Q. Which of the following has the highest freezing point depression?
-
A.
0.1 molal NaCl
-
B.
0.1 molal KBr
-
C.
0.1 molal CaCl2
-
D.
0.1 molal glucose
Solution
CaCl2 dissociates into 3 ions (Ca2+ and 2 Cl-), resulting in the highest freezing point depression.
Correct Answer: C — 0.1 molal CaCl2
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Q. Which of the following has the highest ionization energy?
Solution
Silicon (Si) has the highest ionization energy among the given elements due to its higher nuclear charge and smaller atomic radius.
Correct Answer: D — Si
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Q. Which of the following has the highest standard molar entropy (S°) at 298 K?
-
A.
H2(g)
-
B.
O2(g)
-
C.
N2(g)
-
D.
H2O(l)
Solution
H2O(l) has a higher standard molar entropy than the diatomic gases due to its molecular complexity and interactions.
Correct Answer: D — H2O(l)
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Q. Which of the following has the lowest bond energy?
Solution
F2 has the lowest bond energy due to the repulsion between the lone pairs on the fluorine atoms.
Correct Answer: C — F2
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Q. Which of the following has the lowest bond order?
Solution
He2 has a bond order of 0, calculated as (2 bonding electrons - 2 antibonding electrons)/2 = 0.
Correct Answer: D — He2
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Q. Which of the following has the lowest vapor pressure?
-
A.
Pure water
-
B.
0.1 M NaCl solution
-
C.
0.1 M KCl solution
-
D.
0.1 M glucose solution
Solution
The 0.1 M NaCl and KCl solutions will have lower vapor pressures than pure water due to the presence of solute particles.
Correct Answer: B — 0.1 M NaCl solution
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Q. Which of the following hydrocarbons is a cyclic compound?
-
A.
Butene
-
B.
Cyclobutane
-
C.
Hexane
-
D.
Octene
Solution
Cyclobutane is a cyclic compound, while the others are linear alkenes or alkanes.
Correct Answer: B — Cyclobutane
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Q. Which of the following hydrocarbons is a gas at room temperature?
-
A.
Octane
-
B.
Hexane
-
C.
Methane
-
D.
Decane
Solution
Methane (CH4) is a gas at room temperature, while the others are liquids.
Correct Answer: C — Methane
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Q. Which of the following hydrogen compounds is used as a reducing agent?
-
A.
H2O
-
B.
H2
-
C.
HCl
-
D.
NH3
Solution
Hydrogen gas (H2) is commonly used as a reducing agent in various chemical reactions.
Correct Answer: B — H2
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Q. Which of the following ions has the smallest ionic radius?
-
A.
Na+
-
B.
Mg2+
-
C.
Al3+
-
D.
Si4+
Solution
Si4+ has the smallest ionic radius due to its high positive charge, which pulls the electrons closer.
Correct Answer: D — Si4+
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Q. Which of the following ions is colored in solution?
-
A.
Na+
-
B.
Ca2+
-
C.
Cu2+
-
D.
Mg2+
Solution
Cu2+ ions are colored in solution due to d-d transitions.
Correct Answer: C — Cu2+
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Q. Which of the following ions is responsible for the green color of a solution?
-
A.
Cu2+
-
B.
Fe2+
-
C.
Ni2+
-
D.
Co2+
Solution
Co2+ ions typically impart a green color to solutions due to d-d transitions.
Correct Answer: D — Co2+
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Q. Which of the following ions will cause the precipitation of AgCl from a solution of AgNO3?
-
A.
Na+
-
B.
Cl-
-
C.
NO3-
-
D.
K+
Solution
Cl- ions will react with Ag+ ions from AgNO3 to form AgCl, which is insoluble in water and will precipitate out.
Correct Answer: B — Cl-
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Q. Which of the following ions will cause the precipitation of BaSO4 from a solution of barium chloride?
-
A.
Na+
-
B.
Cl-
-
C.
SO4^2-
-
D.
K+
Solution
The presence of SO4^2- ions will react with Ba2+ ions to form insoluble BaSO4, causing precipitation.
Correct Answer: C — SO4^2-
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Q. Which of the following ions will cause the precipitation of silver chloride (AgCl) from a solution?
-
A.
Na+
-
B.
Cl-
-
C.
Ag+
-
D.
K+
Solution
Cl- ions will react with Ag+ ions to form the insoluble salt AgCl, causing precipitation.
Correct Answer: B — Cl-
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Q. Which of the following ions will increase the acidity of a solution?
-
A.
Na+
-
B.
Cl-
-
C.
NH4+
-
D.
