Chemistry
Q. What is the effect of increasing temperature on chemisorption? (2022)
A.
Increases adsorption
B.
Decreases adsorption
C.
No effect
D.
Depends on the gas
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Solution
Chemisorption is an exothermic process, and increasing temperature generally decreases the extent of chemisorption.
Correct Answer: B — Decreases adsorption
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Q. What is the effect of increasing temperature on the volume of a gas at constant pressure?
A.
Volume decreases
B.
Volume increases
C.
Volume remains constant
D.
Volume fluctuates
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Solution
According to Charles's Law, increasing the temperature of a gas at constant pressure increases its volume.
Correct Answer: B — Volume increases
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Q. What is the effect of increasing the temperature on the solubility of most solid solutes in water? (2023)
A.
Increases solubility
B.
Decreases solubility
C.
No effect
D.
Depends on the solute
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Solution
For most solid solutes, increasing the temperature increases their solubility in water.
Correct Answer: A — Increases solubility
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Q. What is the effect of temperature on chemisorption? (2023)
A.
Increases with temperature
B.
Decreases with temperature
C.
Remains constant
D.
Depends on the gas
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Solution
Chemisorption typically decreases with an increase in temperature because it involves the formation of stronger chemical bonds, which are less favorable at higher thermal energies.
Correct Answer: B — Decreases with temperature
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Q. What is the effect of temperature on chemisorption? (2023) 2023
A.
Increases with temperature
B.
Decreases with temperature
C.
Remains constant
D.
Depends on the gas
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Solution
Chemisorption typically decreases with an increase in temperature because it involves the formation of stronger chemical bonds, which are less favorable at higher thermal energies.
Correct Answer: B — Decreases with temperature
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Q. What is the effect of temperature on the cell potential according to the Nernst equation?
A.
Increases with temperature
B.
Decreases with temperature
C.
No effect
D.
Depends on the reaction
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Solution
According to the Nernst equation, the cell potential generally increases with temperature.
Correct Answer: A — Increases with temperature
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Q. What is the efficiency of a Carnot engine operating between temperatures T1 and T2? (2019) 2019
A.
(T1 - T2) / T1
B.
T2 / T1
C.
(T1 - T2) / T2
D.
1 - (T2 / T1)
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Solution
The efficiency (η) of a Carnot engine is given by η = 1 - (T2 / T1), where T1 is the higher temperature and T2 is the lower temperature.
Correct Answer: D — 1 - (T2 / T1)
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Q. What is the electron configuration of Chromium?
A.
[Ar] 3d4 4s2
B.
[Ar] 3d5 4s1
C.
[Ar] 3d6 4s2
D.
[Ar] 3d3 4s2
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Solution
Chromium (Cr) has the electron configuration [Ar] 3d5 4s1 due to stability of half-filled d-orbitals.
Correct Answer: B — [Ar] 3d5 4s1
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Q. What is the equilibrium constant (Kc) for the reaction 2A + B ⇌ C? (2022)
A.
Kc = [C] / ([A]^2[B])
B.
Kc = [A]^2[B] / [C]
C.
Kc = [B] / ([A]^2[C])
D.
Kc = [C] / ([B][A])
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Solution
The equilibrium constant Kc is defined as the concentration of the products raised to the power of their coefficients divided by the concentration of the reactants raised to the power of their coefficients. For the reaction 2A + B ⇌ C, Kc = [C] / ([A]^2[B]).
Correct Answer: A — Kc = [C] / ([A]^2[B])
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Q. What is the equilibrium constant (Kc) for the reaction: A + B ⇌ C + D? (2022)
A.
Kc = [C][D]/[A][B]
B.
Kc = [A][B]/[C][D]
C.
Kc = [C][D][A][B]
D.
Kc = [A][B][C][D]
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Solution
The equilibrium constant Kc is defined as the ratio of the concentrations of the products to the reactants, each raised to the power of their coefficients in the balanced equation.
Correct Answer: A — Kc = [C][D]/[A][B]
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Q. What is the equilibrium constant (Kc) for the reaction: N2(g) + 3H2(g) ⇌ 2NH3(g)? (2022) 2022
A.
1.0 × 10^-5
B.
1.0 × 10^-2
C.
1.0 × 10^2
D.
1.0 × 10^5
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Solution
The equilibrium constant Kc for the formation of ammonia from nitrogen and hydrogen is typically around 1.0 × 10^5 at standard conditions.
Correct Answer: D — 1.0 × 10^5
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Q. What is the expected major product when 2-bromobutane undergoes elimination reaction?
A.
But-1-ene
B.
But-2-ene
C.
But-3-ene
D.
Butane
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Solution
The major product of the elimination reaction of 2-bromobutane is But-2-ene due to the formation of the more stable alkene.
Correct Answer: B — But-2-ene
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Q. What is the expected product of the reaction of 1-chlorobutane with zinc in dry ether?
A.
Butane
B.
Butyne
C.
Butene
D.
No reaction
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Solution
The reaction of 1-chlorobutane with zinc in dry ether leads to the formation of Butane via Wurtz reaction.
Correct Answer: A — Butane
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Q. What is the expected product when 1-chlorobutane reacts with aqueous NaOH?
A.
Butanol
B.
