Qualitative Analysis of Ions - Higher Difficulty Problems

Q. In a qualitative analysis using paper chromatography, which factor primarily affects the Rf value of a substance?
  • A. Solvent polarity
  • B. Temperature
  • C. pH of the solution
  • D. Molecular weight
Q. In a qualitative analysis using paper chromatography, which factor primarily affects the separation of ions?
  • A. Temperature
  • B. Solvent polarity
  • C. pH of the solution
  • D. Ion concentration
Q. In a titration to determine the presence of acetic acid, which indicator would be most appropriate?
  • A. Phenolphthalein
  • B. Methyl orange
  • C. Bromothymol blue
  • D. Litmus
Q. In a titration to determine the presence of chloride ions, which indicator is most suitable?
  • A. Phenolphthalein
  • B. Methyl orange
  • C. Silver nitrate
  • D. Chromate
Q. In qualitative analysis, what does a positive test for the presence of ammonium ions typically involve?
  • A. Formation of a blue complex
  • B. Evolution of ammonia gas
  • C. Color change with phenolphthalein
  • D. Precipitation with barium sulfate
Q. In qualitative analysis, what does a positive test for the presence of sulfate ions typically involve?
  • A. Formation of a white precipitate
  • B. Formation of a colored solution
  • C. Gas evolution
  • D. No visible change
Q. What is the main advantage of using mass spectrometry in qualitative analysis?
  • A. High sensitivity
  • B. Low cost
  • C. Simplicity of operation
  • D. Speed of analysis
Q. What is the primary purpose of using a buffer solution in electrophoresis?
  • A. To increase the voltage
  • B. To maintain pH stability
  • C. To enhance sample concentration
  • D. To reduce sample size
Q. What is the role of a chelating agent in qualitative analysis?
  • A. To increase solubility
  • B. To stabilize metal ions
  • C. To enhance color change
  • D. To precipitate ions
Q. Which analytical technique is best suited for the qualitative analysis of metal ions in solution?
  • A. Mass spectrometry
  • B. Infrared spectroscopy
  • C. Atomic absorption spectroscopy
  • D. Nuclear magnetic resonance
Q. Which method is most effective for the qualitative analysis of anions in a mixture?
  • A. Titration
  • B. Spectrophotometry
  • C. Chromatography
  • D. Electrophoresis
Q. Which of the following ions can be detected using a flame test that produces a green flame?
  • A. Sodium
  • B. Barium
  • C. Potassium
  • D. Calcium
Q. Which of the following ions would produce a characteristic yellow precipitate when treated with lead(II) nitrate?
  • A. Chloride
  • B. Bromide
  • C. Iodide
  • D. Sulfate
Q. Which of the following ions would produce a yellow precipitate when treated with silver nitrate?
  • A. Chloride
  • B. Bromide
  • C. Iodide
  • D. Sulfate
Q. Which reagent is commonly used in the qualitative analysis of halides to form a precipitate?
  • A. Barium chloride
  • B. Silver nitrate
  • C. Lead(II) nitrate
  • D. Calcium sulfate
Q. Which reagent is commonly used to confirm the presence of sulfate ions in a qualitative analysis?
  • A. Barium chloride
  • B. Silver nitrate
  • C. Hydrochloric acid
  • D. Ammonium hydroxide
Q. Which technique is best suited for separating and identifying amino acids in a mixture?
  • A. Gas chromatography
  • B. High-performance liquid chromatography
  • C. Thin-layer chromatography
  • D. Capillary electrophoresis
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