Chemistry
Q. Which of the following is the functional group of aldehydes? (2023) 2023
A.
-CHO
B.
-CO-
C.
-C=O
D.
-OH
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Solution
Aldehydes contain the functional group -CHO, which is characterized by a carbonyl group (C=O) bonded to a hydrogen atom.
Correct Answer: A — -CHO
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Q. Which of the following is the most acidic among the following oxides? (2019)
A.
SO2
B.
P2O5
C.
CO2
D.
N2O5
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Solution
P2O5 is the most acidic oxide among the given options, as it forms phosphoric acid in water.
Correct Answer: B — P2O5
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Q. Which of the following is the strongest carboxylic acid? (2022)
A.
Formic acid
B.
Acetic acid
C.
Propanoic acid
D.
Butanoic acid
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Solution
Formic acid (HCOOH) is the strongest carboxylic acid among the given options due to the presence of a hydrogen atom directly attached to the carbonyl carbon, which increases its acidity.
Correct Answer: A — Formic acid
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Q. Which of the following ligands is a strong field ligand? (2021) 2021
A.
I-
B.
Br-
C.
CN-
D.
Cl-
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Solution
CN- is a strong field ligand that causes a large splitting of d-orbitals, leading to low-spin complexes.
Correct Answer: C — CN-
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Q. Which of the following methods is used to purify colloidal solutions? (2020)
A.
Filtration
B.
Centrifugation
C.
Dialysis
D.
Evaporation
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Solution
Dialysis is used to purify colloidal solutions by allowing the solvent and small solutes to pass through a semi-permeable membrane while retaining the colloidal particles.
Correct Answer: C — Dialysis
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Q. Which of the following molecules has a polar covalent bond? (2023)
A.
Cl2
B.
H2O
C.
CH4
D.
O2
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Solution
Water (H2O) has a polar covalent bond due to the difference in electronegativity between hydrogen and oxygen.
Correct Answer: B — H2O
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Q. Which of the following molecules has a polar covalent bond? (2023) 2023
A.
Cl2
B.
H2O
C.
CH4
D.
O2
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Solution
Water (H2O) has a polar covalent bond due to the difference in electronegativity between hydrogen and oxygen.
Correct Answer: B — H2O
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Q. Which of the following pairs are both f-block elements?
A.
Uranium and Thorium
B.
Lanthanum and Cerium
C.
Neodymium and Plutonium
D.
Zirconium and Hafnium
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Solution
Neodymium (Nd) and Plutonium (Pu) are both f-block elements.
Correct Answer: C — Neodymium and Plutonium
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Q. Which of the following pairs are f-block elements? (2023)
A.
Zinc and Cadmium
B.
Lanthanum and Cerium
C.
Iron and Cobalt
D.
Copper and Silver
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Solution
Lanthanum (La) and Cerium (Ce) are both f-block elements, belonging to the lanthanide series.
Correct Answer: B — Lanthanum and Cerium
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Q. Which of the following particles has the least mass? (2020) 2020
A.
Proton
B.
Neutron
C.
Electron
D.
Alpha particle
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Solution
The mass of an electron is significantly less than that of protons and neutrons.
Correct Answer: C — Electron
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Q. Which of the following particles has the least mass? (2021) 2021
A.
Proton
B.
Neutron
C.
Electron
D.
Alpha particle
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Solution
The electron has the least mass compared to protons and neutrons.
Correct Answer: C — Electron
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Q. Which of the following processes involves a change from gas to liquid?
A.
Sublimation
B.
Condensation
C.
Evaporation
D.
Freezing
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Solution
Condensation is the process where gas changes to liquid.
Correct Answer: B — Condensation
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Q. Which of the following processes is irreversible? (2022)
A.
Isothermal expansion
B.
Adiabatic expansion
C.
Free expansion
D.
Isobaric process
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Solution
Free expansion is an irreversible process as it occurs without any external pressure acting on the gas.
Correct Answer: C — Free expansion
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Q. Which of the following processes is isochoric? (2023)
A.
Constant volume
B.
Constant pressure
C.
Constant temperature
D.
Adiabatic
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Solution
An isochoric process is one that occurs at constant volume.
Correct Answer: A — Constant volume
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Q. Which of the following quantum numbers describes the shape of an orbital? (2020) 2020
A.
Principal quantum number
B.
Azimuthal quantum number
C.
Magnetic quantum number
D.
Spin quantum number
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Solution
The azimuthal quantum number (l) describes the shape of an orbital.
Correct Answer: B — Azimuthal quantum number
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Q. Which of the following reactions involves a redox process? (2019)
A.
H2 + Cl2 → 2HCl
B.
NaCl → Na + Cl2
C.
CaCO3 → CaO + CO2
D.
H2O → H2 + O2
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Solution
H2O → H2 + O2 involves the oxidation of water to hydrogen and oxygen, making it a redox reaction.
Correct Answer: D — H2O → H2 + O2
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Q. Which of the following species acts as a reducing agent in the reaction 2Fe2O3 + 3C → 4Fe + 3CO? (2022)
A.
