Q. Which of the following is the general formula for alkynes?
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A.
C_nH_(2n+2)
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B.
C_nH_(2n)
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C.
C_nH_(2n-2)
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D.
C_nH_(2n-1)
Solution
The general formula for alkynes is C_nH_(2n-2), where n is the number of carbon atoms.
Correct Answer: C — C_nH_(2n-2)
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Q. Which of the following is the simplest alkyne?
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A.
Ethylene
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B.
Acetylene
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C.
Propylene
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D.
Butyne
Solution
Acetylene (C2H2) is the simplest alkyne.
Correct Answer: B — Acetylene
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Q. Which of the following reactions can alkynes undergo?
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A.
Electrophilic addition
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B.
Nucleophilic substitution
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C.
Free radical substitution
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D.
All of the above
Solution
Alkynes can undergo electrophilic addition reactions due to the presence of the triple bond.
Correct Answer: A — Electrophilic addition
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Q. Which of the following reactions can be used to convert an alkyne to a cis-alkene?
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A.
Hydrogenation
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B.
Halogenation
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C.
Hydroboration
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D.
Ozonolysis
Solution
Hydroboration followed by oxidation converts alkynes to cis-alkenes.
Correct Answer: C — Hydroboration
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Q. Which of the following reactions can be used to convert an alkyne to an alkene?
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A.
Hydrogenation
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B.
Halogenation
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C.
Hydrohalogenation
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D.
Dehydrohalogenation
Solution
Hydrogenation of an alkyne will add hydrogen across the triple bond, converting it to an alkene.
Correct Answer: A — Hydrogenation
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Q. Which of the following reactions can be used to prepare alkynes?
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A.
Hydrogenation of alkenes
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B.
Dehydrohalogenation of alkyl halides
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C.
Oxidation of alkanes
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D.
Hydrolysis of alkynes
Solution
Alkynes can be prepared by the dehydrohalogenation of alkyl halides.
Correct Answer: B — Dehydrohalogenation of alkyl halides
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Q. Which of the following statements about alkynes is incorrect?
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A.
They are unsaturated hydrocarbons.
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B.
They contain at least one triple bond.
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C.
They are more reactive than alkenes.
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D.
They have a higher boiling point than alkenes.
Solution
Alkynes are generally less reactive than alkenes due to the stability of the triple bond.
Correct Answer: C — They are more reactive than alkenes.
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Q. Which of the following statements about alkynes is true?
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A.
They are less acidic than alkenes.
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B.
They can undergo polymerization.
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C.
They have a higher boiling point than alkenes.
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D.
They are more stable than alkenes.
Solution
Alkynes have a higher boiling point than alkenes due to stronger intermolecular forces.
Correct Answer: C — They have a higher boiling point than alkenes.
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Q. Which of the following statements is true about alkynes?
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A.
They are less reactive than alkenes.
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B.
They are more acidic than alkenes.
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C.
They cannot undergo addition reactions.
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D.
They have a higher boiling point than alkenes.
Solution
Alkynes are more acidic than alkenes due to the sp hybridization of the carbon atoms.
Correct Answer: B — They are more acidic than alkenes.
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Q. Which reaction is characteristic of alkynes?
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A.
Hydrogenation
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B.
Halogenation
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C.
Hydrohalogenation
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D.
All of the above
Solution
Alkynes can undergo hydrogenation, halogenation, and hydrohalogenation.
Correct Answer: D — All of the above
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Q. Which reaction is commonly used to convert alkynes to alkenes?
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A.
Hydrogenation
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B.
Halogenation
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C.
Hydroboration
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D.
Dehydrohalogenation
Solution
Hydrogenation is used to convert alkynes to alkenes.
Correct Answer: A — Hydrogenation
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Q. Which reaction is used to prepare alkynes from alkenes?
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A.
Hydrogenation
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B.
Dehydrohalogenation
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C.
Hydrohalogenation
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D.
Halogenation
Solution
Dehydrohalogenation of vicinal dihalides can be used to prepare alkynes from alkenes.
Correct Answer: B — Dehydrohalogenation
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Q. Which reagent can be used to convert an alkyne to a diketone?
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A.
KMnO4
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B.
O3
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C.
H2O
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D.
H2SO4
Solution
Ozonolysis of an alkyne can yield a diketone.
Correct Answer: B — O3
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Q. Which reagent can be used to convert an alkyne to a ketone?
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A.
H2O/H2SO4
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B.
LiAlH4
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C.
B2H6
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D.
KMnO4
Solution
The hydration of an alkyne using H2O in the presence of H2SO4 leads to the formation of a ketone.
Correct Answer: A — H2O/H2SO4
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Q. Which reagent can be used to distinguish between an alkyne and an alkene?
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A.
Bromine water
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B.
Sodium metal
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C.
Potassium permanganate
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D.
Hydrochloric acid
Solution
Bromine water can be used to distinguish between an alkyne and an alkene, as alkynes will decolorize it.
Correct Answer: A — Bromine water
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Q. Which reagent is commonly used to convert alkynes to alkenes?
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A.
H2/Pd
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B.
LiAlH4
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C.
Br2
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D.
KMnO4
Solution
Hydrogenation using H2 in the presence of a catalyst like Pd converts alkynes to alkenes.
Correct Answer: A — H2/Pd
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Q. Which reagent is commonly used to convert an alkyne to a cis-alkene?
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A.
H2/Pd
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B.
H2/Lindlar's catalyst
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C.
LiAlH4
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D.
NaNH2
Solution
H2 in the presence of Lindlar's catalyst is used to convert alkynes to cis-alkenes.
Correct Answer: B — H2/Lindlar's catalyst
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Q. Which reagent is commonly used to test for the presence of alkynes?
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A.
Bromine water
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B.
Silver nitrate
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C.
Sodium metal
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D.
Bayer's reagent
Solution
Bromine water is used to test for the presence of alkynes, which will decolorize the solution.
Correct Answer: A — Bromine water
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Q. Which reagent is used for the selective hydrogenation of alkynes to alkenes?
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A.
Pd/BaSO4
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B.
LiAlH4
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C.
H2/Pt
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D.
NaNH2
Solution
Pd/BaSO4 is used as a catalyst for the selective hydrogenation of alkynes to form alkenes.
Correct Answer: A — Pd/BaSO4
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Q. Which reagent is used to convert an alkyne to a cis-alkene?
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A.
H2/Pd
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B.
H2/Lindlar's catalyst
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C.
Li/NH3
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D.
Na/NH3
Solution
H2 in the presence of Lindlar's catalyst is used to convert an alkyne to a cis-alkene.
Correct Answer: B — H2/Lindlar's catalyst
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