Intro to Spectroscopy (UV-Vis, IR) - Competitive Exam Level
Q. In IR spectroscopy, what does a broad peak around 3200-3600 cm-1 typically indicate?
A.
Alkane C-H stretch
B.
Aromatic C=C stretch
C.
O-H stretch in alcohols
D.
C=O stretch in ketones
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Solution
A broad peak in this region typically indicates the presence of O-H stretching vibrations in alcohols or phenols.
Correct Answer: C — O-H stretch in alcohols
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Q. In IR spectroscopy, which bond typically shows a strong absorption around 3300 cm-1?
A.
C-H bond
B.
N-H bond
C.
O-H bond
D.
C=O bond
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Solution
The O-H bond in alcohols and carboxylic acids typically shows a strong absorption around 3300 cm-1 due to the stretching vibration.
Correct Answer: C — O-H bond
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Q. In IR spectroscopy, which functional group typically shows a strong absorption around 1700 cm-1?
A.
Alcohols
B.
Aldehydes
C.
Carboxylic acids
D.
Ketones
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Solution
Ketones typically show a strong carbonyl (C=O) absorption around 1700 cm-1 due to the stretching vibration.
Correct Answer: D — Ketones
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Q. In UV-Vis spectroscopy, what does a higher absorbance indicate?
A.
Lower concentration of the analyte
B.
Higher concentration of the analyte
C.
Higher wavelength of light
D.
Lower energy of light
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Solution
A higher absorbance indicates a higher concentration of the analyte, as per the Beer-Lambert Law.
Correct Answer: B — Higher concentration of the analyte
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Q. What is the main advantage of using a UV-Vis spectrophotometer?
A.
It can analyze solid samples
B.
It provides real-time analysis
C.
It requires no sample preparation
D.
It can measure very low concentrations
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Solution
One of the main advantages of UV-Vis spectrophotometry is that it can measure very low concentrations of analytes in solution.
Correct Answer: D — It can measure very low concentrations
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Q. What type of transition is primarily observed in UV-Vis spectroscopy?
A.
Nuclear spin transitions
B.
Rotational transitions
C.
Electronic transitions
D.
Vibrational transitions
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Solution
UV-Vis spectroscopy primarily observes electronic transitions, where electrons move between different energy levels.
Correct Answer: C — Electronic transitions
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Q. Which of the following instruments is commonly used for UV-Vis spectroscopy?
A.
Mass spectrometer
B.
NMR spectrometer
C.
Spectrophotometer
D.
Chromatograph
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Solution
A spectrophotometer is the instrument commonly used to measure absorbance in UV-Vis spectroscopy.
Correct Answer: C — Spectrophotometer
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Q. Which of the following is NOT a common application of IR spectroscopy?
A.
Identifying functional groups
B.
Determining molecular weight
C.
Studying molecular vibrations
D.
Analyzing chemical bonds
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Solution
Determining molecular weight is not a common application of IR spectroscopy; it is primarily used for identifying functional groups and studying molecular vibrations.
Correct Answer: B — Determining molecular weight
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