Q. Which of the following groups shows +M effect?
A.
-NO2
B.
-CN
C.
-OCH3
D.
-COOH
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Solution
The -OCH3 group shows +M effect as it donates electrons through resonance.
Correct Answer: C — -OCH3
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Q. Which of the following groups shows a +M effect?
A.
–NO2
B.
–F
C.
–OH
D.
–CN
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Solution
The –OH group donates electron density through resonance, exhibiting a +M effect.
Correct Answer: C — –OH
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Q. Which of the following groups would decrease the electron density on a benzene ring?
A.
-OCH3
B.
-NO2
C.
-CH3
D.
-Cl
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Solution
-NO2 is a strong electron-withdrawing group that decreases electron density on the benzene ring.
Correct Answer: B — -NO2
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Q. Which of the following haloalkanes can be converted to an alcohol by hydrolysis?
A.
Bromobenzene
B.
Chloroethane
C.
Iodobutane
D.
All of the above
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Solution
Iodobutane can be converted to an alcohol by hydrolysis, while bromobenzene requires a different mechanism due to its aromatic nature.
Correct Answer: C — Iodobutane
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Q. Which of the following haloalkanes is expected to have the highest boiling point?
A.
Chloroethane
B.
Bromoethane
C.
Iodoethane
D.
Fluoroethane
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Solution
Iodoethane has the highest boiling point due to the larger size and polarizability of iodine.
Correct Answer: C — Iodoethane
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Q. Which of the following haloalkanes is least soluble in water?
A.
Chloroethane
B.
Bromoethane
C.
Iodoethane
D.
Fluoroethane
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Solution
Iodoethane is least soluble in water due to its larger size and lower polarity compared to the others.
Correct Answer: C — Iodoethane
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Q. Which of the following haloalkanes is most reactive towards nucleophilic substitution?
A.
1-bromopropane
B.
2-bromopropane
C.
3-bromopropane
D.
Bromobenzene
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Solution
3-bromopropane is more reactive due to the stability of the tertiary carbocation formed during the reaction.
Correct Answer: C — 3-bromopropane
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Q. Which of the following haloalkanes is the most reactive towards nucleophilic substitution?
A.
1-bromopropane
B.
2-bromopropane
C.
3-bromopropane
D.
bromobenzene
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Solution
3-bromopropane is a tertiary haloalkane, which is more reactive towards nucleophilic substitution due to steric hindrance and stability of the carbocation formed.
Correct Answer: C — 3-bromopropane
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Q. Which of the following haloalkanes will undergo elimination reaction more readily?
A.
1-chloropropane
B.
2-chloropropane
C.
3-chloropropane
D.
chlorobenzene
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Solution
3-chloropropane is a tertiary haloalkane and will undergo elimination more readily due to the stability of the resulting alkene.
Correct Answer: C — 3-chloropropane
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Q. Which of the following haloalkanes will undergo elimination reaction most readily?
A.
1-bromopropane
B.
2-bromopropane
C.
3-bromopropane
D.
bromobenzene
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Solution
2-bromopropane undergoes elimination readily due to the formation of a stable alkene.
Correct Answer: C — 3-bromopropane
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Q. Which of the following haloarenes can undergo nucleophilic substitution?
A.
Chlorobenzene
B.
Bromobenzene
C.
Iodobenzene
D.
All of the above
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Solution
All of the listed haloarenes can undergo nucleophilic substitution under suitable conditions.
Correct Answer: D — All of the above
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Q. Which of the following haloarenes is most reactive in nucleophilic aromatic substitution?
A.
Chlorobenzene
B.
Bromobenzene
C.
Nitrochlorobenzene
D.
Fluorobenzene
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Solution
Nitrochlorobenzene is most reactive due to the electron-withdrawing nitro group, which stabilizes the negative charge in the intermediate.
Correct Answer: C — Nitrochlorobenzene
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Q. Which of the following haloarenes is most reactive towards nucleophilic substitution?
A.
Chlorobenzene
B.
Bromobenzene
C.
Iodobenzene
D.
Fluorobenzene
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Solution
Iodobenzene is the most reactive towards nucleophilic substitution due to the weaker C-I bond compared to the other haloarenes.
Correct Answer: C — Iodobenzene
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Q. Which of the following hydrocarbons is a cyclic compound?
A.
Butene
B.
Cyclobutane
C.
Hexane
D.
Octene
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Solution
Cyclobutane is a cyclic compound, while the others are linear alkenes or alkanes.
Correct Answer: B — Cyclobutane
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Q. Which of the following hydrocarbons is a gas at room temperature?
A.
Octane
B.
Hexane
C.
Methane
D.
