Q. Which of the following compounds is an aldehyde?
-
A.
C2H5OH
-
B.
CH3CHO
-
C.
C3H6O
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D.
C6H12O6
Solution
The compound CH3CHO is an aldehyde, characterized by the presence of the -CHO functional group.
Correct Answer: B — CH3CHO
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Q. Which of the following compounds is an example of a ketone?
-
A.
Propanal
-
B.
Butan-2-one
-
C.
Benzaldehyde
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D.
Acetic acid
Solution
Butan-2-one is a ketone as it has the carbonyl group (C=O) located between two carbon atoms.
Correct Answer: B — Butan-2-one
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Q. Which of the following is a characteristic reaction of ketones?
-
A.
Oxidation to carboxylic acids
-
B.
Reduction to alcohols
-
C.
Formation of hemiacetals
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D.
Formation of aldehydes
Solution
Ketones can react with alcohols to form hemiacetals, which is a characteristic reaction.
Correct Answer: C — Formation of hemiacetals
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Q. Which of the following is a ketone?
-
A.
Propionaldehyde
-
B.
Butanal
-
C.
Acetone
-
D.
Formaldehyde
Solution
Acetone (CH3COCH3) is a ketone.
Correct Answer: C — Acetone
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Q. Which of the following is a method for preparing aldehydes?
-
A.
Hydration of alkynes
-
B.
Oxidation of primary alcohols
-
C.
Reduction of carboxylic acids
-
D.
Dehydration of alcohols
Solution
Aldehydes can be prepared by the oxidation of primary alcohols.
Correct Answer: B — Oxidation of primary alcohols
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Q. Which of the following is a method for synthesizing aldehydes?
-
A.
Hydration of alkynes
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B.
Hydrolysis of esters
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C.
Reduction of carboxylic acids
-
D.
Oxidation of primary alcohols
Solution
Aldehydes can be synthesized by the hydration of alkynes.
Correct Answer: A — Hydration of alkynes
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Q. Which of the following is a method for the synthesis of ketones?
-
A.
Oxidation of primary alcohols
-
B.
Hydration of alkynes
-
C.
Reduction of carboxylic acids
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D.
Dehydration of alcohols
Solution
The hydration of alkynes leads to the formation of ketones, especially when using a catalyst.
Correct Answer: B — Hydration of alkynes
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Q. Which of the following is a method to distinguish between aldehydes and ketones?
-
A.
Benedict's test
-
B.
Tollens' test
-
C.
Iodoform test
-
D.
Fehling's test
Solution
Tollens' test can be used to distinguish between aldehydes and ketones, as aldehydes reduce Tollens' reagent.
Correct Answer: B — Tollens' test
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Q. Which of the following is a method to prepare aldehydes?
-
A.
Hydration of alkynes
-
B.
Hydrolysis of nitriles
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C.
Oxidation of primary alcohols
-
D.
All of the above
Solution
All of the listed methods can be used to prepare aldehydes.
Correct Answer: D — All of the above
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Q. Which of the following is a reducing agent for aldehydes?
-
A.
H2
-
B.
KMnO4
-
C.
Na2Cr2O7
-
D.
HCl
Solution
Hydrogen gas (H2) can act as a reducing agent for aldehydes, converting them to alcohols.
Correct Answer: A — H2
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Q. Which of the following is a reducing agent that can reduce ketones?
-
A.
H2/Pd
-
B.
KMnO4
-
C.
Na2Cr2O7
-
D.
AgNO3
Solution
H2 in the presence of palladium (Pd) is a reducing agent that can reduce ketones to alcohols.
Correct Answer: A — H2/Pd
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Q. Which of the following is the correct IUPAC name for CH3CHO?
-
A.
Ethanal
-
B.
Propanal
-
C.
Butanal
-
D.
Methanal
Solution
The correct IUPAC name for CH3CHO is Ethanal.
Correct Answer: A — Ethanal
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Q. Which of the following is the functional group of aldehydes?
-
A.
-CHO
-
B.
-CO-
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C.
-C=O
-
D.
