Q. Which of the following groups would decrease the electron density on a benzene ring?
-
A.
-OCH3
-
B.
-NO2
-
C.
-CH3
-
D.
-Cl
Solution
-NO2 is a strong electron-withdrawing group that decreases electron density on the benzene ring.
Correct Answer: B — -NO2
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Q. Which of the following is a characteristic feature of alkanes?
-
A.
They contain at least one double bond
-
B.
They are saturated hydrocarbons
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C.
They have a cyclic structure
-
D.
They contain functional groups
Solution
Alkanes are saturated hydrocarbons, meaning they contain only single bonds between carbon atoms.
Correct Answer: B — They are saturated hydrocarbons
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Q. Which of the following is a characteristic of +M effect?
-
A.
Electron withdrawal
-
B.
Electron donation
-
C.
No effect
-
D.
Increased acidity
Solution
+M effect is characterized by electron donation through resonance, enhancing stability.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of alkanes?
-
A.
Unsaturated
-
B.
Cyclic
-
C.
Saturated
-
D.
Aromatic
Solution
Alkanes are saturated hydrocarbons, meaning they contain only single bonds.
Correct Answer: C — Saturated
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Q. Which of the following is a characteristic of aromatic compounds?
-
A.
Non-planar structure
-
B.
Presence of double bonds
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C.
Follows Huckel's rule
-
D.
Saturated
Solution
Aromatic compounds follow Huckel's rule, which states that they must have (4n + 2) π electrons in a cyclic, planar structure.
Correct Answer: C — Follows Huckel's rule
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Q. Which of the following is a characteristic of cis-trans isomers?
-
A.
Same connectivity, different spatial arrangement
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B.
Different connectivity
-
C.
Same molecular formula, different molecular weight
-
D.
Different boiling points only
Solution
Cis-trans isomers have the same connectivity but differ in the spatial arrangement of groups around a double bond.
Correct Answer: A — Same connectivity, different spatial arrangement
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Q. Which of the following is a characteristic of geometric isomers?
-
A.
Different connectivity of atoms
-
B.
Different spatial arrangement
-
C.
Different molecular formulas
-
D.
Different functional groups
Solution
Geometric isomers have the same connectivity of atoms but differ in their spatial arrangement.
Correct Answer: B — Different spatial arrangement
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Q. Which of the following is a characteristic of optical isomers?
-
A.
They have the same physical properties
-
B.
They rotate plane-polarized light in opposite directions
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C.
They have different molecular weights
-
D.
They cannot be superimposed on each other
Solution
Optical isomers, or enantiomers, rotate plane-polarized light in opposite directions.
Correct Answer: B — They rotate plane-polarized light in opposite directions
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Q. Which of the following is a characteristic of structural isomers?
-
A.
Same connectivity
-
B.
Different connectivity
-
C.
Same physical properties
-
D.
Same optical activity
Solution
Structural isomers have different connectivity of atoms, leading to different compounds.
Correct Answer: B — Different connectivity
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Q. Which of the following is a characteristic of the +I effect?
-
A.
Electron donation
-
B.
Electron withdrawal
-
C.
Resonance stabilization
-
D.
Inductive withdrawal
Solution
The +I effect is characterized by electron donation through the inductive effect.
Correct Answer: A — Electron donation
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Q. Which of the following is a characteristic of the +M effect?
-
A.
Electron withdrawal
-
B.
Electron donation
-
C.
Increases acidity
-
D.
Decreases stability
Solution
+M effect refers to the donation of electron density through resonance.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of the inductive effect?
-
A.
It is a temporary effect.
-
B.
It operates through pi bonds.
-
C.
It decreases with distance.
-
D.
It is stronger than the mesomeric effect.
Solution
The inductive effect decreases with distance from the electronegative atom or group.
Correct Answer: C — It decreases with distance.
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Q. Which of the following is a characteristic reaction of alkenes?
-
A.
Hydrogenation
-
B.
Hydrolysis
-
C.
Oxidation
-
D.
Reduction
Solution
Alkenes undergo hydrogenation, where they react with hydrogen in the presence of a catalyst.
Correct Answer: A — Hydrogenation
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Q. Which of the following is a primary amine?
-
A.
CH3NH2
-
B.
(CH3)2NH
-
C.
(C2H5)3N
-
D.
C6H5NH2
Solution
CH3NH2 is a primary amine as it has one alkyl group attached to the nitrogen atom.
Correct Answer: A — CH3NH2
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Q. Which of the following is a property of alkanes?
-
A.
They are polar
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B.
They are soluble in water
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C.
They are non-polar
-
D.
They have high reactivity
Solution
Alkanes are non-polar molecules and are generally insoluble in water.
Correct Answer: C — They are non-polar
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Q. Which of the following is a strong +I effect group?
-
A.
