Q. In which scenario would ΔG = 0?
A.
At the start of a reaction.
B.
At equilibrium.
C.
When the reaction is spontaneous.
D.
When the reaction is non-spontaneous.
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Solution
ΔG = 0 occurs at equilibrium, where the forward and reverse reactions occur at the same rate.
Correct Answer: B — At equilibrium.
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Q. In which scenario would ΔG be equal to ΔH?
A.
At absolute zero.
B.
When ΔS = 0.
C.
For a spontaneous reaction.
D.
For an endothermic reaction.
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Solution
ΔG equals ΔH when the entropy change (ΔS) is zero, indicating no change in disorder.
Correct Answer: B — When ΔS = 0.
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Q. In which scenario would ΔG be zero?
A.
At standard conditions
B.
At equilibrium
C.
In a spontaneous reaction
D.
In a non-spontaneous reaction
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Solution
ΔG is zero at equilibrium, indicating no net change in the concentrations of reactants and products.
Correct Answer: B — At equilibrium
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Q. The enthalpy change for a reaction can be calculated using which of the following?
A.
Bond energies
B.
Standard enthalpies of formation
C.
Calorimetry
D.
All of the above
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Solution
The enthalpy change for a reaction can be calculated using bond energies, standard enthalpies of formation, and calorimetry.
Correct Answer: D — All of the above
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Q. The enthalpy change for the reaction A + B → C is +50 kJ/mol. What can be said about the reaction?
A.
It is exothermic
B.
It is endothermic
C.
It is spontaneous
D.
It is at equilibrium
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Solution
A positive enthalpy change indicates that the reaction absorbs heat, thus it is endothermic.
Correct Answer: B — It is endothermic
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Q. The enthalpy of vaporization of a substance is defined as:
A.
The heat required to melt the substance
B.
The heat required to convert a liquid into a gas
C.
The heat released during condensation
D.
The heat required to raise the temperature of a substance
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Solution
The enthalpy of vaporization is the heat required to convert a liquid into a gas at constant temperature and pressure.
Correct Answer: B — The heat required to convert a liquid into a gas
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Q. The enthalpy of vaporization of water is approximately ____ kJ/mol.
A.
40.79
B.
60.79
C.
80.79
D.
100.79
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Solution
The enthalpy of vaporization of water is approximately 40.79 kJ/mol.
Correct Answer: A — 40.79
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Q. The enthalpy of vaporization of water is approximately:
A.
40.79 kJ/mol
B.
2260 kJ/mol
C.
100 kJ/mol
D.
60 kJ/mol
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Solution
The enthalpy of vaporization of water is approximately 2260 kJ/mol.
Correct Answer: B — 2260 kJ/mol
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Q. The entropy change for a phase transition at constant temperature is given by:
A.
ΔS = ΔH/T
B.
ΔS = T/ΔH
C.
ΔS = ΔH*T
D.
ΔS = ΔH + T
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Solution
For a phase transition at constant temperature, the change in entropy is given by ΔS = ΔH/T, where ΔH is the enthalpy change.
Correct Answer: A — ΔS = ΔH/T
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Q. The entropy change for a reaction can be calculated using which of the following?
A.
ΔS = ΣS(products) - ΣS(reactants)
B.
ΔS = ΣS(reactants) - ΣS(products)
C.
ΔS = Q/T
D.
ΔS = W/T
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Solution
The change in entropy for a reaction is calculated using the formula ΔS = ΣS(products) - ΣS(reactants).
Correct Answer: A — ΔS = ΣS(products) - ΣS(reactants)
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Q. The entropy of a perfect crystal at absolute zero is given by:
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Solution
According to the third law of thermodynamics, the entropy of a perfect crystal at absolute zero is zero.
Correct Answer: B — 0
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Q. The entropy of a perfect crystal at absolute zero is:
A.
Maximum
B.
Minimum
C.
Undefined
D.
Infinite
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Solution
According to the third law of thermodynamics, the entropy of a perfect crystal at absolute zero is zero, which is the minimum value.
Correct Answer: B — Minimum
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Q. The entropy of a perfect crystal at absolute zero temperature is given by which law?
A.
Third law of thermodynamics
B.
First law of thermodynamics
C.
Second law of thermodynamics
D.
Zeroth law of thermodynamics
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Solution
The third law of thermodynamics states that the entropy of a perfect crystal approaches zero as the temperature approaches absolute zero.
Correct Answer: A — Third law of thermodynamics
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Q. The entropy of a perfect crystal at absolute zero temperature is given by:
A.
0
B.
1
C.
Infinity
D.
Depends on the substance
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Solution
According to the third law of thermodynamics, the entropy of a perfect crystal at absolute zero is exactly zero.
Correct Answer: A — 0
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Q. The entropy of a perfect crystalline substance at absolute zero is given by which law?
A.
Third law of thermodynamics
B.
First law of thermodynamics
C.
Second law of thermodynamics
D.
Zeroth law of thermodynamics
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Solution
The third law of thermodynamics states that the entropy of a perfect crystalline substance approaches zero as the temperature approaches absolute zero.