-OH
Solution
Aldehydes contain the functional group -CHO, which is characterized by a carbonyl group (C=O) bonded to a hydrogen atom.
Correct Answer: A — -CHO
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Q. Which of the following is the simplest ketone?
-
A.
Ethanal
-
B.
Propanal
-
C.
Butan-2-one
-
D.
Acetone
Solution
Acetone (propan-2-one) is the simplest ketone, with the formula (CH3)2CO.
Correct Answer: D — Acetone
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Q. Which of the following statements is true about aldehydes?
-
A.
They cannot form hydrogen bonds
-
B.
They are generally more reactive than ketones
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C.
They have higher boiling points than ketones
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D.
They are less soluble in water than ketones
Solution
Aldehydes are generally more reactive than ketones due to the presence of the hydrogen atom attached to the carbonyl carbon.
Correct Answer: B — They are generally more reactive than ketones
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Q. Which of the following statements is true about ketones?
-
A.
They can be oxidized to carboxylic acids
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B.
They have a higher boiling point than aldehydes
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C.
They cannot form hydrogen bonds
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D.
They are more reactive than aldehydes
Solution
Ketones cannot form hydrogen bonds with themselves due to the absence of a hydrogen atom attached to the carbonyl carbon.
Correct Answer: C — They cannot form hydrogen bonds
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Q. Which reagent is commonly used to convert an aldehyde to a primary alcohol?
-
A.
KMnO4
-
B.
LiAlH4
-
C.
NaBH4
-
D.
H2SO4
Solution
Sodium borohydride (NaBH4) is commonly used to reduce aldehydes to primary alcohols.
Correct Answer: C — NaBH4
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Q. Which reagent is commonly used to distinguish between aldehydes and ketones?
-
A.
Benedict's solution
-
B.
Tollens' reagent
-
C.
Fehling's solution
-
D.
All of the above
Solution
All of the mentioned reagents can be used to distinguish between aldehydes and ketones, as aldehydes can be oxidized while ketones cannot.
Correct Answer: D — All of the above
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Q. Which reagent is commonly used to oxidize aldehydes to carboxylic acids?
-
A.
KMnO4
-
B.
NaBH4
-
C.
LiAlH4
-
D.
H2
Solution
Potassium permanganate (KMnO4) is a strong oxidizing agent that can oxidize aldehydes to carboxylic acids.
Correct Answer: A — KMnO4
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Q. Which reagent is commonly used to oxidize primary alcohols to aldehydes?
-
A.
KMnO4
-
B.
PCC
-
C.
Na2Cr2O7
-
D.
H2SO4
Solution
Pyridinium chlorochromate (PCC) is a mild oxidizing agent that selectively oxidizes primary alcohols to aldehydes.
Correct Answer: B — PCC
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Q. Which reagent is commonly used to reduce aldehydes to primary alcohols?
-
A.
LiAlH4
-
B.
KMnO4
-
C.
NaBH4
-
D.
H2SO4
Solution
Sodium borohydride (NaBH4) is commonly used to reduce aldehydes to primary alcohols.
Correct Answer: C — NaBH4
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Q. Which reagent is commonly used to test for aldehydes?
-
A.
Benedict's solution
-
B.
Tollens' reagent
-
C.
Fehling's solution
-
D.
All of the above
Solution
All of the mentioned reagents can be used to test for aldehydes.
Correct Answer: D — All of the above
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Q. Which reagent is used to convert an aldehyde to a primary alcohol?
-
A.
LiAlH4
-
B.
NaBH4
-
C.
H2/Pd
-
D.
All of the above
Solution
All of the above reagents can reduce an aldehyde to a primary alcohol.
Correct Answer: D — All of the above
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Q. Which reagent is used to distinguish between aldehydes and ketones?
-
A.
Benedict's solution
-
B.
Tollens' reagent
-
C.
Fehling's solution
-
D.
All of the above
Solution
All of the mentioned reagents can be used to distinguish between aldehydes and ketones, as aldehydes reduce these reagents while ketones do not.
Correct Answer: D — All of the above
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