Thermodynamics

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Q. In which scenario would ΔG = 0?
  • A. At the start of a reaction.
  • B. At equilibrium.
  • C. When the reaction is spontaneous.
  • D. When the reaction is non-spontaneous.
Q. In which scenario would ΔG be equal to ΔH?
  • A. At absolute zero.
  • B. When ΔS = 0.
  • C. For a spontaneous reaction.
  • D. For an endothermic reaction.
Q. In which scenario would ΔG be zero?
  • A. At standard conditions
  • B. At equilibrium
  • C. In a spontaneous reaction
  • D. In a non-spontaneous reaction
Q. The enthalpy change for a reaction can be calculated using which of the following?
  • A. Bond energies
  • B. Standard enthalpies of formation
  • C. Calorimetry
  • D. All of the above
Q. The enthalpy change for the reaction A + B → C is +50 kJ/mol. What can be said about the reaction?
  • A. It is exothermic
  • B. It is endothermic
  • C. It is spontaneous
  • D. It is at equilibrium
Q. The enthalpy of vaporization of a substance is defined as:
  • A. The heat required to melt the substance
  • B. The heat required to convert a liquid into a gas
  • C. The heat released during condensation
  • D. The heat required to raise the temperature of a substance
Q. The enthalpy of vaporization of water is approximately ____ kJ/mol.
  • A. 40.79
  • B. 60.79
  • C. 80.79
  • D. 100.79
Q. The enthalpy of vaporization of water is approximately:
  • A. 40.79 kJ/mol
  • B. 2260 kJ/mol
  • C. 100 kJ/mol
  • D. 60 kJ/mol
Q. The entropy change for a phase transition at constant temperature is given by:
  • A. ΔS = ΔH/T
  • B. ΔS = T/ΔH
  • C. ΔS = ΔH*T
  • D. ΔS = ΔH + T
Q. The entropy change for a reaction can be calculated using which of the following?
  • A. ΔS = ΣS(products) - ΣS(reactants)
  • B. ΔS = ΣS(reactants) - ΣS(products)
  • C. ΔS = Q/T
  • D. ΔS = W/T
Q. The entropy of a perfect crystal at absolute zero is given by:
  • A. R
  • B. 0
  • C.
  • D. 1
Q. The entropy of a perfect crystal at absolute zero is:
  • A. Maximum
  • B. Minimum
  • C. Undefined
  • D. Infinite
Q. The entropy of a perfect crystal at absolute zero temperature is given by which law?
  • A. Third law of thermodynamics
  • B. First law of thermodynamics
  • C. Second law of thermodynamics
  • D. Zeroth law of thermodynamics
Q. The entropy of a perfect crystal at absolute zero temperature is given by:
  • A. 0
  • B. 1
  • C. Infinity
  • D. Depends on the substance
Q. The entropy of a perfect crystalline substance at absolute zero is given by which law?
  • A. Third law of thermodynamics
  • B. First law of thermodynamics
  • C. Second law of thermodynamics
  • D. Zeroth law of thermodynamics
Q. The entropy of a perfect crystalline substance at absolute zero is:
  • A. Zero
  • B. Maximum
  • C. Undefined
  • D. Infinite
Q. What does a large negative value of ΔG indicate about a reaction?
  • A. The reaction is highly spontaneous.
  • B. The reaction is non-spontaneous.
  • C. The reaction is at equilibrium.
  • D. The reaction requires a catalyst.
Q. What does a negative ΔG indicate about a chemical reaction?
  • A. The reaction is at equilibrium.
  • B. The reaction is non-spontaneous.
  • C. The reaction is spontaneous.
  • D. The reaction requires energy input.
Q. What does a positive ΔG indicate about a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is non-spontaneous.
  • C. The reaction is at equilibrium.
  • D. The reaction releases energy.
Q. What does a positive ΔG indicate about the spontaneity of a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is non-spontaneous.
  • C. The reaction is at equilibrium.
  • D. The reaction is exothermic.
Q. What does a positive ΔS indicate about a system?
  • A. The system is becoming more ordered.
  • B. The system is becoming more disordered.
  • C. The reaction is non-spontaneous.
  • D. The reaction is at equilibrium.
Q. What does a ΔG value of zero indicate about a reaction?
  • A. The reaction is spontaneous.
  • B. The reaction is at equilibrium.
  • C. The reaction is non-spontaneous.
  • D. The reaction is exothermic.
Q. What does the Gibbs free energy change indicate?
  • A. Spontaneity of a reaction
  • B. Rate of a reaction
  • C. Equilibrium constant
  • D. Activation energy
Q. What does the term 'enthalpy of reaction' refer to?
  • A. The heat absorbed or released at constant pressure
  • B. The change in internal energy
  • C. The work done by the system
  • D. The temperature change during a reaction
Q. What does the term 'entropy' refer to in thermodynamics?
  • A. Energy stored in a system
  • B. Disorder or randomness in a system
  • C. Heat content of a system
  • D. Pressure of a system
Q. What does the term 'Gibbs free energy' indicate?
  • A. The total energy of a system
  • B. The energy available to do work
  • C. The heat content of a system
  • D. The entropy of a system
Q. What effect does increasing temperature have on the Gibbs Free Energy of an endothermic reaction?
  • A. ΔG increases.
  • B. ΔG decreases.
  • C. ΔG remains constant.
  • D. ΔG becomes zero.
Q. What happens to the entropy of a system when it undergoes an irreversible process?
  • A. It decreases
  • B. It remains constant
  • C. It increases
  • D. It becomes zero
Q. What is the change in enthalpy for an endothermic reaction?
  • A. Negative
  • B. Positive
  • C. Zero
  • D. Undefined
Q. What is the change in enthalpy for an exothermic reaction?
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Undefined
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