric effect
C.
Steric hindrance
D.
Hydrogen bonding
Show solution
Solution
The inductive effect of the -Cl group in chloroacetic acid increases its acidity compared to acetic acid.
Correct Answer: A — Inductive effect
Learn More →
Q. What is the primary reason for the stability of phenol compared to cyclohexanol?
A.
Inductive effect
B.
Mesomeric effect
C.
Steric hindrance
D.
Hydrogen bonding
Show solution
Solution
Phenol is stabilized by resonance (mesomeric effect) which is not present in cyclohexanol.
Correct Answer: B — Mesomeric effect
Learn More →
Q. Which of the following compounds is least acidic due to +M effect?
A.
Phenol
B.
Acetic acid
C.
Formic acid
D.
Benzoic acid
Show solution
Solution
Phenol is less acidic compared to the other acids listed due to the +M effect of the aromatic ring, which destabilizes the negative charge on the phenoxide ion.
Correct Answer: A — Phenol
Learn More →
Q. Which of the following compounds is most acidic due to inductive effect?
A.
CH3COOH
B.
CCl3COOH
C.
C2H5COOH
D.
C6H5COOH
Show solution
Solution
CCl3COOH is most acidic due to the strong -I effect of the -CCl3 group.
Correct Answer: B — CCl3COOH
Learn More →
Q. Which of the following compounds is most affected by the mesomeric effect?
A.
Ethylbenzene
B.
Benzaldehyde
C.
Cyclohexanol
D.
Propane
Show solution
Solution
Benzaldehyde is most affected by the mesomeric effect due to the presence of the carbonyl group which can participate in resonance.
Correct Answer: B — Benzaldehyde
Learn More →
Q. Which of the following compounds is most stabilized by resonance?
A.
Benzene
B.
Cyclohexane
C.
Ethylene
D.
Acetylene
Show solution
Solution
Benzene is highly stabilized by resonance due to its delocalized pi electrons.
Correct Answer: A — Benzene
Learn More →
Q. Which of the following compounds is stabilized by +M effect?
A.
Phenol
B.
Acetic acid
C.
Nitrobenzene
D.
Benzaldehyde
Show solution
Solution
Phenol is stabilized by the +M effect due to the presence of the -OH group which donates electron density.
Correct Answer: A — Phenol
Learn More →
Showing 1 to 30 of 76 (3 Pages)