Q. Which of the following compounds shows both -I and +M effects?
-
A.
Acetic acid
-
B.
Nitrobenzene
-
C.
Anisole
-
D.
Benzaldehyde
Solution
Benzaldehyde shows a -I effect due to the carbonyl group and a +M effect due to the aromatic ring.
Correct Answer: D — Benzaldehyde
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Q. Which of the following compounds will be most stable due to resonance?
-
A.
C6H5NO2
-
B.
C6H5Cl
-
C.
C6H5OH
-
D.
C6H5CH3
Solution
C6H5NO2 is most stable due to the strong electron-withdrawing effect of the -NO2 group, which stabilizes the negative charge through resonance.
Correct Answer: A — C6H5NO2
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Q. Which of the following compounds will have the highest electron density at the ortho position due to +M effect?
-
A.
C6H5NO2
-
B.
C6H5OH
-
C.
C6H5Cl
-
D.
C6H5CH3
Solution
C6H5OH has the highest electron density at the ortho position due to the +M effect of the -OH group.
Correct Answer: B — C6H5OH
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Q. Which of the following compounds will have the highest electron density due to +M effect?
-
A.
Phenol
-
B.
Benzaldehyde
-
C.
Nitrobenzene
-
D.
Aniline
Solution
Aniline has the highest electron density due to the +M effect of the amino group.
Correct Answer: D — Aniline
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Q. Which of the following compounds would be most acidic due to the inductive effect?
-
A.
CH3COOH
-
B.
ClCH2COOH
-
C.
FCH2COOH
-
D.
BrCH2COOH
Solution
FCH2COOH is the most acidic due to the strong -I effect of the fluorine atom.
Correct Answer: C — FCH2COOH
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Q. Which of the following compounds would be most stabilized by +M effect?
-
A.
Phenol
-
B.
Acetic acid
-
C.
Chloroethane
-
D.
Nitrobenzene
Solution
Phenol is stabilized by the +M effect due to the presence of the -OH group, which donates electron density.
Correct Answer: A — Phenol
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Q. Which of the following groups exhibits a -I effect?
-
A.
-OH
-
B.
-NO2
-
C.
-CH3
-
D.
-Cl
Solution
The -NO2 group is a strong electron-withdrawing group that exhibits a -I effect.
Correct Answer: B — -NO2
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Q. Which of the following groups exhibits a strong +M effect?
-
A.
-NO2
-
B.
-OH
-
C.
-CN
-
D.
-COOH
Solution
The -OH group exhibits a strong +M effect due to its ability to donate electron density through resonance.
Correct Answer: B — -OH
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Q. Which of the following groups exhibits a strong -I effect?
-
A.
–NO2
-
B.
–CH3
-
C.
–OH
-
D.
–NH2
Solution
The –NO2 group is a strong electron-withdrawing group and exhibits a strong -I effect.
Correct Answer: A — –NO2
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Q. Which of the following groups has a -I effect?
-
A.
-NH2
-
B.
-F
-
C.
-OCH3
-
D.
-C2H5
Solution
-F exhibits a -I effect as it withdraws electron density from the rest of the molecule.
Correct Answer: B — -F
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Q. Which of the following groups has both +M and -I effects?
-
A.
-NH2
-
B.
-NO2
-
C.
-COOH
-
D.
-F
Solution
The -NH2 group has a +M effect due to resonance donation and a -I effect due to its electronegativity.
Correct Answer: A — -NH2
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Q. Which of the following groups has the strongest -I effect?
-
A.
-F
-
B.
-Cl
-
C.
-Br
-
D.
-I
Solution
-F has the strongest -I effect due to its high electronegativity.
Correct Answer: A — -F
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Q. Which of the following groups is a strong +M (mesomeric) director?
-
A.
–NO2
-
B.
–OH
-
C.
–COOH
-
D.
–CN
Solution
The –OH group is a strong +M director as it donates electron density through resonance.
Correct Answer: B — –OH
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Q. Which of the following groups is a strong -I group?
-
A.
-F
-
B.
-CH3
-
C.
-OCH3
-
D.
-Br
Solution
The -F group is a strong -I group due to its high electronegativity.
Correct Answer: A — -F
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Q. Which of the following groups is a strong -M group?
-
A.
-OH
-
B.
-OCH3
-
C.
