Q. What is the primary reason for the lowering of vapor pressure in a solution?
A.
Increased temperature
B.
Decreased surface area
C.
Presence of solute particles
D.
Increased molecular weight of solvent
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Solution
The presence of solute particles reduces the number of solvent molecules at the surface, leading to a lower vapor pressure.
Correct Answer: C — Presence of solute particles
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Q. What is the relationship between the molality of a solution and its boiling point elevation?
A.
Directly proportional
B.
Inversely proportional
C.
No relationship
D.
Exponential relationship
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Solution
Boiling point elevation is directly proportional to the molality of the solution.
Correct Answer: A — Directly proportional
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Q. What is the van 't Hoff factor (i) for a strong electrolyte like NaCl in solution?
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Solution
NaCl dissociates into two ions (Na+ and Cl-), so the van 't Hoff factor (i) is 2.
Correct Answer: B — 2
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Q. What is the van 't Hoff factor (i) for a strong electrolyte that completely dissociates into 3 ions?
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Solution
The van 't Hoff factor (i) is equal to the number of particles the solute dissociates into. For a strong electrolyte that dissociates into 3 ions, i = 3.
Correct Answer: C — 3
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Q. What is the van 't Hoff factor (i) for glucose in solution?
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Solution
The van 't Hoff factor (i) for glucose is 1, as it does not dissociate in solution.
Correct Answer: A — 1
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Q. What is the van 't Hoff factor for a non-electrolyte solute?
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Solution
For a non-electrolyte solute, the van 't Hoff factor (i) is 1, as it does not dissociate into ions.
Correct Answer: B — 1
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Q. What is the vapor pressure of a solution containing 0.1 mol of a non-volatile solute in 1 kg of water? (Vapor pressure of pure water = 23.76 mmHg)
A.
22.88 mmHg
B.
21.76 mmHg
C.
20.76 mmHg
D.
19.76 mmHg
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Solution
Vapor pressure = P°_solvent * (n_solvent / (n_solvent + n_solute)) = 23.76 * (55.5 / (55.5 + 0.1)) = 22.88 mmHg
Correct Answer: A — 22.88 mmHg
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Q. What is the vapor pressure of a solution containing a non-volatile solute compared to the pure solvent?
A.
Higher than the pure solvent
B.
Lower than the pure solvent
C.
Equal to the pure solvent
D.
Unpredictable
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Solution
The vapor pressure of a solution containing a non-volatile solute is lower than that of the pure solvent due to the presence of solute particles.
Correct Answer: B — Lower than the pure solvent
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Q. Which colligative property can be used to determine the molar mass of a solute?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
All of the above
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Solution
All of these colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which colligative property is affected by the presence of electrolytes?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
All of the above
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Solution
Electrolytes dissociate into ions, affecting all colligative properties by increasing the number of solute particles.
Correct Answer: D — All of the above
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Q. Which colligative property is used to determine molar mass of a solute?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of these colligative properties can be used to determine the molar mass of a solute by applying the appropriate formulas.
Correct Answer: D — All of the above
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Q. Which colligative property is used to determine the molar mass of a solute?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of the listed colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which of the following colligative properties is affected by the number of solute particles in a solution?
A.
Vapor pressure lowering
B.
Density
C.
Color
D.
Viscosity
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Solution
Vapor pressure lowering is a colligative property that depends on the number of solute particles in a solution.
Correct Answer: A — Vapor pressure lowering
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Q. Which of the following colligative properties is used to determine molar mass?
A.
Boiling point elevation
B.
Freezing point depression
C.
Osmotic pressure
D.
All of the above
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Solution
All of the listed colligative properties can be used to determine the molar mass of a solute.
Correct Answer: D — All of the above
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Q. Which of the following colligative properties is used to determine the molar mass of a solute?
A.
Vapor pressure lowering
B.
Boiling point elevation
C.
Freezing point depression
D.
Osmotic pressure
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Solution
Freezing point depression can be used to determine the molar mass of a solute by measuring the decrease in freezing point.
Correct Answer: C — Freezing point depression
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Q. Which of the following has the highest freezing point depression?
A.
0.1 molal NaCl
B.
0.1 molal KBr
C.
0.1 molal CaCl2
D.
0.1 molal glucose
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Solution
CaCl2 dissociates into 3 ions (Ca2+ and 2 Cl-), resulting in the highest freezing point depression.
Correct Answer: C — 0.1 molal CaCl2
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Q. Which of the following has the lowest vapor pressure?
A.
Pure water
B.
0.1 M NaCl solution
C.
0.1 M KCl solution
D.
0.1 M glucose solution
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Solution
The 0.1 M NaCl and KCl solutions will have lower vapor pressures than pure water due to the presence of solute particles.
Correct Answer: B — 0.1 M NaCl solution
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Q. Which of the following solutions will have the highest boiling point?
A.
0.1 M NaCl
B.
0.1 M KCl
C.
0.1 M glucose
D.
0.1 M MgCl2
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Solution
0.1 M MgCl2 will have the highest boiling point due to the highest van 't Hoff factor (i = 3).
Correct Answer: D — 0.1 M MgCl2
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Q. Which of the following statements about colligative properties is true?
A.
They depend on the identity of the solute
B.
They depend on the number of solute particles
C.
They are independent of temperature
D.
They are only applicable to ionic compounds
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Solution
Colligative properties depend on the number of solute particles in a solution, not their identity.
Correct Answer: B — They depend on the number of solute particles
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Q. Which of the following statements is true regarding colligative properties?
A.
They depend on the identity of the solute
B.
They depend on the concentration of the solute
C.
They depend on the nature of the solvent
D.
They depend on the number of solute particles
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Solution
Colligative properties depend on the number of solute particles, not their identity.
Correct Answer: D — They depend on the number of solute particles
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Q. Which of the following will exhibit the greatest freezing point depression?
A.
0.1 M NaCl
B.
0.1 M K2SO4
C.
0.1 M CaCl2
D.
0.1 M urea
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Solution
0.1 M K2SO4 will exhibit the greatest freezing point depression due to its van 't Hoff factor of 3.
Correct Answer: C — 0.1 M CaCl2
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Q. Which of the following will exhibit the greatest vapor pressure lowering?
A.
0.1 M NaCl
B.
0.1 M CaCl2
C.
0.1 M K2SO4
D.
0.1 M glucose
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Solution
CaCl2 dissociates into three ions (Ca2+ and 2 Cl-), leading to the greatest vapor pressure lowering among the options.
Correct Answer: B — 0.1 M CaCl2
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Q. Which of the following will exhibit the lowest vapor pressure?
A.
Pure water
B.
0.1 M NaCl solution
C.
0.1 M KCl solution
D.
0.1 M glucose solution
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Solution
The 0.1 M NaCl solution will exhibit the lowest vapor pressure due to the presence of more solute particles (2 ions per formula unit).
Correct Answer: B — 0.1 M NaCl solution
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Q. Which of the following will have the lowest freezing point?
A.
0.1 m NaCl
B.
0.1 m KBr
C.
0.1 m MgCl2
D.
0.1 m C6H12O6
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Solution
0.1 m MgCl2 produces 3 particles (Mg2+ and 2 Cl-), leading to the lowest freezing point among the options.
Correct Answer: C — 0.1 m MgCl2
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