Q. Which of the following compounds is stabilized by +M effect?
-
A.
Phenol
-
B.
Acetic acid
-
C.
Nitrobenzene
-
D.
Benzaldehyde
Solution
Phenol is stabilized by the +M effect due to the presence of the -OH group which donates electron density.
Correct Answer: A — Phenol
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Q. Which of the following compounds is the most acidic?
-
A.
Ethylene
-
B.
Propene
-
C.
Propyne
-
D.
Butyne
Solution
Propyne is the most acidic due to the sp hybridization of the carbon atom involved in the triple bond.
Correct Answer: C — Propyne
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Q. Which of the following compounds is used as a flavoring agent in food?
-
A.
Vanillin
-
B.
Acetic acid
-
C.
Sodium chloride
-
D.
Citric acid
Solution
Vanillin is the primary component of the extract of the vanilla bean and is used as a flavoring agent.
Correct Answer: A — Vanillin
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Q. Which of the following compounds is used as a food colorant?
-
A.
Carotenoids
-
B.
Sodium chloride
-
C.
Vinegar
-
D.
Citric acid
Solution
Carotenoids are natural pigments used as food colorants.
Correct Answer: A — Carotenoids
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Q. Which of the following compounds is used as a sweetener?
-
A.
Aspartame
-
B.
Sodium chloride
-
C.
Vinegar
-
D.
Citric acid
Solution
Aspartame is a widely used artificial sweetener in many food products.
Correct Answer: A — Aspartame
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Q. Which of the following compounds is used in the treatment of heartburn?
-
A.
Sodium bicarbonate
-
B.
Calcium carbonate
-
C.
Magnesium hydroxide
-
D.
All of the above
Solution
All of the listed compounds are antacids used to treat heartburn.
Correct Answer: D — All of the above
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Q. Which of the following compounds shows both -I and +M effects?
-
A.
Acetic acid
-
B.
Nitrobenzene
-
C.
Anisole
-
D.
Benzaldehyde
Solution
Benzaldehyde shows a -I effect due to the carbonyl group and a +M effect due to the aromatic ring.
Correct Answer: D — Benzaldehyde
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Q. Which of the following compounds will be most stable due to resonance?
-
A.
C6H5NO2
-
B.
C6H5Cl
-
C.
C6H5OH
-
D.
C6H5CH3
Solution
C6H5NO2 is most stable due to the strong electron-withdrawing effect of the -NO2 group, which stabilizes the negative charge through resonance.
Correct Answer: A — C6H5NO2
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Q. Which of the following compounds will have the highest electron density at the ortho position due to +M effect?
-
A.
C6H5NO2
-
B.
C6H5OH
-
C.
C6H5Cl
-
D.
C6H5CH3
Solution
C6H5OH has the highest electron density at the ortho position due to the +M effect of the -OH group.
Correct Answer: B — C6H5OH
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Q. Which of the following compounds will have the highest electron density due to +M effect?
-
A.
Phenol
-
B.
Benzaldehyde
-
C.
Nitrobenzene
-
D.
Aniline
Solution
Aniline has the highest electron density due to the +M effect of the amino group.
Correct Answer: D — Aniline
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Q. Which of the following compounds will undergo nucleophilic substitution via an SN1 mechanism?
-
A.
1-chloropropane
-
B.
2-chloropropane
-
C.
3-chloropropane
-
D.
chlorobenzene
Solution
3-chloropropane is a tertiary haloalkane, which favors the SN1 mechanism due to the formation of a stable tertiary carbocation.
Correct Answer: C — 3-chloropropane
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Q. Which of the following compounds would be most acidic due to the inductive effect?
-
A.
CH3COOH
-
B.
ClCH2COOH
-
C.
FCH2COOH
-
D.
BrCH2COOH
Solution
FCH2COOH is the most acidic due to the strong -I effect of the fluorine atom.
Correct Answer: C — FCH2COOH
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Q. Which of the following compounds would be most stabilized by +M effect?
-
A.
Phenol
-
B.
Acetic acid
-
C.
Chloroethane
-
D.
Nitrobenzene
Solution
Phenol is stabilized by the +M effect due to the presence of the -OH group, which donates electron density.
Correct Answer: A — Phenol
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Q. Which of the following ethers is commonly used as an anesthetic?
-
A.
Diethyl ether
-
B.
Methyl ethyl ether
-
C.
Phenyl ether
-
D.