-NO2
-
D.
-NH2
Solution
-NO2 is a strong -M group as it withdraws electron density through resonance.
Correct Answer: C — -NO2
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Q. Which of the following groups is a strong electron-donating group?
-
A.
–NO2
-
B.
–OH
-
C.
–CN
-
D.
–COOH
Solution
The –OH group is a strong electron-donating group through resonance (+M effect).
Correct Answer: B — –OH
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Q. Which of the following groups is a weak +M director?
-
A.
-OH
-
B.
-OCH3
-
C.
-NH2
-
D.
-CH3
Solution
-CH3 is a weak +M director as it can donate some electron density but is less effective than -OH or -OCH3.
Correct Answer: D — -CH3
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Q. Which of the following groups is a weak -I effect group?
-
A.
–F
-
B.
–Cl
-
C.
–Br
-
D.
–I
Solution
The –I effect decreases in strength down the group in the halogens, making –I the weakest -I group.
Correct Answer: D — –I
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Q. Which of the following groups is a weak -I effect?
-
A.
-CH3
-
B.
-Cl
-
C.
-Br
-
D.
-I
Solution
The -CH3 group exhibits a weak -I effect as it is a weak electron-donating group.
Correct Answer: A — -CH3
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Q. Which of the following groups is a weak -M group?
-
A.
-CHO
-
B.
-COOH
-
C.
-NO2
-
D.
-F
Solution
-F is a weak -M group as it has a slight electron-withdrawing effect but is not as strong as -CHO or -COOH.
Correct Answer: D — -F
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Q. Which of the following groups is considered a weak -I group?
-
A.
-NO2
-
B.
-CN
-
C.
-F
-
D.
-COOH
Solution
-F is considered a weak -I group compared to -NO2 and -CN.
Correct Answer: C — -F
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Q. Which of the following groups is known for its +I effect?
-
A.
-CH3
-
B.
-OH
-
C.
-NO2
-
D.
-COOH
Solution
-CH3 exhibits a +I effect as it donates electron density through inductive effect.
Correct Answer: A — -CH3
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Q. Which of the following groups shows +M effect?
-
A.
-NO2
-
B.
-CN
-
C.
-OCH3
-
D.
-COOH
Solution
The -OCH3 group shows +M effect as it donates electrons through resonance.
Correct Answer: C — -OCH3
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Q. Which of the following groups shows a +M effect?
-
A.
–NO2
-
B.
–F
-
C.
–OH
-
D.
–CN
Solution
The –OH group donates electron density through resonance, exhibiting a +M effect.
Correct Answer: C — –OH
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Q. Which of the following groups would decrease the electron density on a benzene ring?
-
A.
-OCH3
-
B.
-NO2
-
C.
-CH3
-
D.
-Cl
Solution
-NO2 is a strong electron-withdrawing group that decreases electron density on the benzene ring.
Correct Answer: B — -NO2
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Q. Which of the following is a characteristic of +M effect?
-
A.
Electron withdrawal
-
B.
Electron donation
-
C.
No effect
-
D.
Increased acidity
Solution
+M effect is characterized by electron donation through resonance, enhancing stability.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of the +I effect?
-
A.
Electron donation
-
B.
Electron withdrawal
-
C.
Resonance stabilization
-
D.
Inductive withdrawal
Solution
The +I effect is characterized by electron donation through the inductive effect.
Correct Answer: A — Electron donation
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Q. Which of the following is a characteristic of the +M effect?
-
A.
Electron withdrawal
-
B.
Electron donation
-
C.
Increases acidity
-
D.
Decreases stability
Solution
+M effect refers to the donation of electron density through resonance.
Correct Answer: B — Electron donation
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Q. Which of the following is a characteristic of the inductive effect?
-
A.
It is a temporary effect.
-
B.
It operates through pi bonds.
-
C.
It decreases with distance.
-
D.
It is stronger than the mesomeric effect.
Solution
The inductive effect decreases with distance from the electronegative atom or group.
Correct Answer: C — It decreases with distance.
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Q. Which of the following is a strong +I effect group?
-
A.
-F
-
B.
-Cl
-
C.
-Br
-
D.
-CH3
Solution
The -CH3 group is a strong +I effect group as it donates electron density through the inductive effect.
Correct Answer: D — -CH3
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