Q. Which of the following compounds is the most acidic?
A.
Ethylene
B.
Propene
C.
Propyne
D.
Butyne
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Solution
Propyne is the most acidic due to the sp hybridization of the carbon atom involved in the triple bond.
Correct Answer: C — Propyne
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Q. Which of the following hydrocarbons is a cyclic compound?
A.
Butene
B.
Cyclobutane
C.
Hexane
D.
Octene
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Solution
Cyclobutane is a cyclic compound, while the others are linear alkenes or alkanes.
Correct Answer: B — Cyclobutane
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Q. Which of the following hydrocarbons is a gas at room temperature?
A.
Octane
B.
Hexane
C.
Methane
D.
Decane
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Solution
Methane (CH4) is a gas at room temperature, while the others are liquids.
Correct Answer: C — Methane
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Q. Which of the following is a branched alkane?
A.
Pentane
B.
Isopentane
C.
Hexane
D.
Heptane
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Solution
Isopentane is a branched alkane, while the others are straight-chain alkanes.
Correct Answer: B — Isopentane
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Q. Which of the following is a branched-chain alkane?
A.
Pentane
B.
2-Methylbutane
C.
Hexane
D.
Heptane
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Solution
2-Methylbutane is a branched-chain alkane derived from butane.
Correct Answer: B — 2-Methylbutane
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Q. Which of the following is a characteristic feature of cycloalkanes?
A.
They are always aromatic
B.
They contain a ring structure
C.
They have double bonds
D.
They are always gaseous at room temperature
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Solution
Cycloalkanes are characterized by their ring structure.
Correct Answer: B — They contain a ring structure
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Q. Which of the following is a characteristic of cycloalkanes?
A.
They are always aromatic
B.
They have a ring structure
C.
They are unsaturated
D.
They contain only single bonds
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Solution
Cycloalkanes have a ring structure and can be saturated or unsaturated.
Correct Answer: B — They have a ring structure
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Q. Which of the following is a characteristic of saturated hydrocarbons?
A.
They contain double bonds
B.
They contain triple bonds
C.
They are less stable than unsaturated hydrocarbons
D.
They contain only single bonds
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Solution
Saturated hydrocarbons contain only single bonds between carbon atoms.
Correct Answer: D — They contain only single bonds
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Q. Which of the following is a characteristic property of alkynes?
A.
Higher boiling points than alkenes
B.
Lower reactivity than alkenes
C.
Inability to undergo addition reactions
D.
Higher density than alkanes
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Solution
Alkynes generally have higher boiling points than alkenes due to stronger intermolecular forces.
Correct Answer: A — Higher boiling points than alkenes
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Q. Which of the following is a characteristic reaction of alkanes?
A.
Nucleophilic substitution
B.
Electrophilic addition
C.
Free radical halogenation
D.
Hydrogenation
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Solution
Free radical halogenation is a characteristic reaction of alkanes.
Correct Answer: C — Free radical halogenation
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Q. Which of the following is a common electrophile in electrophilic aromatic substitution reactions?
A.
Bromine
B.
Hydrogen
C.
Water
D.
Methane
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Solution
Bromine, often in the presence of a catalyst like FeBr3, acts as a common electrophile in electrophilic aromatic substitution reactions.
Correct Answer: A — Bromine
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Q. Which of the following is a common electrophile in electrophilic aromatic substitution?
A.
Br2
B.
H2O
C.
NaOH
D.
CH3OH
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Solution
Bromine (Br2) can act as an electrophile in the presence of a catalyst like FeBr3 during electrophilic aromatic substitution.
Correct Answer: A — Br2
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Q. Which of the following is a common method for synthesizing aromatic compounds?
A.
Friedel-Crafts alkylation
B.
Hydrogenation
C.
Dehydration
D.
Oxidation
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Solution
Friedel-Crafts alkylation is a common method used to synthesize aromatic compounds by introducing alkyl groups onto the aromatic ring.
Correct Answer: A — Friedel-Crafts alkylation
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Q. Which of the following is a common method for the synthesis of aromatic compounds?
A.
Hydrogenation
B.
Dehydrogenation
C.
Electrophilic substitution
D.
Nucleophilic addition
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Solution
Electrophilic substitution is a common method for synthesizing aromatic compounds by introducing new substituents onto the aromatic ring.
Correct Answer: C — Electrophilic substitution
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Q. Which of the following is a common test for the presence of aromatic compounds?
A.
Bromine water test
B.
Baeyer test
C.
Tollen's test
D.
Benzene test
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Solution
The bromine water test can be used to detect unsaturation; however, aromatic compounds do not react with bromine water, indicating their stability.
Correct Answer: A — Bromine water test
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Q. Which of the following is a derivative of benzene?
A.
Ethylene
B.
Acetylene
C.
