Q. In which of the following molecules does the molecular orbital diagram show a paramagnetic behavior?
Solution
O2 is paramagnetic due to the presence of two unpaired electrons in its molecular orbitals.
Correct Answer: B — O2
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Q. In which of the following molecules does the molecular orbital theory predict a triple bond?
Solution
N2 has a triple bond, with a bond order of 3 according to molecular orbital theory.
Correct Answer: A — N2
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Q. In which of the following molecules does the molecular orbital theory predict a paramagnetic behavior?
Solution
O2 is paramagnetic due to the presence of two unpaired electrons in its molecular orbitals.
Correct Answer: B — O2
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Q. In which of the following species does the molecular orbital configuration show a paramagnetic behavior?
Solution
O2 has unpaired electrons in its molecular orbital configuration, making it paramagnetic.
Correct Answer: B — O2
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Q. What is the bond angle in a methane (CH4) molecule?
-
A.
90 degrees
-
B.
109.5 degrees
-
C.
120 degrees
-
D.
180 degrees
Solution
In methane, the bond angle is approximately 109.5 degrees due to its tetrahedral geometry.
Correct Answer: B — 109.5 degrees
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Q. What is the bond angle in a tetrahedral molecule?
-
A.
90 degrees
-
B.
120 degrees
-
C.
109.5 degrees
-
D.
180 degrees
Solution
In a tetrahedral geometry, the bond angles are approximately 109.5 degrees.
Correct Answer: C — 109.5 degrees
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Q. What is the bond angle in a trigonal planar molecule?
-
A.
120 degrees
-
B.
109.5 degrees
-
C.
180 degrees
-
D.
90 degrees
Solution
In a trigonal planar geometry, the bond angles are 120 degrees.
Correct Answer: A — 120 degrees
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Q. What is the bond angle in a water molecule (H2O) according to VSEPR theory?
-
A.
120 degrees
-
B.
109.5 degrees
-
C.
104.5 degrees
-
D.
90 degrees
Solution
The bond angle in H2O is approximately 104.5 degrees due to the two lone pairs on oxygen.
Correct Answer: C — 104.5 degrees
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Q. What is the bond angle in a water molecule (H2O)?
-
A.
120 degrees
-
B.
109.5 degrees
-
C.
104.5 degrees
-
D.
180 degrees
Solution
The bond angle in H2O is approximately 104.5 degrees due to the two lone pairs on oxygen.
Correct Answer: C — 104.5 degrees
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Q. What is the bond order of the CO molecule?
Solution
CO has a bond order of 3, calculated as (10 bonding - 3 antibonding)/2.
Correct Answer: C — 3
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Q. What is the bond order of the ion O2-?
Solution
O2- has a bond order of 1, calculated as (10 bonding electrons - 7 antibonding electrons)/2 = 1.
Correct Answer: B — 2
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Q. What is the bond order of the molecule B2 according to molecular orbital theory?
Solution
B2 has a bond order of 1, calculated as (2 bonding - 0 antibonding)/2.
Correct Answer: B — 1
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Q. What is the bond order of the molecule B2?
Solution
B2 has a bond order of 1, calculated from its molecular orbital configuration.
Correct Answer: A — 1
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Q. What is the bond order of the molecule CO?
Solution
CO has a bond order of 3, calculated as (10 bonding electrons - 2 antibonding electrons)/2 = 3.
Correct Answer: C — 3
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Q. What is the bond order of the molecule He2?
Solution
He2 has a bond order of 0, as it has no net bonding electrons.
Correct Answer: A — 0
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Q. What is the bond order of the N2 molecule?
Solution
N2 has a bond order of 3, calculated as (10 bonding - 0 antibonding)/2 = 3.
Correct Answer: C — 3
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Q. What is the bond order of the O2 molecule according to Molecular Orbital Theory?
Solution
O2 has 12 total electrons, leading to a bond order of (10 bonding - 6 antibonding)/2 = 1.
Correct Answer: B — 2
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Q. What is the effect of increasing electronegativity difference on bond character?
-
A.
Increases covalent character
-
B.
Decreases ionic character
-
C.
Increases ionic character
-
D.
No effect
Solution
Increasing electronegativity difference between two atoms leads to an increase in ionic character of the bond.
Correct Answer: C — Increases ionic character
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Q. What is the electron pair geometry of NH3?
-
A.
Tetrahedral
-
B.
Trigonal planar
-
C.
Octahedral
-
D.
Linear
Solution
NH3 has four electron pairs (three bonding pairs and one lone pair), giving it a tetrahedral electron pair geometry.
Correct Answer: A — Tetrahedral
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Q. What is the electron pair geometry of SF6?
-
A.
Tetrahedral
-
B.
Trigonal bipyramidal
-
C.
Octahedral
-
D.
Square planar
Solution
SF6 has six bonding pairs and no lone pairs, resulting in an octahedral electron pair geometry.
Correct Answer: C — Octahedral
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Q. What is the geometry of a molecule with sp3d hybridization?
-
A.
Linear
-
B.
Trigonal planar
-
C.
Tetrahedral
-
D.
Trigonal bipyramidal
Solution
Molecules with sp3d hybridization have a trigonal bipyramidal geometry.
Correct Answer: D — Trigonal bipyramidal
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Q. What is the hybridization of a molecule with a tetrahedral shape?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
sp3d
Solution
A tetrahedral shape corresponds to sp3 hybridization.
Correct Answer: C — sp3
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Q. What is the hybridization of the carbon atom in acetylene (C2H2)?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
In acetylene, each carbon atom is sp hybridized, forming a triple bond between them.
Correct Answer: A — sp
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Q. What is the hybridization of the carbon atom in CO2?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
In CO2, the carbon atom forms two double bonds with oxygen atoms, indicating sp hybridization.
Correct Answer: A — sp
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Q. What is the hybridization of the central atom in a molecule with a tetrahedral shape?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
sp3d
Solution
A tetrahedral shape corresponds to sp3 hybridization.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in CH4?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
In CH4, the central carbon atom forms four equivalent bonds with hydrogen atoms, indicating sp3 hybridization.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in CO2?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
The carbon atom in CO2 is sp hybridized, forming two double bonds with oxygen atoms.
Correct Answer: A — sp
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Q. What is the hybridization of the central atom in H2O?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
Oxygen in H2O is sp3 hybridized, forming two bonds and two lone pairs.
Correct Answer: C — sp3
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Q. What is the hybridization of the central atom in N2O?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
dsp3
Solution
The central nitrogen atom in N2O is sp hybridized, leading to a linear arrangement.
Correct Answer: A — sp
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Q. What is the hybridization of the central atom in NH3?
-
A.
sp
-
B.
sp2
-
C.
sp3
-
D.
sp3d
Solution
The central nitrogen atom in NH3 is sp3 hybridized due to three bonding pairs and one lone pair.
Correct Answer: C — sp3
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