Correct Answer: A — Third law of thermodynamics
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Q. The entropy of a perfect crystalline substance at absolute zero is:
A.
Zero
B.
Maximum
C.
Undefined
D.
Infinite
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Solution
According to the third law of thermodynamics, the entropy of a perfect crystalline substance at absolute zero is zero.
Correct Answer: A — Zero
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Q. What does a large negative value of ΔG indicate about a reaction?
A.
The reaction is highly spontaneous.
B.
The reaction is non-spontaneous.
C.
The reaction is at equilibrium.
D.
The reaction requires a catalyst.
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Solution
A large negative value of ΔG indicates that the reaction is highly spontaneous and favors the formation of products.
Correct Answer: A — The reaction is highly spontaneous.
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Q. What does a negative ΔG indicate about a chemical reaction?
A.
The reaction is at equilibrium.
B.
The reaction is non-spontaneous.
C.
The reaction is spontaneous.
D.
The reaction requires energy input.
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Solution
A negative ΔG indicates that the reaction is spontaneous under the given conditions.
Correct Answer: C — The reaction is spontaneous.
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Q. What does a positive ΔG indicate about a reaction?
A.
The reaction is spontaneous.
B.
The reaction is non-spontaneous.
C.
The reaction is at equilibrium.
D.
The reaction releases energy.
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Solution
A positive ΔG indicates that the reaction is non-spontaneous.
Correct Answer: B — The reaction is non-spontaneous.
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Q. What does a positive ΔG indicate about the spontaneity of a reaction?
A.
The reaction is spontaneous.
B.
The reaction is non-spontaneous.
C.
The reaction is at equilibrium.
D.
The reaction is exothermic.
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Solution
A positive ΔG indicates that the reaction is non-spontaneous.
Correct Answer: B — The reaction is non-spontaneous.
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Q. What does a positive ΔS indicate about a system?
A.
The system is becoming more ordered.
B.
The system is becoming more disordered.
C.
The reaction is non-spontaneous.
D.
The reaction is at equilibrium.
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Solution
A positive ΔS indicates an increase in disorder or randomness in the system.
Correct Answer: B — The system is becoming more disordered.
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Q. What does a ΔG value of zero indicate about a reaction?
A.
The reaction is spontaneous.
B.
The reaction is at equilibrium.
C.
The reaction is non-spontaneous.
D.
The reaction is exothermic.
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Solution
A ΔG value of zero indicates that the reaction is at equilibrium, meaning the forward and reverse reactions occur at the same rate.
Correct Answer: B — The reaction is at equilibrium.
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Q. What does the Gibbs free energy change indicate?
A.
Spontaneity of a reaction
B.
Rate of a reaction
C.
Equilibrium constant
D.
Activation energy
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Solution
The Gibbs free energy change indicates the spontaneity of a reaction; a negative value suggests spontaneity.
Correct Answer: A — Spontaneity of a reaction
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Q. What does the term 'enthalpy of reaction' refer to?
A.
The heat absorbed or released at constant pressure
B.
The change in internal energy
C.
The work done by the system
D.
The temperature change during a reaction
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Solution
The enthalpy of reaction refers to the heat absorbed or released at constant pressure.
Correct Answer: A — The heat absorbed or released at constant pressure
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Q. What does the term 'entropy' refer to in thermodynamics?
A.
Energy stored in a system
B.
Disorder or randomness in a system
C.
Heat content of a system
D.
Pressure of a system
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Solution
Entropy is a measure of the disorder or randomness in a system.
Correct Answer: B — Disorder or randomness in a system
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Q. What does the term 'Gibbs free energy' indicate?
A.
The total energy of a system
B.
The energy available to do work
C.
The heat content of a system
D.
The entropy of a system
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Solution
Gibbs free energy indicates the maximum reversible work that can be performed by a thermodynamic system at constant temperature and pressure.
Correct Answer: B — The energy available to do work
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Q. What effect does increasing temperature have on the Gibbs Free Energy of an endothermic reaction?
A.
ΔG increases.
B.
ΔG decreases.
C.
ΔG remains constant.
D.
ΔG becomes zero.
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Solution
For an endothermic reaction, increasing temperature generally decreases ΔG, making the reaction more favorable.
Correct Answer: B — ΔG decreases.
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Q. What happens to the entropy of a system when it undergoes an irreversible process?
A.
It decreases
B.
It remains constant
C.
It increases
D.
It becomes zero
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Solution
The entropy of a system increases when it undergoes an irreversible process.
Correct Answer: C — It increases
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Q. What is the change in enthalpy for an endothermic reaction?
A.
Negative
B.
Positive
C.
Zero
D.
Undefined
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Solution
In an endothermic reaction, heat is absorbed from the surroundings, resulting in a positive change in enthalpy.
Correct Answer: B — Positive
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Q. What is the change in enthalpy for an exothermic reaction?
A.
Positive
B.
Negative
C.
Zero
D.
Undefined
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Solution
In an exothermic reaction, heat is released, resulting in a negative change in enthalpy.
Correct Answer: B — Negative
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