Phenol
D.
Propylene
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Solution
Phenol is a derivative of benzene, where one hydrogen atom is replaced by a hydroxyl group (-OH).
Correct Answer: C — Phenol
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Q. Which of the following is a method for the preparation of alkenes?
A.
Hydrogenation
B.
Dehydrohalogenation
C.
Hydrolysis
D.
Oxidation
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Solution
Dehydrohalogenation is a common method for preparing alkenes from alkyl halides.
Correct Answer: B — Dehydrohalogenation
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Q. Which of the following is a primary alcohol derived from an alkane?
A.
Methanol
B.
Ethanol
C.
Propan-1-ol
D.
Butanol
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Solution
Propan-1-ol is a primary alcohol derived from propane.
Correct Answer: C — Propan-1-ol
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Q. Which of the following is a property of alkenes?
A.
Saturated
B.
Unsaturated
C.
Non-polar
D.
Inert
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Solution
Alkenes are unsaturated hydrocarbons due to the presence of at least one double bond.
Correct Answer: B — Unsaturated
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Q. Which of the following is a property of alkynes?
A.
They are saturated
B.
They contain a triple bond
C.
They are less reactive than alkenes
D.
They have the formula CnH2n
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Solution
Alkynes contain at least one triple bond between carbon atoms.
Correct Answer: B — They contain a triple bond
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Q. Which of the following is a property of aromatic compounds?
A.
High reactivity
B.
Planar structure
C.
Non-polar nature
D.
All of the above
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Solution
Aromatic compounds are characterized by a planar structure and exhibit unique stability due to resonance, but they are generally less reactive than alkenes.
Correct Answer: B — Planar structure
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Q. Which of the following is a property of aromatic hydrocarbons?
A.
They are always saturated
B.
They have a pleasant smell
C.
They contain a benzene ring
D.
They are non-polar
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Solution
Aromatic hydrocarbons contain a benzene ring.
Correct Answer: C — They contain a benzene ring
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Q. Which of the following is a property of cycloalkanes?
A.
They are always aromatic
B.
They have a ring structure
C.
They are unsaturated
D.
They contain only single bonds
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Solution
Cycloalkanes have a ring structure and can be saturated or unsaturated depending on the number of hydrogen atoms.
Correct Answer: B — They have a ring structure
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Q. Which of the following is a terminal alkyne?
A.
1-butyne
B.
2-butyne
C.
1-pentyne
D.
3-pentyne
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Solution
1-butyne is a terminal alkyne because it has a triple bond at the end of the carbon chain.
Correct Answer: A — 1-butyne
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Q. Which of the following is an alkane?
A.
C2H4
B.
C3H6
C.
C4H10
D.
C5H8
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Solution
Alkanes are saturated hydrocarbons with the general formula CnH2n+2. C4H10 (butane) fits this formula.
Correct Answer: C — C4H10
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Q. Which of the following is NOT an aromatic compound?
A.
Naphthalene
B.
Benzene
C.
Cyclooctatetraene
D.
Anthracene
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Solution
Cyclooctatetraene is not aromatic because it does not satisfy Huckel's rule; it is non-planar and does not have a continuous overlap of p-orbitals.
Correct Answer: C — Cyclooctatetraene
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Q. Which of the following is the correct formula for ethyne?
A.
C2H2
B.
C2H4
C.
C2H6
D.
C2H8
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Solution
Ethyne, also known as acetylene, has the formula C2H2, which indicates it is an alkyne.
Correct Answer: A — C2H2
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Q. Which of the following is the correct reaction for the hydrogenation of 1-butyne?
A.
C4H6 + H2 → C4H10
B.
C4H6 + H2 → C4H8
C.
C4H6 + H2 → C4H12
D.
C4H6 + H2 → C4H4
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Solution
1-butyne (C4H6) reacts with hydrogen (H2) to form butene (C4H8) under catalytic conditions.
Correct Answer: B — C4H6 + H2 → C4H8
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Q. Which of the following is the correct structure for 2-butyne?
A.
CH3-C≡C-CH3
B.
CH3-CH≡C-CH3
C.
CH3-C=C-CH3
D.
C≡C-CH2-CH3
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Solution
2-butyne has the structure CH3-CH≡C-CH3, with the triple bond between the second and third carbon.
Correct Answer: B — CH3-CH≡C-CH3
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Q. Which of the following is the correct structure for 2-methylpropane?
A.
CH3-CH(CH3)-CH2-CH3
B.
CH3-CH2-CH(CH3)-CH3
C.
CH3-CH(CH3)-CH(CH3)-CH3
D.
CH3-CH2-CH2-CH(CH3)
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Solution
2-methylpropane has a branched structure with a methyl group on the second carbon.
Correct Answer: B — CH3-CH2-CH(CH3)-CH3
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