Aromatic Compounds and Electrophilic Substitution - Applications
Q. In the nitration of benzene, which reagent is used to generate the nitronium ion?
A.
HNO3
B.
H2SO4
C.
HCl
D.
NaNO2
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Solution
In the nitration of benzene, concentrated sulfuric acid (H2SO4) is used to generate the nitronium ion (NO2+) from nitric acid (HNO3).
Correct Answer: B — H2SO4
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Q. In the nitration of toluene, which position is predominantly substituted?
A.
Ortho
B.
Meta
C.
Para
D.
All equally
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Solution
The para position is predominantly substituted due to steric hindrance at the ortho position, making the para product more favorable.
Correct Answer: C — Para
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Q. What is the effect of a nitro group on the reactivity of a benzene ring in electrophilic substitution?
A.
Activates the ring
B.
Deactivates the ring
C.
No effect
D.
Makes the ring non-reactive
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Solution
A nitro group is a strong electron-withdrawing group that deactivates the benzene ring, making it less reactive towards electrophilic substitution.
Correct Answer: B — Deactivates the ring
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Q. What is the IUPAC name of the compound with the formula C6H5NO2?
A.
Nitrobenzene
B.
Aniline
C.
Benzamide
D.
Benzonitrile
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Solution
The IUPAC name of C6H5NO2 is nitrobenzene, which contains a nitro group (-NO2) attached to a benzene ring.
Correct Answer: A — Nitrobenzene
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Q. What is the product of the Friedel-Crafts acylation of benzene with acetyl chloride?
A.
Acetophenone
B.
Benzophenone
C.
Benzyl acetate
D.
Phenyl acetate
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Solution
The product of the Friedel-Crafts acylation of benzene with acetyl chloride is acetophenone, where an acyl group is introduced to the benzene ring.
Correct Answer: A — Acetophenone
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Q. What is the role of a catalyst in electrophilic aromatic substitution reactions?
A.
To stabilize the product
B.
To generate the electrophile
C.
To increase the temperature
D.
To decrease the reaction time
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Solution
The catalyst in electrophilic aromatic substitution reactions, such as AlCl3 or FeBr3, is used to generate the electrophile that will react with the aromatic compound.
Correct Answer: B — To generate the electrophile
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Q. Which of the following compounds undergoes electrophilic substitution more readily than benzene?
A.
Toluene
B.
Cyclohexane
C.
Phenol
D.
Naphthalene
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Solution
Phenol is more reactive than benzene due to the electron-donating effect of the hydroxyl group, which stabilizes the carbocation intermediate.
Correct Answer: C — Phenol
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Q. Which of the following compounds undergoes electrophilic substitution most readily?
A.
Toluene
B.
Benzene
C.
Nitrobenzene
D.
Chlorobenzene
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Solution
Toluene undergoes electrophilic substitution most readily due to the electron-donating effect of the methyl group, which activates the benzene ring.
Correct Answer: A — Toluene
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Q. Which of the following reactions is an example of electrophilic aromatic substitution?
A.
Hydrogenation of benzene
B.
Nitration of benzene
C.
Oxidation of toluene
D.
Reduction of nitrobenzene
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Solution
Nitration of benzene is an example of electrophilic aromatic substitution, where a nitro group replaces a hydrogen atom on the benzene ring.
Correct Answer: B — Nitration of benzene
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