Physical Chemistry - Thermodynamics
Q. In which of the following processes is the enthalpy change (ΔH) equal to the heat absorbed at constant pressure? (2019)
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A.
Isothermal process
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B.
Isochoric process
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C.
Isobaric process
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D.
Adiabatic process
Solution
In an isobaric process, the enthalpy change (ΔH) is equal to the heat absorbed or released at constant pressure.
Correct Answer: C — Isobaric process
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Q. The heat capacity at constant volume (Cv) is defined as: (2022)
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A.
The amount of heat required to raise the temperature of a substance by 1°C at constant pressure.
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B.
The amount of heat required to raise the temperature of a substance by 1°C at constant volume.
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C.
The total heat content of a substance.
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D.
The heat required to change the phase of a substance.
Solution
The heat capacity at constant volume (Cv) is defined as the amount of heat required to raise the temperature of a substance by 1°C at constant volume.
Correct Answer: B — The amount of heat required to raise the temperature of a substance by 1°C at constant volume.
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Q. What is the change in internal energy (ΔU) for an ideal gas during an isothermal process? (2021)
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A.
ΔU = 0
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B.
ΔU = nRT
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C.
ΔU = -nRT
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D.
ΔU = PV
Solution
In an isothermal process for an ideal gas, the temperature remains constant, which means the internal energy does not change. Therefore, ΔU = 0.
Correct Answer: A — ΔU = 0
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Q. What is the standard enthalpy change (ΔH°) for the formation of water from its elements? (2022)
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A.
-285.83 kJ/mol
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B.
0 kJ/mol
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C.
285.83 kJ/mol
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D.
-241.82 kJ/mol
Solution
The standard enthalpy change for the formation of water from its elements (H2 and O2) is -285.83 kJ/mol.
Correct Answer: A — -285.83 kJ/mol
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