Transition Elements and Coordination Chemistry Basics - Real World Applications
Q. In redox reactions, what happens to the oxidation state of a transition metal when it acts as a reducing agent?
A.
It increases
B.
It decreases
C.
It remains the same
D.
It becomes zero
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Solution
When a transition metal acts as a reducing agent, it donates electrons, resulting in a decrease in its oxidation state.
Correct Answer: B — It decreases
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Q. What is the coordination number of a metal in a complex with an octahedral geometry?
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Solution
In an octahedral complex, the coordination number is 6, as there are six ligands surrounding the central metal atom.
Correct Answer: C — 6
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Q. What is the coordination number of the metal ion in the complex [Co(NH3)6]Cl3?
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Solution
The coordination number of the metal ion in [Co(NH3)6]Cl3 is 6, as it is surrounded by six ammonia ligands.
Correct Answer: C — 6
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Q. What is the primary role of ligands in coordination chemistry?
A.
To increase the oxidation state
B.
To stabilize the metal center
C.
To provide electrons for bonding
D.
To change the color of the complex
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Solution
Ligands provide electron pairs to the metal center, forming coordinate covalent bonds and stabilizing the metal complex.
Correct Answer: C — To provide electrons for bonding
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Q. What type of bond is primarily formed between a transition metal and a ligand in coordination complexes?
A.
Ionic bond
B.
Covalent bond
C.
Metallic bond
D.
Coordinate covalent bond
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Solution
In coordination complexes, the bond formed between a transition metal and a ligand is primarily a coordinate covalent bond, where the ligand donates a pair of electrons.
Correct Answer: D — Coordinate covalent bond
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Q. What type of reaction occurs when a transition metal complex is reduced?
A.
Oxidation
B.
Reduction
C.
Hydrolysis
D.
Precipitation
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Solution
Reduction of a transition metal complex involves the gain of electrons, which is the definition of a reduction reaction.
Correct Answer: B — Reduction
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Q. Which of the following is a common application of coordination compounds in medicine?
A.
Antacids
B.
Chemotherapy drugs
C.
Pain relievers
D.
Antibiotics
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Solution
Coordination compounds are commonly used in chemotherapy drugs, such as cisplatin, which is used to treat various cancers.
Correct Answer: B — Chemotherapy drugs
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Q. Which of the following ligands is considered a strong field ligand?
A.
Iodide
B.
Water
C.
Cyanide
D.
Chloride
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Solution
Cyanide (CN-) is a strong field ligand that causes greater splitting of d-orbitals in transition metal complexes.
Correct Answer: C — Cyanide
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Q. Which of the following transition metals is commonly used as a catalyst in the Haber process?
A.
Iron
B.
Nickel
C.
Copper
D.
Cobalt
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Solution
Iron is the transition metal used as a catalyst in the Haber process for synthesizing ammonia from nitrogen and hydrogen.
Correct Answer: A — Iron
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Q. Which of the following transition metals is commonly used as a catalyst in the Haber process for ammonia synthesis?
A.
Iron
B.
Copper
C.
Nickel
D.
Cobalt
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Solution
Iron is used as a catalyst in the Haber process to synthesize ammonia from nitrogen and hydrogen.
Correct Answer: A — Iron
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Q. Which of the following transition metals is known for forming colored compounds due to d-d electron transitions?
A.
Zinc
B.
Copper
C.
Calcium
D.
Barium
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Solution
Copper is a transition metal that forms colored compounds due to the presence of partially filled d-orbitals, allowing for d-d electron transitions.
Correct Answer: B — Copper
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Q. Which of the following transition metals is most commonly associated with the formation of colored compounds?
A.
Calcium
B.
Sodium
C.
Iron
D.
Barium
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Solution
Iron is a transition metal that is commonly associated with the formation of colored compounds due to its variable oxidation states.
Correct Answer: C — Iron
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Q. Which transition metal is known for its ability to form complex ions with a variety of ligands and is used in biological systems?
A.
Zinc
B.
Iron
C.
Copper
D.
Manganese
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Solution
Copper is known for its ability to form complex ions and plays a crucial role in biological systems, such as in hemocyanin.
Correct Answer: C — Copper
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