Q. What is the value of k if the roots of the equation x^2 - kx + 12 = 0 are 3 and 4?
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Solution
Using Vieta's formulas, k = 3 + 4 = 7.
Correct Answer: A — 7
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Q. What is the van 't Hoff factor (i) for a strong electrolyte like NaCl in solution?
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Solution
NaCl dissociates into two ions (Na+ and Cl-), so the van 't Hoff factor (i) is 2.
Correct Answer: B — 2
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Q. What is the van 't Hoff factor (i) for a strong electrolyte that completely dissociates into 3 ions?
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Solution
The van 't Hoff factor (i) is equal to the number of particles the solute dissociates into. For a strong electrolyte that dissociates into 3 ions, i = 3.
Correct Answer: C — 3
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Q. What is the van 't Hoff factor (i) for glucose in solution?
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Solution
The van 't Hoff factor (i) for glucose is 1, as it does not dissociate in solution.
Correct Answer: A — 1
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Q. What is the van 't Hoff factor for a non-electrolyte solute?
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Solution
For a non-electrolyte solute, the van 't Hoff factor (i) is 1, as it does not dissociate into ions.
Correct Answer: B — 1
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Q. What is the vapor pressure of a solution containing 0.1 mol of a non-volatile solute in 1 kg of water? (Vapor pressure of pure water = 23.76 mmHg)
A.
22.88 mmHg
B.
21.76 mmHg
C.
20.76 mmHg
D.
19.76 mmHg
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Solution
Vapor pressure = P°_solvent * (n_solvent / (n_solvent + n_solute)) = 23.76 * (55.5 / (55.5 + 0.1)) = 22.88 mmHg
Correct Answer: A — 22.88 mmHg
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Q. What is the vapor pressure of a solution containing 1 mole of a non-volatile solute in 9 moles of solvent, if the vapor pressure of the pure solvent is 100 mmHg?
A.
90 mmHg
B.
100 mmHg
C.
10 mmHg
D.
80 mmHg
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Solution
Using Raoult's law, P_solution = X_solvent * P°_solvent = (9/10) * 100 mmHg = 90 mmHg.
Correct Answer: A — 90 mmHg
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Q. What is the vapor pressure of a solution containing 1 mole of a non-volatile solute in 10 moles of solvent, assuming ideal behavior?
A.
0.1 P0
B.
0.9 P0
C.
1.0 P0
D.
0.5 P0
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Solution
Using Raoult's law, the vapor pressure of the solution = (moles of solvent / total moles) * P0 = (10 / 11) * P0 = 0.909 P0.
Correct Answer: B — 0.9 P0
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Q. What is the vapor pressure of a solution containing 1 mole of a non-volatile solute in 3 moles of solvent, assuming ideal behavior?
A.
0.25 P0
B.
0.75 P0
C.
1.0 P0
D.
0.5 P0
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Solution
Vapor pressure lowering = (moles of solute / total moles) * P0 = (1 / (1 + 3)) * P0 = 0.25 P0, so vapor pressure = P0 - 0.25 P0 = 0.75 P0.
Correct Answer: B — 0.75 P0
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Q. What is the vapor pressure of a solution containing 1 mole of non-volatile solute in 3 moles of solvent if the vapor pressure of the pure solvent is 100 mmHg?
A.
75 mmHg
B.
100 mmHg
C.
25 mmHg
D.
50 mmHg
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Solution
Using Raoult's law, P_solution = X_solvent * P°_solvent. X_solvent = 3/(1+3) = 0.75, so P_solution = 0.75 * 100 mmHg = 75 mmHg.
Correct Answer: A — 75 mmHg
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Q. What is the vapor pressure of a solution containing 1 mole of solute in 3 moles of solvent, assuming ideal behavior?
A.
0.25 P0
B.
0.75 P0
C.
0.5 P0
D.
P0
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Solution
Using Raoult's law, the vapor pressure of the solution = (moles of solvent / total moles) * P0 = (3 / (3 + 1)) * P0 = 0.75 P0.
Correct Answer: B — 0.75 P0
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Q. What is the vapor pressure of a solution containing a non-volatile solute compared to the pure solvent?
A.
Higher than the pure solvent
B.
Lower than the pure solvent
C.
Equal to the pure solvent
D.
Unpredictable
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Solution
The vapor pressure of a solution containing a non-volatile solute is lower than that of the pure solvent due to the presence of solute particles.
Correct Answer: B — Lower than the pure solvent
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Q. What is the volume of 1 M NaOH solution required to obtain 0.5 moles of NaOH?
A.
0.5 L
B.
1 L
C.
2 L
D.
0.25 L
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Solution
Using the formula M = moles/volume, Volume = moles/M = 0.5 moles / 1 M = 0.5 L.