Butene
C.
No reaction
D.
Butyric acid
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Solution
The expected product is Butanol due to nucleophilic substitution with hydroxide ion.
Correct Answer: A — Butanol
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Q. What is the Faraday's constant value?
A.
96485 C/mol
B.
96500 C/mol
C.
96500 A·s/mol
D.
96480 C/mol
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Solution
Faraday's constant is approximately 96485 C/mol.
Correct Answer: A — 96485 C/mol
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Q. What is the Faraday's constant?
A.
96485 C/mol
B.
96500 C/mol
C.
96500 J/mol
D.
96485 J/mol
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Solution
Faraday's constant is approximately 96485 C/mol.
Correct Answer: A — 96485 C/mol
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Q. What is the final concentration when 100 mL of 1 M NaCl is diluted to 500 mL? (2021)
A.
0.2 M
B.
0.5 M
C.
1 M
D.
2 M
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Solution
Using M1V1 = M2V2, (1 M)(0.1 L) = M2(0.5 L). M2 = 0.2 M.
Correct Answer: B — 0.5 M
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Q. What is the final volume when 100 mL of a 3 M solution is diluted to a concentration of 1 M? (2022) 2022
A.
300 mL
B.
200 mL
C.
100 mL
D.
150 mL
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Solution
Using the dilution formula C1V1 = C2V2, we have 3 M * 100 mL = 1 M * V2. Thus, V2 = 300 mL.
Correct Answer: A — 300 mL
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Q. What is the formula for calculating the number of moles? (2023) 2023
A.
Mass/Volume
B.
Mass/Molar Mass
C.
Volume/Mass
D.
Molar Mass/Volume
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Solution
The number of moles is calculated using the formula: Moles = Mass / Molar Mass.
Correct Answer: B — Mass/Molar Mass
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Q. What is the formula for the complex formed between iron(III) and thiocyanate? (2021)
A.
[Fe(SCN)3]
B.
[Fe(SCN)2]
C.
[Fe(SCN)6]3+
D.
[Fe(SCN)4]2-
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Solution
The complex formed is [Fe(SCN)3] as iron(III) can bond with three thiocyanate ions.
Correct Answer: A — [Fe(SCN)3]
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Q. What is the freezing point depression of a solution containing 1 mol of NaCl in 1 kg of water? (Kf for water = 1.86 °C kg/mol) (2023)
A.
1.86 °C
B.
3.72 °C
C.
2.00 °C
D.
0.93 °C
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Solution
Freezing point depression (ΔTf) = i * Kf * m. For NaCl, i = 2 (dissociates into Na+ and Cl-). m = 1 mol/kg. ΔTf = 2 * 1.86 °C kg/mol * 1 = 3.72 °C.
Correct Answer: B — 3.72 °C
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Q. What is the functional group of alcohols? (2020)
A.
-OH
B.
-COOH
C.
-CHO
D.
-NH2
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Solution
The functional group of alcohols is the hydroxyl group (-OH).
Correct Answer: A — -OH
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Q. What is the functional group of aldehydes?
A.
-OH
B.
-CHO
C.
-C=O
D.
-COOH
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Solution
The functional group of aldehydes is -CHO.
Correct Answer: B — -CHO
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Q. What is the functional group of phenols? (2019) 2019
A.
-OH
B.
-COOH
C.
-CHO
D.
-NH2
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Solution
Phenols contain a hydroxyl group (-OH) directly attached to an aromatic ring.
Correct Answer: A — -OH
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Q. What is the functional group present in alcohols? (2023) 2023
A.
Aldehyde
B.
Ketone
C.
Hydroxyl
D.
Carboxylic acid
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Solution
Alcohols contain a hydroxyl (-OH) functional group.
Correct Answer: C — Hydroxyl
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Q. What is the functional group present in phenols? (2021)
A.
-OH
B.
-COOH
C.
-CHO
D.
-NH2
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Solution
Phenols contain a hydroxyl group (-OH) directly attached to an aromatic hydrocarbon group.
Correct Answer: A — -OH
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Q. What is the functional group present in phenols? (2021) 2021
A.
-OH
B.
-COOH
C.
-CHO
D.
-NH2
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Solution
Phenols contain a hydroxyl group (-OH) directly attached to an aromatic hydrocarbon group.
Correct Answer: A — -OH
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Q. What is the general formula for secondary amines? (2021) 2021
A.
RNH2
B.
R2NH
C.
R3N
D.
RNH
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Solution
The general formula for secondary amines is R2NH, where R represents an alkyl or aryl group.
Correct Answer: B — R2NH
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Q. What is the geometry of a molecule with two bonding pairs and no lone pairs on the central atom? (2023)
A.
Linear
B.
Trigonal planar
C.
Tetrahedral
D.
Bent
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Solution
The geometry is linear when there are two bonding pairs and no lone pairs on the central atom.
Correct Answer: A — Linear
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Q. What is the geometry of the complex ion [Ag(NH3)2]+? (2019) 2019
A.
Tetrahedral
B.
Square planar
C.
Octahedral
D.
Linear
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Solution
The complex [Ag(NH3)2]+ has a linear geometry due to the presence of two ligands around the silver ion.
Correct Answer: D — Linear
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