Engineering & Architecture Admissions
Q. Which of the following statements is true regarding the complex [Co(NH3)6]3+?
A.
It is tetrahedral
B.
It is octahedral
C.
It is square planar
D.
It has no unpaired electrons
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Solution
[Co(NH3)6]3+ is octahedral in geometry due to the six ligands surrounding the cobalt ion.
Correct Answer: B — It is octahedral
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Q. Which of the following statements is true regarding the complex [Cu(NH3)4]SO4?
A.
Cu is in +1 oxidation state
B.
Cu is in +2 oxidation state
C.
NH3 is a monodentate ligand
D.
All of the above
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Solution
In [Cu(NH3)4]SO4, copper is in +2 oxidation state, NH3 is a monodentate ligand, making the statement 'All of the above' incorrect.
Correct Answer: D — All of the above
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Q. Which of the following statements is true regarding the Earth's magnetic field?
A.
It is uniform everywhere
B.
It has a magnetic north and south pole
C.
It is only present at the equator
D.
It does not affect compass needles
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Solution
The Earth's magnetic field has a magnetic north and south pole and affects compass needles, causing them to align with the field.
Correct Answer: B — It has a magnetic north and south pole
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Q. Which of the following statements is true regarding the energy levels of molecular orbitals?
A.
σ orbitals are always lower in energy than π orbitals.
B.
π orbitals are always lower in energy than σ orbitals.
C.
For second period elements, σ2p is lower than π2p.
D.
Bonding orbitals are higher in energy than antibonding orbitals.
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Solution
For second period elements, σ2p is lower in energy than π2p.
Correct Answer: C — For second period elements, σ2p is lower than π2p.
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Q. Which of the following statements is true regarding the equilibrium constant (K) for a reaction?
A.
K is temperature dependent
B.
K is pressure dependent
C.
K is concentration dependent
D.
K is always equal to 1
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Solution
The equilibrium constant (K) is dependent on temperature; it changes with temperature variations.
Correct Answer: A — K is temperature dependent
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Q. Which of the following statements is true regarding the equilibrium constant Kc?
A.
Kc is temperature dependent
B.
Kc is pressure dependent
C.
Kc is concentration dependent
D.
Kc is independent of the reaction
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Solution
The equilibrium constant Kc is dependent on temperature; changing the temperature will change the value of Kc.
Correct Answer: A — Kc is temperature dependent
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Q. Which of the following statements is true regarding the first law of thermodynamics?
A.
It applies only to closed systems.
B.
It is a statement of conservation of energy.
C.
It can be violated under certain conditions.
D.
It only applies to mechanical systems.
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Solution
The first law of thermodynamics is a statement of conservation of energy, applicable to all thermodynamic systems.
Correct Answer: B — It is a statement of conservation of energy.
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Q. Which of the following statements is true regarding the inductive effect?
A.
It is a temporary effect.
B.
It operates through pi bonds.
C.
It is stronger than the mesomeric effect.
D.
It decreases with distance.
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Solution
The inductive effect decreases with distance from the electronegative atom or group.
Correct Answer: D — It decreases with distance.
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Q. Which of the following statements is true regarding the Langmuir adsorption isotherm?
A.
It assumes a monolayer adsorption.
B.
It applies to multilayer adsorption.
C.
It is temperature independent.
D.
It is only applicable to gases.
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Solution
The Langmuir adsorption isotherm assumes that adsorption occurs in a monolayer on a surface with a finite number of identical sites.
Correct Answer: A — It assumes a monolayer adsorption.
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Q. Which of the following statements is true regarding the mean free path of gas molecules?
A.
It increases with increasing temperature.
B.
It decreases with increasing pressure.
C.
It is independent of the size of the gas molecules.
D.
It is constant for all gases.
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Solution
The mean free path decreases with increasing pressure because more molecules are present in a given volume, leading to more frequent collisions.
Correct Answer: B — It decreases with increasing pressure.
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Q. Which of the following statements is true regarding the mesomeric effect?
A.
It can only be observed in aliphatic compounds.
B.
It involves the movement of sigma electrons.
C.
It is responsible for the stability of resonance structures.
D.
It is a short-range effect.
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Solution
The mesomeric effect is responsible for the stability of resonance structures due to the delocalization of pi electrons.
Correct Answer: C — It is responsible for the stability of resonance structures.
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Q. Which of the following statements is true regarding the molecular orbital configuration of O2?
A.
It has 2 unpaired electrons
B.
It has 4 unpaired electrons
C.
It is diamagnetic
D.
It has a bond order of 3
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Solution
O2 has 2 unpaired electrons in its molecular orbital configuration, making it paramagnetic.
Correct Answer: A — It has 2 unpaired electrons
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Q. Which of the following statements is true regarding the molecular orbital theory?
A.
It only applies to diatomic molecules.
B.
It explains the magnetic properties of molecules.
C.
It does not consider electron spin.
D.
It is less accurate than valence bond theory.
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Solution
Molecular orbital theory explains the magnetic properties of molecules, such as paramagnetism in O2.
Correct Answer: B — It explains the magnetic properties of molecules.
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Q. Which of the following statements is true regarding the moment of inertia?
A.
It depends on the mass distribution
B.
It is always constant
C.
It is independent of the axis of rotation
D.
It is only relevant for rigid bodies
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Solution
The moment of inertia depends on the mass distribution relative to the axis of rotation.
