Physical Chemistry

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Q. If 7x - 3 = 4x + 6, what is the value of x?
  • A. 3
  • B. 2
  • C. 1
  • D. 0
Q. If 7x = 21, what is the value of x?
  • A. 1
  • B. 2
  • C. 3
  • D. 4
Q. If a beam is supported at both ends and a load is applied at the center, what is the reaction force at each support?
  • A. Equal to the load
  • B. Half the load
  • C. Double the load
  • D. Zero
Q. If a force of 10 N is applied at an angle of 30 degrees to the horizontal, what is the horizontal component of the force?
  • A. 5 N
  • B. 8.66 N
  • C. 10 N
  • D. 0 N
Q. If a reaction has a ΔG of +5 kJ/mol, what can be inferred?
  • A. The reaction is spontaneous
  • B. The reaction is non-spontaneous
  • C. The reaction is at equilibrium
  • D. The reaction is exothermic
Q. If a reaction has ΔH = 100 kJ and ΔS = -200 J/K, what is ΔG at 298 K?
  • A. 0 kJ
  • B. 100 kJ
  • C. 200 kJ
  • D. 300 kJ
Q. If a solution has a vapor pressure of 80 mmHg and the pure solvent has a vapor pressure of 100 mmHg, what is the mole fraction of the solvent?
  • A. 0.8
  • B. 0.75
  • C. 0.6
  • D. 0.5
Q. If an electron has quantum numbers n=2, l=0, and m_l=0, which orbital does it occupy?
  • A. 2s
  • B. 2p
  • C. 1s
  • D. 3s
Q. If an electron has quantum numbers n=3, l=1, and m_l=-1, what is the possible value of the spin quantum number?
  • A. +1/2
  • B. -1/2
  • C. 0
  • D. 1
Q. If an electron has the quantum numbers n=3, l=1, m_l=0, what type of orbital does it occupy?
  • A. s
  • B. p
  • C. d
  • D. f
Q. If an electron has the quantum numbers n=3, l=1, m_l=0, what type of orbital is it in?
  • A. s
  • B. p
  • C. d
  • D. f
Q. If an electron has the quantum numbers n=3, l=1, what is the possible range of m_l?
  • A. -1, 0, +1
  • B. 0, +1, +2
  • C. -2, -1, 0
  • D. -1, 0, +1, +2
Q. If an electron is in the state characterized by the quantum numbers n=4, l=0, what is the value of m_l?
  • A. 0
  • B. 1
  • C. -1
  • D. 2
Q. If an electron is in the state characterized by the quantum numbers n=4, l=2, what is the value of m_l?
  • A. -2
  • B. 0
  • C. 2
  • D. All of the above
Q. If n=4 and l=2, what is the type of orbital?
  • A. s
  • B. p
  • C. d
  • D. f
Q. If the activation energy of a reaction is increased, what happens to the rate constant k?
  • A. Increases
  • B. Decreases
  • C. Remains the same
  • D. Becomes zero
Q. If the azimuthal quantum number l = 1, what is the shape of the orbital?
  • A. Spherical
  • B. Dumbbell
  • C. Double dumbbell
  • D. None of the above
Q. If the concentration of reactants is increased in a system at equilibrium, what will happen to the position of equilibrium?
  • A. Shift to the right
  • B. Shift to the left
  • C. No change
  • D. Depends on temperature
Q. If the enthalpy of a system increases, the process is considered _____.
  • A. exothermic
  • B. endothermic
  • C. isothermal
  • D. adiabatic
Q. If the enthalpy of a system increases, what can be inferred about the system?
  • A. It is losing heat
  • B. It is gaining heat
  • C. It is at equilibrium
  • D. It is undergoing a phase change
Q. If the enthalpy of reaction is -100 kJ, what can be said about the reaction?
  • A. It absorbs heat
  • B. It releases heat
  • C. It is at equilibrium
  • D. It requires energy input
Q. If the entropy of a system increases, what can be inferred about the spontaneity of the process?
  • A. The process is non-spontaneous
  • B. The process is spontaneous
  • C. The process is at equilibrium
  • D. None of the above
Q. If the entropy of a system increases, what is the effect on Gibbs Free Energy at constant temperature?
  • A. ΔG increases
  • B. ΔG decreases
  • C. ΔG remains constant
  • D. ΔG becomes zero
Q. If the equation x^2 - 5x + k = 0 has equal roots, what is the value of k?
  • A. 5
  • B. 6
  • C. 7
  • D. 8
Q. If the equilibrium constant Kc for a reaction is 10 at a certain temperature, what is the value of Kc for the reverse reaction?
  • A. 0.1
  • B. 1
  • C. 10
  • D. 100
Q. If the equilibrium constant Kc for a reaction is 10, what can be said about the position of equilibrium?
  • A. Products are favored
  • B. Reactants are favored
  • C. Equilibrium is at the center
  • D. No conclusion can be drawn
Q. If the equilibrium constant Kc for a reaction is less than 1, what does it indicate about the equilibrium position?
  • A. Products are favored
  • B. Reactants are favored
  • C. Equal amounts of reactants and products
  • D. Reaction does not occur
Q. If the forward reaction is exothermic, what effect does increasing the temperature have on the equilibrium position?
  • A. Shifts to the right
  • B. Shifts to the left
  • C. No effect
  • D. Increases the rate of reaction
Q. If the mole fraction of a solute in a solution is 0.2, what is the mole fraction of the solvent?
  • A. 0.8
  • B. 0.2
  • C. 0.5
  • D. 0.6
Q. If the mole fraction of a solvent in a solution is 0.75, what is the vapor pressure of the solvent if its pure vapor pressure is 100 mmHg?
  • A. 75 mmHg
  • B. 100 mmHg
  • C. 25 mmHg
  • D. 50 mmHg
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