Physical Chemistry - Solid State
Q. In a simple cubic lattice, how many atoms are present in one unit cell? (2019)
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Solution
In a simple cubic lattice, there is 1 atom per unit cell (1/8 atom from each of the 8 corners).
Correct Answer: A — 1
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Q. What is the coordination number of atoms in a face-centered cubic (FCC) structure? (2021)
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Solution
In a face-centered cubic (FCC) structure, each atom is in contact with 12 other atoms, giving it a coordination number of 12.
Correct Answer: D — 12
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Q. What is the formula for calculating the number of atoms in a face-centered cubic unit cell? (2022)
A.
N = 4
B.
N = 2
C.
N = 1
D.
N = 8
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Solution
In a face-centered cubic unit cell, there are 4 atoms (1/8 from each of the 8 corners and 1/2 from each of the 6 faces).
Correct Answer: A — N = 4
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Q. What is the primary type of bonding in metallic solids? (2020)
A.
Ionic bonding
B.
Covalent bonding
C.
Metallic bonding
D.
Hydrogen bonding
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Solution
Metallic solids are primarily held together by metallic bonding, which involves a 'sea of electrons' that are free to move.
Correct Answer: C — Metallic bonding
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Q. What type of packing is observed in a body-centered cubic (BCC) structure? (2023)
A.
Hexagonal close packing
B.
Cubic close packing
C.
Simple cubic packing
D.
Body-centered packing
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Solution
The body-centered cubic (BCC) structure features body-centered packing, where one atom is at the center of the cube and eight atoms are at the corners.
Correct Answer: D — Body-centered packing
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Q. Which of the following is a characteristic of ionic solids? (2020)
A.
High electrical conductivity in solid state
B.
High melting point
C.
Low density
D.
Malleable
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Solution
Ionic solids are characterized by high melting points due to the strong electrostatic forces between the ions.
Correct Answer: B — High melting point
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Q. Which of the following is an example of a molecular solid? (2023)
A.
NaCl
B.
Diamond
C.
Iodine (I2)
D.
Iron (Fe)
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Solution
Iodine (I2) is an example of a molecular solid, where molecules are held together by van der Waals forces.
Correct Answer: C — Iodine (I2)
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Q. Which of the following is NOT a property of metals? (2021)
A.
Good electrical conductivity
B.
Brittleness
C.
Malleability
D.
Ductility
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Solution
Brittleness is not a property of metals; they are typically malleable and ductile.
Correct Answer: B — Brittleness
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Q. Which of the following structures has the highest packing efficiency? (2019)
A.
Simple cubic
B.
Body-centered cubic
C.
Face-centered cubic
D.
Hexagonal close-packed
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Solution
The face-centered cubic (FCC) structure has the highest packing efficiency of approximately 74%.
Correct Answer: C — Face-centered cubic
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Q. Which type of solid has a definite melting point? (2022)
A.
Amorphous solid
B.
Crystalline solid
C.
Polymeric solid
D.
Metallic solid
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Solution
Crystalline solids have a definite melting point due to their ordered structure, unlike amorphous solids which melt over a range of temperatures.
Correct Answer: B — Crystalline solid
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