-F
-
B.
-Cl
-
C.
-Br
-
D.
-CH3
Solution
The -CH3 group is a strong +I effect group as it donates electron density through the inductive effect.
Correct Answer: D — -CH3
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Q. Which of the following is a strong -M group?
-
A.
-OCH3
-
B.
-NO2
-
C.
-CH3
-
D.
-F
Solution
-NO2 is a strong -M group as it withdraws electron density through resonance.
Correct Answer: B — -NO2
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Q. Which of the following is an example of a -I effect?
-
A.
–F
-
B.
–OCH3
-
C.
–CH3
-
D.
–C2H5
Solution
The –F group is an example of a -I effect as it withdraws electron density through sigma bonds.
Correct Answer: A — –F
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Q. Which of the following is an example of a -I group?
-
A.
–F
-
B.
–Cl
-
C.
–Br
-
D.
–I
Solution
All halogens (-F, -Cl, -Br, -I) exhibit -I effect, but -F is the strongest among them.
Correct Answer: A — –F
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Q. Which of the following is an example of a -M effect?
-
A.
–NO2
-
B.
–CH3
-
C.
–OCH3
-
D.
–Cl
Solution
The –NO2 group withdraws electron density through resonance, exhibiting a -M effect.
Correct Answer: A — –NO2
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Q. Which of the following is an example of a compound that exhibits tautomeric isomerism?
-
A.
Acetaldehyde
-
B.
Acetone
-
C.
Ethanol
-
D.
Benzene
Solution
Acetaldehyde can exist in two forms (keto and enol) that readily interconvert, demonstrating tautomeric isomerism.
Correct Answer: A — Acetaldehyde
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Q. Which of the following is an example of chain isomerism?
-
A.
Pentane and 2-methylbutane
-
B.
Butene and Butyne
-
C.
Ethanol and Dimethyl ether
-
D.
Acetic acid and Propanoic acid
Solution
Pentane and 2-methylbutane differ in the arrangement of carbon atoms, thus showing chain isomerism.
Correct Answer: A — Pentane and 2-methylbutane
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Q. Which of the following is an example of cis-trans isomerism?
-
A.
1-pentene
-
B.
2-pentene
-
C.
3-pentene
-
D.
Cyclopentane
Solution
2-pentene can exist in cis and trans forms due to the presence of a double bond.
Correct Answer: B — 2-pentene
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Q. Which of the following is an example of optical isomerism?
-
A.
Lactic acid
-
B.
Butane
-
C.
Cyclohexane
-
D.
Acetone
Solution
Lactic acid has a chiral center and can exist as two enantiomers, thus exhibiting optical isomerism.
Correct Answer: A — Lactic acid
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Q. Which of the following is an example of structural isomerism?
-
A.
Cis-2-butene and trans-2-butene
-
B.
1-bromopropane and 2-bromopropane
-
C.
Glucose and fructose
-
D.
1,2-dichloroethane and 1,1-dichloroethane
Solution
1-bromopropane and 2-bromopropane differ in the position of the bromine atom, showing structural isomerism.
Correct Answer: B — 1-bromopropane and 2-bromopropane
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Q. Which of the following is an example of tautomeric isomerism?
-
A.
Acetaldehyde and Ethanol
-
B.
Acetone and Propan-2-ol
-
C.
Keto-enol tautomerism
-
D.
Cis and Trans isomers
Solution
Keto-enol tautomerism is a classic example of tautomeric isomerism.
Correct Answer: C — Keto-enol tautomerism
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Q. Which of the following is NOT a characteristic of the inductive effect?
-
A.
Permanent
-
B.
Distance-dependent
-
C.
Reversible
-
D.
Weakens with distance
Solution
The inductive effect is permanent and weakens with distance, but it is not reversible.
Correct Answer: C — Reversible
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Q. Which of the following is NOT a type of isomerism?
-
A.
Geometric isomerism
-
B.
Optical isomerism
-
C.
Hydrogen isomerism
-
D.
Structural isomerism
Solution
Hydrogen isomerism is not a recognized type of isomerism in chemistry.
Correct Answer: C — Hydrogen isomerism
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Q. Which of the following is the correct IUPAC name for C2H5-CO-CH3?
-
A.
2-Pentanone
-
B.
3-Pentanone
-
C.
Butan-2-one
-
D.
Butan-3-one
Solution
The compound is a ketone with a four-carbon chain, and the carbonyl group is on the second carbon, hence it is Butan-2-one.
Correct Answer: C — Butan-2-one
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Q. Which of the following is the correct IUPAC name for C3H6?
-
A.
Propene
-
B.
Cyclopropane
-
C.
Propane
-
D.
1-Propyn
Solution
C3H6 corresponds to propene, which is an alkene with a double bond.
Correct Answer: A — Propene
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