Chemistry Syllabus (JEE Main)

Q. In a zero-order reaction, how does the rate change with respect to concentration?
  • A. Increases linearly
  • B. Decreases linearly
  • C. Remains constant
  • D. Increases exponentially
Q. In a zero-order reaction, if the rate constant k is 5 mol/L/s, how long will it take for the concentration to decrease from 2 mol/L to 0 mol/L?
  • A. 0.4 s
  • B. 0.5 s
  • C. 0.6 s
  • D. 0.8 s
Q. In a zero-order reaction, the rate of reaction is independent of which of the following?
  • A. Concentration of reactants
  • B. Temperature
  • C. Catalyst
  • D. All of the above
Q. In an endothermic reaction, the enthalpy of the products is ____ than that of the reactants.
  • A. higher
  • B. lower
  • C. equal
  • D. unpredictable
Q. In an ideal solution, the enthalpy of mixing is:
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Varies with concentration
Q. In an irreversible process, the change in entropy of the universe is:
  • A. Zero
  • B. Positive
  • C. Negative
  • D. Undefined
Q. In an isothermal process, the temperature of the system remains constant. What is the work done by the gas during expansion?
  • A. Zero
  • B. nRT ln(Vf/Vi)
  • C. nRT (Vf - Vi)
  • D. nR (Tf - Ti)
Q. In electrochemistry, what does the term 'reduction' refer to?
  • A. Loss of electrons
  • B. Gain of electrons
  • C. Loss of protons
  • D. Gain of protons
Q. In molecular orbital theory, which of the following orbitals is the highest energy in O2?
  • A. σ2p
  • B. π2p
  • C. σ2s
  • D. π2s
Q. In molecular orbital theory, which of the following statements is correct regarding the energy levels of orbitals?
  • A. σ orbitals are always lower than π orbitals.
  • B. π orbitals are always lower than σ orbitals.
  • C. σ* orbitals are always higher than π* orbitals.
  • D. Energy levels can vary based on the atoms involved.
Q. In the complex [Ni(CO)4], what is the hybridization of the nickel atom?
  • A. sp
  • B. sp2
  • C. sp3
  • D. d2sp3
Q. In the context of adsorption, what does the term 'saturation' refer to?
  • A. Complete coverage of the adsorbent surface
  • B. Maximum temperature for adsorption
  • C. Equilibrium state of adsorption and desorption
  • D. None of the above
Q. In the equilibrium constant expression Kc, what is the unit for Kc if the reaction is A(g) + B(g) ⇌ C(g)?
  • A. mol/L
  • B. L/mol
  • C. dimensionless
  • D. mol^2/L^2
Q. In the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what happens if SO3 is removed?
  • A. Shift to the right
  • B. Shift to the left
  • C. No change
  • D. Increase in pressure
Q. In the Freundlich adsorption isotherm, which parameter indicates the extent of adsorption?
  • A. K
  • B. n
  • C. P
  • D. T
Q. In the ideal gas equation PV=nRT, what does 'n' represent?
  • A. Pressure
  • B. Volume
  • C. Number of moles
  • D. Temperature
Q. In the Langmuir adsorption isotherm, what assumption is made about the adsorption sites?
  • A. They are identical and have the same energy
  • B. They are different and have varying energy
  • C. They can accommodate multiple layers
  • D. They are not limited in number
Q. In the Langmuir adsorption isotherm, what does the term 'b' represent?
  • A. Adsorption energy
  • B. Surface area
  • C. Equilibrium constant
  • D. Adsorption capacity
Q. In the molecular orbital diagram of diatomic nitrogen (N2), which orbitals are filled first?
  • A. σ2s, σ*2s
  • B. σ2p, π2p
  • C. π2p, σ2p
  • D. σ*2p, π*2p
Q. In the molecular orbital theory, which of the following is true for the π molecular orbitals?
  • A. They are formed by end-to-end overlap.
  • B. They are lower in energy than σ orbitals.
  • C. They can accommodate a maximum of 2 electrons.
  • D. They are always bonding.
Q. In the molecular orbital theory, which of the following orbitals is lower in energy than the 2p orbitals?
  • A. 2s
  • B. 3s
  • C. 2p
  • D. 3p
Q. In the molecular orbital theory, which of the following orbitals is lower in energy for homonuclear diatomic molecules?
  • A. σ2p
  • B. π2p
  • C. σ2s
  • D. π2s
Q. In the molecular orbital theory, which of the following orbitals is the highest energy in O2?
  • A. σ2p
  • B. π2p
  • C. σ*2p
  • D. π*2p
Q. In the molecular orbital theory, which of the following orbitals is the highest occupied molecular orbital (HOMO) in O2?
  • A. σ2p
  • B. π2p
  • C. σ*2p
  • D. π*2p
Q. In the molecular orbital theory, which of the following pairs of orbitals can combine to form a sigma bond?
  • A. s and p
  • B. p and p
  • C. s and s
  • D. d and p
Q. In the molecular orbital theory, which orbitals combine to form sigma bonds?
  • A. s and p orbitals
  • B. p and d orbitals
  • C. s orbitals only
  • D. p orbitals only
Q. In the reaction 2Ag+ + Zn → 2Ag + Zn2+, which species is oxidized?
  • A. Ag+
  • B. Zn
  • C. Ag
  • D. Zn2+
Q. In the reaction 2Ag+ + Zn → 2Ag + Zn2+, which species is reduced?
  • A. Ag+
  • B. Zn
  • C. Ag
  • D. Zn2+
Q. In the reaction 2AgNO3 + Cu → 2Ag + Cu(NO3)2, what is the oxidation state of silver in AgNO3?
  • A. +1
  • B. 0
  • C. +2
  • D. +3
Q. In the reaction 2Ag^+ + Zn → 2Ag + Zn^2+, what is the oxidation state change for zinc?
  • A. 0 to +2
  • B. +2 to 0
  • C. +2 to +1
  • D. 0 to -1
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