Decane
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Solution
Methane (CH4) is a gas at room temperature, while the others are liquids.
Correct Answer: C — Methane
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Q. Which of the following is a biodegradable polymer?
A.
Polyethylene
B.
Polylactic acid (PLA)
C.
Polypropylene
D.
Polystyrene
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Solution
Polylactic acid (PLA) is a biodegradable polymer derived from renewable resources.
Correct Answer: B — Polylactic acid (PLA)
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Q. Which of the following is a branched alkane?
A.
Pentane
B.
Isopentane
C.
Hexane
D.
Heptane
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Solution
Isopentane is a branched alkane, while the others are straight-chain alkanes.
Correct Answer: B — Isopentane
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Q. Which of the following is a branched-chain alkane?
A.
Pentane
B.
2-Methylbutane
C.
Hexane
D.
Heptane
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Solution
2-Methylbutane is a branched-chain alkane derived from butane.
Correct Answer: B — 2-Methylbutane
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Q. Which of the following is a carbohydrate?
A.
Glucose
B.
Amino acid
C.
Fatty acid
D.
Nucleotide
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Solution
Glucose is a simple sugar and a primary carbohydrate.
Correct Answer: A — Glucose
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Q. Which of the following is a characteristic feature of alkanes?
A.
They contain at least one double bond
B.
They are saturated hydrocarbons
C.
They have a cyclic structure
D.
They contain functional groups
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Solution
Alkanes are saturated hydrocarbons, meaning they contain only single bonds between carbon atoms.
Correct Answer: B — They are saturated hydrocarbons
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Q. Which of the following is a characteristic feature of cycloalkanes?
A.
They are always aromatic
B.
They contain a ring structure
C.
They have double bonds
D.
They are always gaseous at room temperature
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Solution
Cycloalkanes are characterized by their ring structure.
Correct Answer: B — They contain a ring structure
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Q. Which of the following is a characteristic of +M effect?
A.
Electron withdrawal
B.
Electron donation
C.
No effect
D.
Increased acidity
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Solution
+M effect is characterized by electron donation through resonance, enhancing stability.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of alkanes?
A.
Unsaturated
B.
Cyclic
C.
Saturated
D.
Aromatic
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Solution
Alkanes are saturated hydrocarbons, meaning they contain only single bonds.
Correct Answer: C — Saturated
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Q. Which of the following is a characteristic of aromatic compounds?
A.
Non-planar structure
B.
Presence of double bonds
C.
Follows Huckel's rule
D.
Saturated
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Solution
Aromatic compounds follow Huckel's rule, which states that they must have (4n + 2) π electrons in a cyclic, planar structure.
Correct Answer: C — Follows Huckel's rule
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Q. Which of the following is a characteristic of carbohydrates?
A.
High energy density
B.
Soluble in organic solvents
C.
Hydrophilic nature
D.
Insoluble in water
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Solution
Carbohydrates are generally hydrophilic, meaning they are soluble in water.
Correct Answer: C — Hydrophilic nature
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Q. Which of the following is a characteristic of cellulose?
A.
Soluble in water
B.
Composed of glucose units
C.
Used for energy storage
D.
Contains α-1,4 glycosidic bonds
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Solution
Cellulose is composed of glucose units linked by β-1,4 glycosidic bonds and is not soluble in water.
Correct Answer: B — Composed of glucose units
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Q. Which of the following is a characteristic of cis-trans isomers?
A.
Same connectivity, different spatial arrangement
B.
Different connectivity
C.
Same molecular formula, different molecular weight
D.
Different boiling points only
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Solution
Cis-trans isomers have the same connectivity but differ in the spatial arrangement of groups around a double bond.
Correct Answer: A — Same connectivity, different spatial arrangement
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Q. Which of the following is a characteristic of cycloalkanes?
A.
They are always aromatic
B.
They have a ring structure
C.
They are unsaturated
D.
They contain only single bonds
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Solution
Cycloalkanes have a ring structure and can be saturated or unsaturated.
Correct Answer: B — They have a ring structure
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Q. Which of the following is a characteristic of enzymes?
A.
They are consumed in reactions
B.
They increase the activation energy
C.
They are specific to substrates
D.
They function at all temperatures
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Solution
Enzymes are highly specific to their substrates, allowing them to catalyze specific biochemical reactions.
Correct Answer: C — They are specific to substrates
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Q. Which of the following is a characteristic of fibrous proteins?
A.
Soluble in water
B.
Structural role
C.
Globular shape
D.
Enzymatic activity
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Solution
Fibrous proteins are typically insoluble in water and serve structural roles in cells and tissues.
Correct Answer: B — Structural role
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