Correct Answer: A — It depends on the mass distribution
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Q. Which of the following statements is true regarding the photoelectric effect?
A.
Electrons are emitted only if the light is of high intensity
B.
Electrons are emitted regardless of the frequency of light
C.
There is a threshold frequency below which no electrons are emitted
D.
The photoelectric effect can occur with any type of electromagnetic radiation
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Solution
The photoelectric effect requires a minimum threshold frequency; below this frequency, no electrons are emitted regardless of the intensity of the light.
Correct Answer: C — There is a threshold frequency below which no electrons are emitted
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Q. Which of the following statements is true regarding the rate of a reaction?
A.
It increases with increasing temperature
B.
It decreases with increasing concentration
C.
It is constant for all reactions
D.
It is independent of the nature of reactants
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Solution
The rate of a reaction generally increases with increasing temperature.
Correct Answer: A — It increases with increasing temperature
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Q. Which of the following statements is true regarding the rate of reaction?
A.
It is always constant
B.
It decreases with time for a reactant
C.
It increases with time for a product
D.
Both B and C
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Solution
The rate of reaction decreases with time for a reactant and increases with time for a product.
Correct Answer: D — Both B and C
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Q. Which of the following statements is true regarding the second law of thermodynamics?
A.
It allows for the conversion of heat into work with 100% efficiency
B.
It states that energy can be created from nothing
C.
It introduces the concept of entropy
D.
It applies only to mechanical systems
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Solution
The second law of thermodynamics introduces the concept of entropy, stating that the total entropy of an isolated system can never decrease over time.
Correct Answer: C — It introduces the concept of entropy
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Q. Which of the following statements is true regarding the use of a potentiometer?
A.
It can measure current directly
B.
It requires a galvanometer for operation
C.
It can only measure AC voltages
D.
It is not affected by the internal resistance of the source
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Solution
A potentiometer is not affected by the internal resistance of the source because it measures voltage by balancing it against a known voltage.
Correct Answer: D — It is not affected by the internal resistance of the source
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Q. Which of the following statements is true regarding the Van der Waals equation?
A.
It accounts for the volume of gas particles.
B.
It is only applicable to ideal gases.
C.
It does not consider intermolecular forces.
D.
It is a linear equation.
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Solution
The Van der Waals equation accounts for the volume of gas particles and intermolecular forces.
Correct Answer: A — It accounts for the volume of gas particles.
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Q. Which of the following statements is true regarding the Wheatstone bridge?
A.
It can only measure AC resistances
B.
It can measure unknown resistances
C.
It requires a power source to operate
D.
It is only used in high voltage applications
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Solution
The Wheatstone bridge is primarily used to measure unknown resistances by balancing it against known resistances.
Correct Answer: B — It can measure unknown resistances
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Q. Which of the following statements is true regarding total internal reflection?
A.
It occurs when light travels from a denser to a rarer medium.
B.
It occurs when light travels from a rarer to a denser medium.
C.
It can occur at any angle.
D.
It requires a prism.
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Solution
Total internal reflection occurs when light travels from a denser medium to a rarer medium.
Correct Answer: A — It occurs when light travels from a denser to a rarer medium.
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Q. Which of the following states of matter can be compressed the most?
A.
Solid
B.
Liquid
C.
Gas
D.
Plasma
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Solution
Gases can be compressed the most due to the large spaces between particles.
Correct Answer: C — Gas
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Q. Which of the following states of matter has a definite shape and volume?
A.
Gas
B.
Liquid
C.
Solid
D.
Plasma
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Solution
Solids have a definite shape and volume due to closely packed particles.
Correct Answer: C — Solid
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Q. Which of the following states of matter has the highest density?
A.
Gas
B.
Liquid
C.
Solid
D.
Plasma
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Solution
Solids generally have the highest density due to closely packed particles.
Correct Answer: C — Solid
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Q. Which of the following states of matter has the least amount of energy?
A.
Solid
B.
Liquid
C.
Gas
D.
Plasma
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Solution
Solids have the least amount of energy compared to liquids, gases, and plasma.
Correct Answer: A — Solid
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Q. Which of the following states of matter has the least amount of kinetic energy?
A.
Solid
B.
Liquid
C.
Gas
D.
Plasma
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Solution
Solids have the least amount of kinetic energy as their particles are closely packed and vibrate in fixed positions.
Correct Answer: A — Solid
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Q. Which of the following surfaces is the best emitter of radiation?
A.
Shiny surface
B.
Dull black surface
C.
White surface
D.
Transparent surface
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Solution
A dull black surface is the best emitter of radiation according to Kirchhoff's law of thermal radiation.
Correct Answer: B — Dull black surface
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Q. Which of the following surfaces is the best emitter of thermal radiation?
A.
Shiny metal
B.
White paint
C.
Black paint
D.
Glass
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Solution
A black surface is the best emitter of thermal radiation due to its high emissivity.
Correct Answer: C — Black paint
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Q. Which of the following techniques is commonly used to determine protein structure?
A.
Mass spectrometry
B.
Nuclear magnetic resonance (NMR)
C.
X-ray crystallography
D.
Both B and C
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Solution
Both nuclear magnetic resonance (NMR) and X-ray crystallography are commonly used techniques to determine the three-dimensional structure of proteins.
Correct Answer: D — Both B and C
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