Physical Chemistry

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Q. In which of the following molecules does the molecular orbital configuration show unpaired electrons?
  • A. N2
  • B. O2
  • C. F2
  • D. Ne2
Q. In which of the following molecules does the molecular orbital diagram show a paramagnetic behavior?
  • A. N2
  • B. O2
  • C. F2
  • D. Ne2
Q. In which of the following molecules does the molecular orbital theory predict a paramagnetic behavior?
  • A. N2
  • B. O2
  • C. C2
  • D. Ne2
Q. In which of the following molecules does the molecular orbital theory predict a triple bond?
  • A. N2
  • B. O2
  • C. C2
  • D. H2
Q. In which of the following orbitals would an electron have the highest energy?
  • A. 1s
  • B. 2s
  • C. 2p
  • D. 3s
Q. In which of the following reactions is the enthalpy change likely to be the largest?
  • A. Dissolving salt in water
  • B. Combustion of gasoline
  • C. Melting of ice
  • D. Sublimation of dry ice
Q. In which of the following reactions is the entropy change expected to be negative?
  • A. N2(g) + 3H2(g) → 2NH3(g)
  • B. C(s) + O2(g) → CO2(g)
  • C. 2H2(g) + O2(g) → 2H2O(g)
  • D. CaCO3(s) → CaO(s) + CO2(g)
Q. In which of the following scenarios does a liquid exhibit the highest boiling point?
  • A. High molecular weight and strong intermolecular forces
  • B. Low molecular weight and weak intermolecular forces
  • C. High molecular weight and weak intermolecular forces
  • D. Low molecular weight and strong intermolecular forces
Q. In which of the following scenarios does a liquid exhibit the highest density?
  • A. At its boiling point
  • B. At its freezing point
  • C. At room temperature
  • D. At its critical point
Q. In which of the following scenarios is the entropy of the system likely to decrease?
  • A. Ice melting
  • B. Water freezing
  • C. Gas expanding
  • D. Liquid evaporating
Q. In which of the following scenarios is ΔG equal to ΔH?
  • A. At high temperatures with ΔS = 0.
  • B. At low temperatures with ΔS = 0.
  • C. At constant pressure and temperature.
  • D. In a phase transition.
Q. In which of the following scenarios would the entropy of the system decrease?
  • A. Ice melting
  • B. Water evaporating
  • C. Gas compressing
  • D. Sugar dissolving in water
Q. In which of the following scenarios would you expect a liquid to have the highest viscosity?
  • A. At high temperatures
  • B. At low temperatures
  • C. When mixed with gases
  • D. When agitated
Q. In which of the following species does the molecular orbital configuration show a paramagnetic behavior?
  • A. N2
  • B. O2
  • C. F2
  • D. Ne2
Q. In which of the following states does a liquid exhibit the highest density?
  • A. At low temperatures
  • B. At high temperatures
  • C. At critical temperature
  • D. At boiling point
Q. In which of the following states of matter do particles have the least freedom of movement?
  • A. Solid
  • B. Liquid
  • C. Gas
  • D. Plasma
Q. In which process does the entropy of the system decrease?
  • A. Freezing of water
  • B. Evaporation of water
  • C. Sublimation of dry ice
  • D. Dissolving salt in water
Q. In which scenario would the Gibbs Free Energy of a system be at its minimum?
  • A. At equilibrium
  • B. At the start of a reaction
  • C. At maximum temperature
  • D. At maximum pressure
Q. In which scenario would ΔG = 0?
  • A. At the start of a reaction.
  • B. At equilibrium.
  • C. When the reaction is spontaneous.
  • D. When the reaction is non-spontaneous.
Q. In which scenario would ΔG be equal to ΔH?
  • A. At absolute zero.
  • B. When ΔS = 0.
  • C. For a spontaneous reaction.
  • D. For an endothermic reaction.
Q. In which scenario would ΔG be zero?
  • A. At standard conditions
  • B. At equilibrium
  • C. In a spontaneous reaction
  • D. In a non-spontaneous reaction
Q. In which state of matter do molecules have the least freedom of movement?
  • A. Solid
  • B. Liquid
  • C. Gas
  • D. Plasma
Q. In which state of matter do particles have the highest kinetic energy?
  • A. Solid
  • B. Liquid
  • C. Gas
  • D. Plasma
Q. In which type of reaction is the change in enthalpy equal to the heat absorbed or released at constant pressure?
  • A. Endothermic reaction
  • B. Exothermic reaction
  • C. Isothermal reaction
  • D. Adiabatic reaction
Q. Solve for x: 3(x - 1) = 2(x + 4).
  • A. -10
  • B. 10
  • C. 2
  • D. 3
Q. Solve for x: 3(x - 2) = 12.
  • A. 2
  • B. 4
  • C. 6
  • D. 8
Q. Solve for x: 5x + 2 = 3x + 10.
  • A. 4
  • B. 3
  • C. 2
  • D. 1
Q. Solve for x: x^2 - 9 = 0.
  • A. -3
  • B. 3
  • C. 0
  • D. ±3
Q. Solve for y: 4y + 8 = 24.
  • A. 2
  • B. 3
  • C. 4
  • D. 5
Q. The Arrhenius equation relates the rate constant to which of the following?
  • A. Temperature and concentration
  • B. Temperature and activation energy
  • C. Concentration and pressure
  • D. Temperature and volume
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