Major Competitive Exams
Q. Which of the following has a central atom with sp3d hybridization?
-
A.
XeF4
-
B.
SF4
-
C.
PCl5
-
D.
BrF5
Solution
In BrF5, bromine undergoes sp3d hybridization to form five bonds with fluorine and has one lone pair.
Correct Answer: D — BrF5
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Q. Which of the following has a central atom with sp3d2 hybridization?
-
A.
XeF2
-
B.
SF6
-
C.
BrF5
-
D.
PCl5
Solution
In BrF5, the bromine atom is sp3d2 hybridized, allowing it to form five bonds with fluorine.
Correct Answer: C — BrF5
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Q. Which of the following has a linear molecular geometry?
-
A.
BeCl2
-
B.
NH3
-
C.
H2O
-
D.
CH4
Solution
BeCl2 has two bonding pairs and no lone pairs, resulting in a linear geometry.
Correct Answer: A — BeCl2
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Q. Which of the following has a molecular geometry that is not symmetrical?
-
A.
CCl4
-
B.
NH3
-
C.
CO2
-
D.
BF3
Solution
NH3 has a trigonal pyramidal shape, which is not symmetrical due to the lone pair.
Correct Answer: B — NH3
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Q. Which of the following has a pyramidal shape?
-
A.
CH4
-
B.
H2O
-
C.
NH3
-
D.
CO2
Solution
NH3 has three bonding pairs and one lone pair, resulting in a trigonal pyramidal shape.
Correct Answer: C — NH3
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Q. Which of the following has a seesaw molecular geometry?
-
A.
SF4
-
B.
ClF3
-
C.
NH4+
-
D.
XeF2
Solution
SF4 has four bonding pairs and one lone pair, resulting in a seesaw molecular geometry.
Correct Answer: A — SF4
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Q. Which of the following has a seesaw shape according to VSEPR theory?
-
A.
SF4
-
B.
PCl5
-
C.
XeF2
-
D.
NH3
Solution
SF4 has four bonding pairs and one lone pair, resulting in a seesaw shape.
Correct Answer: A — SF4
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Q. Which of the following has a seesaw shape?
-
A.
SF4
-
B.
PCl5
-
C.
XeF4
-
D.
NH3
Solution
SF4 has four bonding pairs and one lone pair, resulting in a seesaw shape.
Correct Answer: A — SF4
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Q. Which of the following has a square planar geometry?
-
A.
XeF4
-
B.
SF4
-
C.
ClF3
-
D.
BrF5
Solution
XeF4 has four bonding pairs and two lone pairs, resulting in a square planar geometry.
Correct Answer: A — XeF4
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Q. Which of the following has a tetrahedral shape due to hybridization?
-
A.
NH3
-
B.
H2O
-
C.
CH4
-
D.
BF3
Solution
CH4 has a tetrahedral shape due to the sp3 hybridization of the carbon atom.
Correct Answer: C — CH4
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Q. Which of the following has a tetrahedral shape?
-
A.
CH4
-
B.
C2H4
-
C.
NH3
-
D.
H2O
Solution
CH4 has a tetrahedral shape due to the sp3 hybridization of the carbon atom.
Correct Answer: A — CH4
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Q. Which of the following has a trigonal bipyramidal geometry?
-
A.
PCl5
-
B.
NH3
-
C.
H2O
-
D.
CO2
Solution
PCl5 has five bonding pairs and no lone pairs, resulting in a trigonal bipyramidal geometry.
Correct Answer: A — PCl5
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Q. Which of the following has a trigonal planar geometry?
-
A.
CH4
-
B.
BF3
-
C.
NH3
-
D.
H2O
Solution
BF3 has a trigonal planar geometry due to sp2 hybridization of boron.
Correct Answer: B — BF3
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Q. Which of the following has an incomplete d-subshell?
-
A.
Scandium
-
B.
Titanium
-
C.
Vanadium
-
D.
Chromium
Solution
Chromium (Cr) has an electronic configuration of [Ar] 4s1 3d5, which means it has an incomplete d-subshell.
Correct Answer: D — Chromium
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Q. Which of the following has sp hybridization?
-
A.
C2H2
-
B.
C2H4
-
C.
CH4
-
D.
NH3
Solution
C2H2 has sp hybridization, with a triple bond between the two carbon atoms.