Tert-butyl ether
Solution
Diethyl ether is well-known for its use as a general anesthetic in the past.
Correct Answer: A — Diethyl ether
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Q. Which of the following groups exhibits a -I effect?
-
A.
-OH
-
B.
-NO2
-
C.
-CH3
-
D.
-Cl
Solution
The -NO2 group is a strong electron-withdrawing group that exhibits a -I effect.
Correct Answer: B — -NO2
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Q. Which of the following groups exhibits a strong +M effect?
-
A.
-NO2
-
B.
-OH
-
C.
-CN
-
D.
-COOH
Solution
The -OH group exhibits a strong +M effect due to its ability to donate electron density through resonance.
Correct Answer: B — -OH
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Q. Which of the following groups exhibits a strong -I effect?
-
A.
–NO2
-
B.
–CH3
-
C.
–OH
-
D.
–NH2
Solution
The –NO2 group is a strong electron-withdrawing group and exhibits a strong -I effect.
Correct Answer: A — –NO2
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Q. Which of the following groups has a -I effect?
-
A.
-NH2
-
B.
-F
-
C.
-OCH3
-
D.
-C2H5
Solution
-F exhibits a -I effect as it withdraws electron density from the rest of the molecule.
Correct Answer: B — -F
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Q. Which of the following groups has both +M and -I effects?
-
A.
-NH2
-
B.
-NO2
-
C.
-COOH
-
D.
-F
Solution
The -NH2 group has a +M effect due to resonance donation and a -I effect due to its electronegativity.
Correct Answer: A — -NH2
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Q. Which of the following groups has the strongest -I effect?
-
A.
-F
-
B.
-Cl
-
C.
-Br
-
D.
-I
Solution
-F has the strongest -I effect due to its high electronegativity.
Correct Answer: A — -F
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Q. Which of the following groups is a strong +M (mesomeric) director?
-
A.
–NO2
-
B.
–OH
-
C.
–COOH
-
D.
–CN
Solution
The –OH group is a strong +M director as it donates electron density through resonance.
Correct Answer: B — –OH
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Q. Which of the following groups is a strong -I group?
-
A.
-F
-
B.
-CH3
-
C.
-OCH3
-
D.
-Br
Solution
The -F group is a strong -I group due to its high electronegativity.
Correct Answer: A — -F
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Q. Which of the following groups is a strong -M group?
-
A.
-OH
-
B.
-OCH3
-
C.
-NO2
-
D.
-NH2
Solution
-NO2 is a strong -M group as it withdraws electron density through resonance.
Correct Answer: C — -NO2
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Q. Which of the following groups is a strong electron-donating group?
-
A.
–NO2
-
B.
–OH
-
C.
–CN
-
D.
–COOH
Solution
The –OH group is a strong electron-donating group through resonance (+M effect).
Correct Answer: B — –OH
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Q. Which of the following groups is a weak +M director?
-
A.
-OH
-
B.
-OCH3
-
C.
-NH2
-
D.
-CH3
Solution
-CH3 is a weak +M director as it can donate some electron density but is less effective than -OH or -OCH3.
Correct Answer: D — -CH3
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Q. Which of the following groups is a weak -I effect group?
-
A.
–F
-
B.
–Cl
-
C.
–Br
-
D.
–I
Solution
The –I effect decreases in strength down the group in the halogens, making –I the weakest -I group.
Correct Answer: D — –I
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Q. Which of the following groups is a weak -I effect?
-
A.
-CH3
-
B.
-Cl
-
C.
-Br
-
D.
-I
Solution
The -CH3 group exhibits a weak -I effect as it is a weak electron-donating group.
Correct Answer: A — -CH3
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Q. Which of the following groups is a weak -M group?
-
A.
-CHO
-
B.
-COOH
-
C.
-NO2
-
D.
-F
Solution
-F is a weak -M group as it has a slight electron-withdrawing effect but is not as strong as -CHO or -COOH.
Correct Answer: D — -F
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Q. Which of the following groups is considered a weak -I group?
-
A.
-NO2
-
B.
-CN
-
C.
-F
-
D.
-COOH
Solution
-F is considered a weak -I group compared to -NO2 and -CN.
Correct Answer: C — -F
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Q. Which of the following groups is known for its +I effect?
-
A.
-CH3
-
B.
-OH
-
C.
-NO2
-
D.
-COOH
Solution
-CH3 exhibits a +I effect as it donates electron density through inductive effect.
Correct Answer: A — -CH3
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