K+
Solution
NH4+ is the conjugate acid of a weak base (NH3) and will increase the acidity of the solution.
Correct Answer: C — NH4+
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Q. Which of the following is a bidentate ligand?
-
A.
NH3
-
B.
EDTA
-
C.
Cl-
-
D.
H2O
Solution
EDTA is a bidentate ligand because it can form two bonds with a metal ion due to its two donor atoms.
Correct Answer: B — EDTA
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Q. Which of the following is a biodegradable polymer?
-
A.
Polyethylene
-
B.
Polylactic acid (PLA)
-
C.
Polypropylene
-
D.
Polystyrene
Solution
Polylactic acid (PLA) is a biodegradable polymer derived from renewable resources.
Correct Answer: B — Polylactic acid (PLA)
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Q. Which of the following is a branched alkane?
-
A.
Pentane
-
B.
Isopentane
-
C.
Hexane
-
D.
Heptane
Solution
Isopentane is a branched alkane, while the others are straight-chain alkanes.
Correct Answer: B — Isopentane
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Q. Which of the following is a branched-chain alkane?
-
A.
Pentane
-
B.
2-Methylbutane
-
C.
Hexane
-
D.
Heptane
Solution
2-Methylbutane is a branched-chain alkane derived from butane.
Correct Answer: B — 2-Methylbutane
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Q. Which of the following is a carbohydrate?
-
A.
Glucose
-
B.
Amino acid
-
C.
Fatty acid
-
D.
Nucleotide
Solution
Glucose is a simple sugar and a primary carbohydrate.
Correct Answer: A — Glucose
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Q. Which of the following is a characteristic feature of alkanes?
-
A.
They contain at least one double bond
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B.
They are saturated hydrocarbons
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C.
They have a cyclic structure
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D.
They contain functional groups
Solution
Alkanes are saturated hydrocarbons, meaning they contain only single bonds between carbon atoms.
Correct Answer: B — They are saturated hydrocarbons
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Q. Which of the following is a characteristic feature of cycloalkanes?
-
A.
They are always aromatic
-
B.
They contain a ring structure
-
C.
They have double bonds
-
D.
They are always gaseous at room temperature
Solution
Cycloalkanes are characterized by their ring structure.
Correct Answer: B — They contain a ring structure
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Q. Which of the following is a characteristic of +M effect?
-
A.
Electron withdrawal
-
B.
Electron donation
-
C.
No effect
-
D.
Increased acidity
Solution
+M effect is characterized by electron donation through resonance, enhancing stability.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of a base?
-
A.
Sour taste
-
B.
Bitter taste
-
C.
Turns litmus red
-
D.
Reacts with metals to produce hydrogen
Solution
Bases typically have a bitter taste and turn litmus paper blue.
Correct Answer: B — Bitter taste
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Q. Which of the following is a characteristic of a buffer solution?
-
A.
It changes pH drastically with small amounts of acid or base
-
B.
It resists changes in pH
-
C.
It has a pH of 7
-
D.
It can only be made from strong acids and bases
Solution
A buffer solution is designed to resist changes in pH when small amounts of acid or base are added.
Correct Answer: B — It resists changes in pH
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Q. Which of the following is a characteristic of a catalyst?
-
A.
It is consumed in the reaction
-
B.
It increases the activation energy
-
C.
It lowers the activation energy
-
D.
It changes the equilibrium constant
Solution
A catalyst lowers the activation energy of a reaction, thereby increasing the rate.
Correct Answer: C — It lowers the activation energy
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Q. Which of the following is a characteristic of a crystalline solid compared to a liquid?
-
A.
Definite melting point
-
B.
Fluidity
-
C.
High compressibility
-
D.
Random arrangement of particles
Solution
Crystalline solids have a definite melting point due to their ordered structure.
Correct Answer: A — Definite melting point
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Q. Which of the following is a characteristic of a first-order reaction?
-
A.
Rate is proportional to the square of the concentration
-
B.
Rate is independent of concentration
-
C.
Rate is directly proportional to concentration
-
D.
Rate is inversely proportional to concentration
Solution
In a first-order reaction, the rate is directly proportional to the concentration of the reactant.
Correct Answer: C — Rate is directly proportional to concentration
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Q. Which of the following is a characteristic of a fuel cell?
-
A.
Produces heat
-
B.
Converts chemical energy directly to electrical energy
-
C.
Requires combustion
-
D.
Is a type of battery
Solution
A fuel cell converts chemical energy directly to electrical energy without combustion.
Correct Answer: B — Converts chemical energy directly to electrical energy
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