Correct Answer: A — C2H2
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Q. Which of the following has the electronic configuration 1s2 2s2 2p6 3s2 3p6?
-
A.
Neon
-
B.
Argon
-
C.
Krypton
-
D.
Xenon
Solution
Argon has 18 electrons, and its electronic configuration is 1s2 2s2 2p6 3s2 3p6.
Correct Answer: B — Argon
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Q. Which of the following has the electronic configuration ending in 4p5?
Solution
Bromine (Br) has the atomic number 35, and its configuration ends in 4p5.
Correct Answer: A — Br
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Q. Which of the following has the electronic configuration of [Kr] 5s2 4d10 5p5?
-
A.
Iodine
-
B.
Xenon
-
C.
Bromine
-
D.
Astatine
Solution
The element with the configuration [Kr] 5s2 4d10 5p5 is Astatine.
Correct Answer: D — Astatine
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Q. Which of the following has the electronic configuration [Kr] 5s2 4d10 5p5?
-
A.
Iodine
-
B.
Bromine
-
C.
Astatine
-
D.
Tellurium
Solution
The configuration [Kr] 5s2 4d10 5p5 corresponds to Astatine.
Correct Answer: C — Astatine
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Q. Which of the following has the electronic configuration [Xe] 4f14 5d10 6s2?
Solution
Mercury (Hg) has the electronic configuration [Xe] 4f14 5d10 6s2.
Correct Answer: B — Hg
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Q. Which of the following has the electronic configuration [Xe] 6s2 4f14 5d10?
-
A.
Lead
-
B.
Bismuth
-
C.
Radon
-
D.
Plutonium
Solution
Bismuth (Bi) has the electronic configuration [Xe] 6s2 4f14 5d10.
Correct Answer: B — Bismuth
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Q. Which of the following has the highest boiling point?
-
A.
H2O
-
B.
CH4
-
C.
NH3
-
D.
CO2
Solution
Water has the highest boiling point due to strong hydrogen bonding between its molecules.
Correct Answer: A — H2O
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Q. Which of the following has the highest bond energy? (2023)
-
A.
C-H
-
B.
C-C
-
C.
C=N
-
D.
C≡C
Solution
C≡C (triple bond) has the highest bond energy due to the strong attraction between the two carbon atoms.
Correct Answer: D — C≡C
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Q. Which of the following has the highest bond order?
Solution
N2 has the highest bond order of 3 among the given options.
Correct Answer: A — N2
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Q. Which of the following has the highest electronegativity?
-
A.
Fluorine
-
B.
Oxygen
-
C.
Nitrogen
-
D.
Chlorine
Solution
Fluorine has the highest electronegativity of all elements.
Correct Answer: A — Fluorine
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Q. Which of the following has the highest energy electron configuration?
-
A.
1s2 2s2 2p6 3s2 3p6
-
B.
1s2 2s2 2p6 3s2 3p5
-
C.
1s2 2s2 2p6 3s2 3p4
-
D.
1s2 2s2 2p6 3s2 3p3
Solution
The configuration 1s2 2s2 2p6 3s2 3p5 (Chlorine) has the highest energy due to the presence of an unpaired electron.
Correct Answer: B — 1s2 2s2 2p6 3s2 3p5
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Q. Which of the following has the highest energy electron in the 4p subshell?
Solution
Selenium (Se) has the highest energy electron in the 4p subshell with the configuration [Ar] 4s2 3d10 4p4.
Correct Answer: C — Se
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Q. Which of the following has the highest enthalpy of formation?
-
A.
O2(g)
-
B.
H2(g)
-
C.
C(s)
-
D.
CO2(g)
Solution
CO2(g) has a higher enthalpy of formation compared to the elements in their standard states.
Correct Answer: D — CO2(g)
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Q. Which of the following has the highest entropy at 25°C?
-
A.
Ice
-
B.
Water
-
C.
Steam
-
D.
All have the same entropy
Solution
Steam has the highest entropy at 25°C because it is in the gaseous state, which has more disorder compared to solid (ice) and liquid (water).
Correct Answer: C — Steam
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Q. Which of the following has the highest entropy at 298 K?
-
A.
Ice (solid H2O)
-
B.
Liquid water (H2O)
-
C.
Water vapor (H2O(g))
-
D.
None of the above
Solution
Water vapor has the highest entropy because gases have greater disorder compared to liquids and solids.
Correct Answer: C — Water vapor (H2O(g))
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