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Which of the following reactions is expected to have a positive change in entrop

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Question: Which of the following reactions is expected to have a positive change in entropy?

Options:

  1. N2(g) + 3H2(g) β†’ 2NH3(g)
  2. C(s) + O2(g) β†’ CO2(g)
  3. 2H2O(l) β†’ 2H2(g) + O2(g)
  4. CaCO3(s) β†’ CaO(s) + CO2(g)

Correct Answer: 2H2O(l) β†’ 2H2(g) + O2(g)

Solution:

The decomposition of liquid water into gaseous hydrogen and oxygen increases the number of gas molecules, leading to a positive change in entropy.

Which of the following reactions is expected to have a positive change in entrop

Practice Questions

Q1
Which of the following reactions is expected to have a positive change in entropy?
  1. N2(g) + 3H2(g) β†’ 2NH3(g)
  2. C(s) + O2(g) β†’ CO2(g)
  3. 2H2O(l) β†’ 2H2(g) + O2(g)
  4. CaCO3(s) β†’ CaO(s) + CO2(g)

Questions & Step-by-Step Solutions

Which of the following reactions is expected to have a positive change in entropy?
  • Step 1: Understand what entropy means. Entropy is a measure of disorder or randomness in a system.
  • Step 2: Identify the reactions being considered. Look for reactions that produce more gas molecules.
  • Step 3: Consider the decomposition of liquid water. The reaction is: 2 H2O (liquid) β†’ 2 H2 (gas) + O2 (gas).
  • Step 4: Count the number of molecules before and after the reaction. Before: 2 molecules of H2O (liquid). After: 2 molecules of H2 (gas) + 1 molecule of O2 (gas) = 3 gas molecules.
  • Step 5: Note that increasing the number of gas molecules generally increases disorder. More gas molecules mean more ways to arrange them.
  • Step 6: Conclude that the decomposition of liquid water into gas increases entropy, leading to a positive change in entropy.
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