Solution & Colligative Properties
Q. If 1 mole of NaCl is dissolved in water, how many particles are present in solution?
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Solution
1 mole of NaCl dissociates into 2 particles (1 Na⁺ and 1 Cl⁻), so there are 2 particles in solution.
Correct Answer: B — 2
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Q. What happens to the freezing point of a solvent when a solute is added?
A.
It increases
B.
It decreases
C.
It remains the same
D.
It fluctuates
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Solution
The freezing point of a solvent decreases when a solute is added, a phenomenon known as freezing point depression.
Correct Answer: B — It decreases
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Q. What is the formula for calculating the boiling point elevation?
A.
ΔT_b = i * K_b * m
B.
ΔT_b = K_b / m
C.
ΔT_b = i * K_f * m
D.
ΔT_b = K_f * m
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Solution
The boiling point elevation is calculated using the formula ΔT_b = i * K_b * m, where i is the van 't Hoff factor, K_b is the ebullioscopic constant, and m is the molality.
Correct Answer: A — ΔT_b = i * K_b * m
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Q. What is the primary reason for the colligative properties of solutions?
A.
Chemical reactivity of solute
B.
Concentration of solute particles
C.
Molecular weight of solute
D.
Temperature of the solution
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Solution
Colligative properties depend on the concentration of solute particles in a solution, not their identity.
Correct Answer: B — Concentration of solute particles
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Q. What is the primary reason for the increase in boiling point when a solute is added?
A.
Increased vapor pressure
B.
Decreased vapor pressure
C.
Increased solubility
D.
Decreased solubility
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Solution
The addition of a solute decreases the vapor pressure of the solvent, which requires a higher temperature to reach the boiling point.
Correct Answer: B — Decreased vapor pressure
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Q. What is the van 't Hoff factor (i) for NaCl in solution?
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Solution
The van 't Hoff factor (i) for NaCl is 2 because it dissociates into two ions: Na+ and Cl-.
Correct Answer: B — 2
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Q. Which of the following factors does NOT affect colligative properties?
A.
Number of solute particles
B.
Nature of the solute
C.
Temperature
D.
Solvent identity
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Solution
Colligative properties depend primarily on the number of solute particles, not the nature of the solute.
Correct Answer: B — Nature of the solute
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Q. Which of the following is NOT a colligative property?
A.
Osmotic pressure
B.
Vapor pressure lowering
C.
Boiling point elevation
D.
Density
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Solution
Density is not a colligative property; it does not depend on the number of solute particles.
Correct Answer: D — Density
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Q. Which of the following solutions would have the highest boiling point?
A.
0.1 m NaCl
B.
0.1 m KCl
C.
0.1 m CaCl2
D.
0.1 m glucose
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Solution
0.1 m CaCl2 produces three particles (Ca2+ and 2 Cl-), leading to the highest boiling point elevation among the options.
Correct Answer: C — 0.1 m CaCl2
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