Correct Answer: A — 0.5 L
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Q. What is the volume of a 2 M solution that contains 4 moles of solute?
A.
2 L
B.
4 L
C.
1 L
D.
0.5 L
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Solution
Volume = moles of solute / molarity = 4 moles / 2 M = 2 L.
Correct Answer: B — 4 L
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Q. What is the volume percent concentration of a solution containing 30 mL of ethanol in 150 mL of solution?
A.
20%
B.
25%
C.
30%
D.
15%
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Solution
Volume percent = (volume of solute / total volume) x 100 = (30 mL / 150 mL) x 100 = 20%.
Correct Answer: B — 25%
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Q. What is the volume percent of ethanol in a solution made by mixing 30 mL of ethanol with 70 mL of water?
A.
30%
B.
70%
C.
50%
D.
20%
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Solution
Volume percent = (volume of solute / total volume) × 100 = (30 mL / (30 mL + 70 mL)) × 100 = 30%.
Correct Answer: A — 30%
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Q. What type of deviation from Raoult's Law is observed in solutions with strong solute-solvent interactions?
A.
Positive deviation
B.
Negative deviation
C.
No deviation
D.
Complete miscibility
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Solution
Negative deviation from Raoult's Law occurs when strong solute-solvent interactions lower the vapor pressure more than expected.
Correct Answer: B — Negative deviation
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Q. What type of solutions does Raoult's Law apply to most accurately?
A.
Ideal solutions
B.
Non-ideal solutions
C.
Concentrated solutions
D.
Dilute solutions
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Solution
Raoult's Law applies most accurately to ideal solutions, where interactions between different molecules are similar to those in pure substances.
Correct Answer: A — Ideal solutions
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Q. What type of solutions does Raoult's Law apply to?
A.
Ideal solutions only.
B.
Non-ideal solutions only.
C.
Both ideal and non-ideal solutions.
D.
Concentrated solutions only.
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Solution
Raoult's Law applies primarily to ideal solutions, where the interactions between different molecules are similar to those in pure substances.
Correct Answer: A — Ideal solutions only.
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Q. Which colligative property can be used to determine the molar mass of a solute?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
All of the above
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Solution
All of these colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which colligative property is affected by the presence of electrolytes?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
All of the above
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Solution
Electrolytes dissociate into ions, affecting all colligative properties by increasing the number of solute particles.
Correct Answer: D — All of the above
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Q. Which colligative property is used to determine molar mass of a solute?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of these colligative properties can be used to determine the molar mass of a solute by applying the appropriate formulas.
Correct Answer: D — All of the above
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Q. Which colligative property is used to determine the molar mass of a solute?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of the listed colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which of the following colligative properties is affected by the number of solute particles in a solution?
A.
Vapor pressure lowering
B.
Density
C.
Color
D.
Viscosity
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Solution
Vapor pressure lowering is a colligative property that depends on the number of solute particles in a solution.
Correct Answer: A — Vapor pressure lowering
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Q. Which of the following colligative properties is used to determine molar mass?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of the listed colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which of the following colligative properties is used to determine the molar mass of a solute?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
Osmotic pressure
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Solution
Freezing point depression can be used to determine the molar mass of a solute by measuring the decrease in freezing point.
Correct Answer: C — Freezing point depression
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Q. Which of the following compounds will have the highest boiling point when dissolved in water?
A.
NaCl
B.
KBr
C.
MgCl2
D.
LiI
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Solution
MgCl2 dissociates into 3 ions (1 Mg²⁺ and 2 Cl⁻), leading to the highest boiling point elevation due to the greatest number of particles.
Correct Answer: C — MgCl2
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Q. Which of the following factors does NOT affect the application of Raoult's Law?
A.
Nature of the solute
B.
Temperature
C.
Mole fraction of the solvent
D.
Pressure of the system
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Solution
Raoult's Law is primarily affected by the nature of the solute, temperature, and mole fraction of the solvent, but not by the pressure of the system.
Correct Answer: D — Pressure of the system
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Q. Which of the following factors does NOT affect the solubility of a gas in a liquid?
A.
Temperature
B.
Pressure
C.
Nature of solute
D.
Volume of solvent
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Solution
The volume of solvent does not directly affect the solubility of a gas; pressure and temperature do.
Correct Answer: D — Volume of solvent
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Q. Which of the following factors does NOT affect the vapor pressure of a solution according to Raoult's Law?
A.
Nature of the solute
B.
Temperature
C.
Mole fraction of the solvent
D.
Pressure of the system
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Solution
Raoult's Law states that the vapor pressure is affected by the nature of the solute, temperature, and mole fraction of the solvent, but not by the pressure of the system.
Correct Answer: D — Pressure of the system
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