Fe2O3
B.
C
C.
Fe
D.
CO
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Solution
Carbon (C) acts as a reducing agent as it donates electrons to reduce Fe2O3 to Fe.
Correct Answer: B — C
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Q. Which of the following species acts as a reducing agent in the reaction 2Fe2O3 + 3C → 4Fe + 3CO2? (2020)
A.
Fe2O3
B.
C
C.
Fe
D.
CO2
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Solution
Carbon (C) acts as a reducing agent as it donates electrons to reduce Fe2O3 to Fe.
Correct Answer: B — C
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Q. Which of the following statements about carboxylic acids is incorrect? (2020)
A.
They can form hydrogen bonds.
B.
They have higher boiling points than alcohols.
C.
They are less acidic than alcohols.
D.
They can be converted to esters.
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Solution
Carboxylic acids are more acidic than alcohols due to the resonance stabilization of their conjugate base, making the statement 'They are less acidic than alcohols' incorrect.
Correct Answer: C — They are less acidic than alcohols.
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Q. Which of the following statements is true about adsorption? (2023)
A.
It is a bulk phenomenon
B.
It is a surface phenomenon
C.
It occurs only in gases
D.
It is always exothermic
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Solution
Adsorption is a surface phenomenon as it occurs at the interface between phases.
Correct Answer: B — It is a surface phenomenon
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Q. Which of the following statements is true about coordination compounds? (2021) 2021
A.
They are always ionic
B.
They can exhibit optical isomerism
C.
They have fixed oxidation states
D.
They cannot form complexes
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Solution
Coordination compounds can exhibit optical isomerism due to the arrangement of ligands around the central metal ion.
Correct Answer: B — They can exhibit optical isomerism
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Q. Which of the following statements is true about galvanic cells? (2020)
A.
They convert chemical energy to electrical energy
B.
They require an external power source
C.
They operate only in acidic solutions
D.
They are always non-spontaneous
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Solution
Galvanic cells convert chemical energy into electrical energy spontaneously.
Correct Answer: A — They convert chemical energy to electrical energy
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Q. Which of the following statements is true for an adiabatic process? (2022) 2022
A.
Heat is exchanged with the surroundings
B.
Work done is zero
C.
Temperature changes
D.
Pressure remains constant
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Solution
In an adiabatic process, there is no heat exchange with the surroundings, and the temperature of the system changes due to work done on or by the system.
Correct Answer: C — Temperature changes
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Q. Which of the following statements is true for an isochoric process? (2023)
A.
Volume remains constant
B.
Pressure remains constant
C.
Temperature remains constant
D.
Heat is absorbed
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Solution
In an isochoric process, the volume of the system remains constant.
Correct Answer: A — Volume remains constant
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Q. Which of the following statements is true for the complex [Fe(CN)6]3-? (2023)
A.
It is a high-spin complex
B.
It is a low-spin complex
C.
It has a coordination number of 4
D.
It is paramagnetic
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Solution
The complex [Fe(CN)6]3- is a low-spin complex due to the strong field nature of CN- ligands, resulting in paired electrons.
Correct Answer: B — It is a low-spin complex
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Q. Which of the following statements is true regarding reduction? (2020)
A.
It involves the gain of electrons
B.
It involves the loss of electrons
C.
It always occurs with oxidation
D.
Both A and C are correct
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Solution
Reduction is defined as the gain of electrons, and it always occurs simultaneously with oxidation in redox reactions.
Correct Answer: D — Both A and C are correct
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Q. Which of the following statements is true regarding the Freundlich adsorption isotherm? (2020)
A.
It applies only to monolayer adsorption.
B.
It is applicable to heterogeneous surfaces.
C.
It predicts a constant adsorption capacity.
D.
It is a linear relationship.
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Solution
The Freundlich adsorption isotherm is applicable to heterogeneous surfaces and describes how adsorption varies with pressure or concentration, indicating that it is not limited to monolayer adsorption.
Correct Answer: B — It is applicable to heterogeneous surfaces.
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Q. Which of the following statements is true regarding the Freundlich adsorption isotherm? (2020) 2020
A.
It is applicable to monolayer adsorption.
B.
It assumes a uniform surface.
C.
It is a linear relationship.
D.
It describes heterogeneous adsorption.
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Solution
The Freundlich adsorption isotherm describes heterogeneous adsorption on surfaces with varying affinities, making it suitable for real-world applications.
Correct Answer: D — It describes heterogeneous adsorption.
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Q. Which of the following states of matter has a definite shape?
A.
Solid
B.
Liquid
C.
Gas
D.
Plasma
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Solution
Solids have a definite shape due to closely packed particles that do not move freely.
Correct Answer: A — Solid
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Q. Which of the following states of matter has a definite volume but no definite shape?
A.
Solid
B.
Liquid
C.
Gas
D.
Plasma
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Solution
Liquids have a definite volume but take the shape of their container.
Correct Answer: B — Liquid
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