Aromatic Compounds and Electrophilic Substitution - Real World Applications

Q. In the nitration of benzene, which reagent is used to generate the electrophile?
  • A. HNO3
  • B. H2SO4
  • C. NO2+
  • D. HCl
Q. In the nitration of toluene, which position is most likely to be substituted?
  • A. Ortho
  • B. Meta
  • C. Para
  • D. All positions equally
Q. What is the effect of a nitro group on the reactivity of benzene in electrophilic substitution?
  • A. Activates the ring
  • B. Deactivates the ring
  • C. No effect
  • D. Increases ortho substitution
Q. What is the product of the reaction between benzene and sulfur trioxide in the presence of sulfuric acid?
  • A. Benzene sulfonic acid
  • B. Benzene thiol
  • C. Benzyl sulfonate
  • D. Benzene sulfide
Q. What is the stereochemical outcome of the electrophilic substitution of a chiral aromatic compound?
  • A. Retention of configuration
  • B. Inversion of configuration
  • C. Racemization
  • D. No stereochemical outcome
Q. What is the stereochemistry of the product formed when 1,2-dibromobenzene undergoes electrophilic substitution?
  • A. R
  • B. S
  • C. R/S mixture
  • D. No stereochemistry
Q. Which aromatic compound is most reactive towards electrophilic substitution?
  • A. Benzene
  • B. Toluene
  • C. Nitrobenzene
  • D. Chlorobenzene
Q. Which of the following compounds is a common electrophile used in Friedel-Crafts acylation?
  • A. Benzoyl chloride
  • B. Bromobenzene
  • C. Toluene
  • D. Phenol
Q. Which of the following compounds is an example of a para-substituted aromatic compound?
  • A. Toluene
  • B. p-Dichlorobenzene
  • C. Aniline
  • D. Phenol
Q. Which of the following is a common application of aromatic compounds in the real world?
  • A. Dyes
  • B. Pharmaceuticals
  • C. Plastics
  • D. All of the above
Q. Which of the following statements about the reactivity of aromatic compounds is true?
  • A. All aromatic compounds are equally reactive
  • B. Electron-withdrawing groups increase reactivity
  • C. Electron-donating groups decrease reactivity
  • D. Reactivity depends on the substituents present
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