Which of the following haloalkanes has the highest boiling point?

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Question: Which of the following haloalkanes has the highest boiling point?

Options:

Correct Answer: C4H9Cl

Solution:

C4H9Cl has the highest boiling point due to increased molecular weight and surface area leading to stronger van der Waals forces.

Which of the following haloalkanes has the highest boiling point?

Which of the following haloalkanes has the highest boiling point?

Step 1: Understand that haloalkanes are compounds that contain carbon, hydrogen, and halogen atoms (like chlorine).
Step 2: Know that boiling point is affected by molecular weight and surface area.
Step 3: Compare the molecular weights of the given haloalkanes. Higher molecular weight usually means a higher boiling point.
Step 4: Consider the surface area of the molecules. Larger surface area can lead to stronger van der Waals forces, which also increases boiling point.
Step 5: Identify that C4H9Cl has a larger molecular weight and surface area compared to other haloalkanes.
Step 6: Conclude that C4H9Cl will have the highest boiling point among the options.

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